磁制冷是一种利用材料的磁热效应进行制冷的新型制冷技术,相比于传统气体压缩制冷,因其绿色环保、高效节能等优点而备受关注。在众多磁相变合金材料中,人们对Mn_2Sb基亚铁磁相变合金研究甚少。文章研究了Cr取代Mn后亚铁磁性Mn_(2-x)Cr_x...磁制冷是一种利用材料的磁热效应进行制冷的新型制冷技术,相比于传统气体压缩制冷,因其绿色环保、高效节能等优点而备受关注。在众多磁相变合金材料中,人们对Mn_2Sb基亚铁磁相变合金研究甚少。文章研究了Cr取代Mn后亚铁磁性Mn_(2-x)Cr_xSb_(0.95)In_(0.05)(x=0.05,0.09,0.13)合金的磁性和磁热性能。室温XRD数据表明合金在室温附近以四角Cu_2Sb型结构为主相。由于反铁磁中有高磁响应,因此从XRD图谱中能观察到少量的铁磁MnSb杂相。随着温度的降低,在这些合金中,发生了亚铁磁到反铁磁的一级磁致弹性转变。同时,在亚铁磁区域观察到两个自旋重新取向转变。由于反铁磁-亚铁磁的转变过程中磁化强度突变,使得在Mn_(1.91)Cr_(0.09)Sb_(0.95)In_(0.05)合金中在0~10 k Oe的磁场变化中获得高达1.63 J/kg·K的大磁熵变。目前的研究可能有助于研究和开发新的磁性冷材料。展开更多
We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferr...We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn （x = 0.11） gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.展开更多
This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co Sn ribbons. The experimental results show that the reverse martensitic transformation temperature TM increases ...This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co Sn ribbons. The experimental results show that the reverse martensitic transformation temperature TM increases with the increasing pre-pressure, suggesting that pre-deformation is another effective way to adjust TM in ferromagnetic shape memory alloys. Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well. It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn Co-Sn ribbons.展开更多
Ferromagnetic shape memory alloys, which undergo the martensitic transformation, are famous multifunctional materials. They exhibit many interesting magnetic properties around the martensitic transformation temperatur...Ferromagnetic shape memory alloys, which undergo the martensitic transformation, are famous multifunctional materials. They exhibit many interesting magnetic properties around the martensitic transformation temperature due to the strong coupling between magnetism and structure. Tuning magnetic phase transition and optimizing the magnetic effects in these alloys are of great importance. In this paper, the regulation of martensitic transformation and the investigation of some related magnetic effects in Ni–Mn-based alloys are reviewed based on our recent research results.展开更多
The spontaneous magnetization of the Ho^3＋ ion in holmium iron garnet （HoIG） single crystals in the temperature range of 4.2-294K along the directions [111], [110], and [100] are calculated, taking into account the...The spontaneous magnetization of the Ho^3＋ ion in holmium iron garnet （HoIG） single crystals in the temperature range of 4.2-294K along the directions [111], [110], and [100] are calculated, taking into account the effects of six magnetically inequivalent sites occupied by the Ho^3＋ ions based on the quantum theory. The calculated results show that the magnetization of the Ho^3＋ ion in HoIG is obviously anisotropic. The theoretical results ave in agreement with those of experiments. A primary interpretation of the anisotropy of magnetization of the Ho^3＋ ion in HoIG is put forward.展开更多
