The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal st...The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal stripping, such as the polymer of naphthenic acid, initial concentrations of iron and naphthenic acid, temperature and agitation time, were investigated, and based on experimental results and theoretical analysis, two kinetic models were established.The stripping rate equation suggests that the hydrothermal stripping process activation energy is 96.4 kJ·mol-1 and the stripping is controlled by hydrolysis of naphthenic complex of iron. The values calculated by the stripping fraction equation comparatively accord with the experimental data.展开更多
基金Supported by National Natural Science Foundation of China (No.20276074)
文摘The iron-loaded organic phase of naphthenic acid-isooctyl alcohol-kerosene was prepared, and the process kinetics of hydrothermal stripping of iron from the phase was studied. Several factors affecting hydrothermal stripping, such as the polymer of naphthenic acid, initial concentrations of iron and naphthenic acid, temperature and agitation time, were investigated, and based on experimental results and theoretical analysis, two kinetic models were established.The stripping rate equation suggests that the hydrothermal stripping process activation energy is 96.4 kJ·mol-1 and the stripping is controlled by hydrolysis of naphthenic complex of iron. The values calculated by the stripping fraction equation comparatively accord with the experimental data.
