PAN(Polyacrylonitrile)-based carbonaceous fibers were prepared at the heat treatment temperature(HTT)range of 650 to 900 oC.The relationships among HTT,carbon content and volume resistivity of the carbonaceous fibers ...PAN(Polyacrylonitrile)-based carbonaceous fibers were prepared at the heat treatment temperature(HTT)range of 650 to 900 oC.The relationships among HTT,carbon content and volume resistivity of the carbonaceous fibers were investigated.The carbonaceous fibers/PTFE(Polytetrafluoroethylene)antistatic coatings were prepared by the spraying technology and the effects of carbonaceous fibers and pigments on surface resistivity of the coatings were systematically discussed.Micrographs provide insight into the antistatic mechanism of the coating.The results show that carbon content of the carbonaceous fibers increases from 68.8% to 74.8%(mass fraction)and the volume resistivity decreases drastically from 1.94×103 to 8.27×10-2 Ω·cm.The surface resistivity of the antistatic coating is adjustable between 105 and 108 Ω to fit the different antistatic materials.Static is dissipated by a conductive network of short fibers and the tunneling effect between the neighboring fibers and conductive pigments.Conductive pigments make the conductive network more perfect and improve the antistatic ability,but insulating pigments acting as barriers for the formation of conductive channel increases the surface resistivity of the coatings.The influence of pigments on the surface resistivity drops gradually with the decrease of the carbonaceous fibers volume resistivity.展开更多
基金Project(2011CB605601)supported by the National Basic Research Program(973 Program)of ChinaProject(50902088)supported by the National Natural Science Foundation of China+1 种基金Project(ZR2011EMM002)supported by the Natural Science Foundation in Shandong Province,ChinaProject(2009AA035301)supported by the National High Technology Research and Development Program(863 Program)of China
文摘PAN(Polyacrylonitrile)-based carbonaceous fibers were prepared at the heat treatment temperature(HTT)range of 650 to 900 oC.The relationships among HTT,carbon content and volume resistivity of the carbonaceous fibers were investigated.The carbonaceous fibers/PTFE(Polytetrafluoroethylene)antistatic coatings were prepared by the spraying technology and the effects of carbonaceous fibers and pigments on surface resistivity of the coatings were systematically discussed.Micrographs provide insight into the antistatic mechanism of the coating.The results show that carbon content of the carbonaceous fibers increases from 68.8% to 74.8%(mass fraction)and the volume resistivity decreases drastically from 1.94×103 to 8.27×10-2 Ω·cm.The surface resistivity of the antistatic coating is adjustable between 105 and 108 Ω to fit the different antistatic materials.Static is dissipated by a conductive network of short fibers and the tunneling effect between the neighboring fibers and conductive pigments.Conductive pigments make the conductive network more perfect and improve the antistatic ability,but insulating pigments acting as barriers for the formation of conductive channel increases the surface resistivity of the coatings.The influence of pigments on the surface resistivity drops gradually with the decrease of the carbonaceous fibers volume resistivity.