Topological superfluid state is different from the normal superfluid one due to the excitation energy gap on the boundary.How to obtain the topological superfluid state by using spin-orbit coupling to control the s-wa...Topological superfluid state is different from the normal superfluid one due to the excitation energy gap on the boundary.How to obtain the topological superfluid state by using spin-orbit coupling to control the s-waves paired mass-imbalanced Fermi gas is a recent novel topic.In this paper,we study the topological superfluid phase diagram of two-dimensional mass-imbalanced Fermi gas with Rashba spin-orbit coupling at zero temperature.We find that due to the competition among mass imbalance,pairing interaction and spin-orbit coupling,there is a double-well structure in the thermodynamic potential,which affects the properties of the ground state of the system.We comprehensively give the phase diagrams of the system on the plane of spin-orbit coupling and chemical potential,and the phase diagrams on the plane of the reduced mass ratio and two-body binding energy.This study not only points out the stable region of topolog-ical superfluid state of mass-imbalanced Fermi gas,but also provides a detailed theoretical basis for better observation of topological superfluid state in experiments.展开更多
The magneto-transport properties are investigated in metamagnetic CoMnSi0.ssGe0.12 alloy. By applying a magnetic field or increasing temperature, a metamagnetic phase transition from antiferromagnetic to ferromagnetic...The magneto-transport properties are investigated in metamagnetic CoMnSi0.ssGe0.12 alloy. By applying a magnetic field or increasing temperature, a metamagnetic phase transition from antiferromagnetic to ferromagnetic is observed in this alloy. Around the metamagnetic phase transition, CoMnSi0.88Ge0.12 alloy exhibits a large and negative magnetoresistance effect （-32%） under a magnetic field of 20 kOe （1Oe = 79.5775 A/m）, which is ascribed to the spin-dependent scattering of conduction electrons.展开更多
以放电等离子烧结(SPS)磁体为前驱烧结磁体,通过热变形制备了纳米晶各向异性磁体。研究了变形速率对磁体微观结构和性能的影响。研究发现,对于不同的应变速率,SPS磁体中不同区域的微观结构显示了不同的热变形行为。较大的晶粒尺寸不利...以放电等离子烧结(SPS)磁体为前驱烧结磁体,通过热变形制备了纳米晶各向异性磁体。研究了变形速率对磁体微观结构和性能的影响。研究发现,对于不同的应变速率,SPS磁体中不同区域的微观结构显示了不同的热变形行为。较大的晶粒尺寸不利于通过热变形制备各向异性Nd Fe B磁体。在不添加重稀土元素和较低稀土含量的情况下,制备出具有良好磁性能(Jr=1.35 T、jHc=829 k A/m和(BH)max=336 k J/m3)和较低矫顽力温度系数(β=–0.682%K-1)的纳米晶热变形磁体。展开更多
文摘磁制冷是一种利用材料的磁热效应进行制冷的新型制冷技术,相比于传统气体压缩制冷,因其绿色环保、高效节能等优点而备受关注。在众多磁相变合金材料中,人们对Mn_2Sb基亚铁磁相变合金研究甚少。文章研究了Cr取代Mn后亚铁磁性Mn_(2-x)Cr_xSb_(0.95)In_(0.05)(x=0.05,0.09,0.13)合金的磁性和磁热性能。室温XRD数据表明合金在室温附近以四角Cu_2Sb型结构为主相。由于反铁磁中有高磁响应,因此从XRD图谱中能观察到少量的铁磁MnSb杂相。随着温度的降低,在这些合金中,发生了亚铁磁到反铁磁的一级磁致弹性转变。同时,在亚铁磁区域观察到两个自旋重新取向转变。由于反铁磁-亚铁磁的转变过程中磁化强度突变,使得在Mn_(1.91)Cr_(0.09)Sb_(0.95)In_(0.05)合金中在0~10 k Oe的磁场变化中获得高达1.63 J/kg·K的大磁熵变。目前的研究可能有助于研究和开发新的磁性冷材料。
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50701022,51001019,and 50831006)the Program for New Century Excellent Talents of China (Grant No. NCET-08-0278)
文摘We have investigated the magnetic transition and magnetocaloric effects of Mn1＋xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn （x = 0.11） gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.
基金Project supported by the National Basic Research Program of China (Grant No. 2005CB623605)the National Natural Science Foundation of China (Grant Nos. 50701022 and 50831006)the Program for New Century Excellent Talents of China (Grant No. NCET-08-0278)
文摘This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co Sn ribbons. The experimental results show that the reverse martensitic transformation temperature TM increases with the increasing pre-pressure, suggesting that pre-deformation is another effective way to adjust TM in ferromagnetic shape memory alloys. Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well. It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn Co-Sn ribbons.
基金the National Basic Research Program of China(Grant No.2012CB932304)the National Natural Science Foundation of China(Grant No.U1232210)
文摘Ferromagnetic shape memory alloys, which undergo the martensitic transformation, are famous multifunctional materials. They exhibit many interesting magnetic properties around the martensitic transformation temperature due to the strong coupling between magnetism and structure. Tuning magnetic phase transition and optimizing the magnetic effects in these alloys are of great importance. In this paper, the regulation of martensitic transformation and the investigation of some related magnetic effects in Ni–Mn-based alloys are reviewed based on our recent research results.
基金Project supported by the National Natural Science Foundation of China (Grant No 0611054000)
文摘The spontaneous magnetization of the Ho^3＋ ion in holmium iron garnet （HoIG） single crystals in the temperature range of 4.2-294K along the directions [111], [110], and [100] are calculated, taking into account the effects of six magnetically inequivalent sites occupied by the Ho^3＋ ions based on the quantum theory. The calculated results show that the magnetization of the Ho^3＋ ion in HoIG is obviously anisotropic. The theoretical results ave in agreement with those of experiments. A primary interpretation of the anisotropy of magnetization of the Ho^3＋ ion in HoIG is put forward.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11875149, 11874127, 52061014, and 61565007)the Youth Jing-gang Scholars Program of Jiangxi Province, Chinathe Program of Qing-jiang Excellent Young Talents, Jiangxi University of Science and Technology
文摘Topological superfluid state is different from the normal superfluid one due to the excitation energy gap on the boundary.How to obtain the topological superfluid state by using spin-orbit coupling to control the s-waves paired mass-imbalanced Fermi gas is a recent novel topic.In this paper,we study the topological superfluid phase diagram of two-dimensional mass-imbalanced Fermi gas with Rashba spin-orbit coupling at zero temperature.We find that due to the competition among mass imbalance,pairing interaction and spin-orbit coupling,there is a double-well structure in the thermodynamic potential,which affects the properties of the ground state of the system.We comprehensively give the phase diagrams of the system on the plane of spin-orbit coupling and chemical potential,and the phase diagrams on the plane of the reduced mass ratio and two-body binding energy.This study not only points out the stable region of topolog-ical superfluid state of mass-imbalanced Fermi gas,but also provides a detailed theoretical basis for better observation of topological superfluid state in experiments.
基金Project supported by the State Key Program for Basic Research of China (Grant No. 2005CB623605)the National Natural Science Foundation of China (Grant Nos. 50701022 and 50831006)the Program for New Century Excellent Talents of China(Grant No. NCET-08-0278)
文摘The magneto-transport properties are investigated in metamagnetic CoMnSi0.ssGe0.12 alloy. By applying a magnetic field or increasing temperature, a metamagnetic phase transition from antiferromagnetic to ferromagnetic is observed in this alloy. Around the metamagnetic phase transition, CoMnSi0.88Ge0.12 alloy exhibits a large and negative magnetoresistance effect （-32%） under a magnetic field of 20 kOe （1Oe = 79.5775 A/m）, which is ascribed to the spin-dependent scattering of conduction electrons.
文摘以放电等离子烧结(SPS)磁体为前驱烧结磁体,通过热变形制备了纳米晶各向异性磁体。研究了变形速率对磁体微观结构和性能的影响。研究发现,对于不同的应变速率,SPS磁体中不同区域的微观结构显示了不同的热变形行为。较大的晶粒尺寸不利于通过热变形制备各向异性Nd Fe B磁体。在不添加重稀土元素和较低稀土含量的情况下,制备出具有良好磁性能(Jr=1.35 T、jHc=829 k A/m和(BH)max=336 k J/m3)和较低矫顽力温度系数(β=–0.682%K-1)的纳米晶热变形磁体。
