The composition of fluid inclusions(FI)often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock.Influence on composition and carbon isotopic composition of gas during primary migratio...The composition of fluid inclusions(FI)often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock.Influence on composition and carbon isotopic composition of gas during primary migration,reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin.The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane.Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in FIs.Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.展开更多
The composition characteristics of light hydrocarbons from crude oil,chloroform bitumen A,saturated hydrocarbon fraction,aromatic hydrocarbon fraction,and asphaltene fraction during cracking have been studied systemat...The composition characteristics of light hydrocarbons from crude oil,chloroform bitumen A,saturated hydrocarbon fraction,aromatic hydrocarbon fraction,and asphaltene fraction during cracking have been studied systematically. The results revealed that the content of n-alkanes,branched alkanes and cycloalkanes in light hydrocarbons from the samples gradually decreased as the simulation temperature increased,and finally almost depleted completely,while the abundance of methane,benzene and its homologues increased obviously and became the main products. The ratios of benzene/n-hexane and toluene/n-heptane can be used as measures for oil cracking levels. Variation characteristics of maturity parameters of light hydrocarbons,for example,iC4/nC4,iC5/nC5,isoheptane value,2,2-DMC4/nC6,and 2-MC6+3-MC6/nC7 for different samples with increasing pyrolysis temperature,are consistent with those in petroleum reservoirs,indicating that these parameters may be efficient maturity index.展开更多
In the processes of discrimination between oil-cracked gases and kerogen-cracked gases,Behar and Pinzgofer et al.'s results were adopted in the former researches,in which the ratio of C2/C3 is basically a constant...In the processes of discrimination between oil-cracked gases and kerogen-cracked gases,Behar and Pinzgofer et al.'s results were adopted in the former researches,in which the ratio of C2/C3 is basically a constant while the ratio of C1/C2 gradually increases in the course of primary cracking of kerogen. Otherwise in the course of secondary cracking of oil,the ratio of C2/C3 increases rapidly while C1/C2 keeps relatively stable. Our study on analogue experiment shows that,whether it is oil or kerogen,in its process of gas generating by cracking,the ratios of C2/C3,C1/C2 or C1/C3 will all be increased with the growth of thermal conditions. In comparison,the ratio of C2/C3,which is affected by genetic type to some comparatively less extent,mainly responds to the maturity of gases,while the value of C2/C3 is about 2,and that of C2/iC4 is about 10,and the corresponding value of Ro is about 1.5%―1.6%. The influence of gas source on C2/C3 is less than that of gas maturity,otherwise C1/C2(or C1/C3) is obviously affected by cracking matrices. The ratios of C1/C2,C1/C3 of oil-cracked gases are less than that of kerogen-cracked gases,under the condition that the ratios of C2/C3 are similar in value,so are the value of dryness indexes. There exists wide diffidence between this view and the former discrimination method in theory. The analysis of the spot sample indicates that we can apply the above basic view to dealing efficiently with the problem of the discrimination between oil-cracked gas and kerogen-cracked gas.展开更多
基金the Chinese Academy of Sciences(Grant No.KZCX2-110)
文摘The composition of fluid inclusions(FI)often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock.Influence on composition and carbon isotopic composition of gas during primary migration,reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin.The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane.Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in FIs.Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.
基金Supported by the National Natural Science Foundation of China (Grant No. 40573030)the National Key Science and Technology Program of China During the 10th Five-Year Plan Period (Grant No. 2004BA616A02-01-01-03)
文摘The composition characteristics of light hydrocarbons from crude oil,chloroform bitumen A,saturated hydrocarbon fraction,aromatic hydrocarbon fraction,and asphaltene fraction during cracking have been studied systematically. The results revealed that the content of n-alkanes,branched alkanes and cycloalkanes in light hydrocarbons from the samples gradually decreased as the simulation temperature increased,and finally almost depleted completely,while the abundance of methane,benzene and its homologues increased obviously and became the main products. The ratios of benzene/n-hexane and toluene/n-heptane can be used as measures for oil cracking levels. Variation characteristics of maturity parameters of light hydrocarbons,for example,iC4/nC4,iC5/nC5,isoheptane value,2,2-DMC4/nC6,and 2-MC6+3-MC6/nC7 for different samples with increasing pyrolysis temperature,are consistent with those in petroleum reservoirs,indicating that these parameters may be efficient maturity index.
基金Supported by the National Key Science and Technology Program of China during the 10th Five-Year Plan Period (Grant No. 2004BA616A02-01-01-03)
文摘In the processes of discrimination between oil-cracked gases and kerogen-cracked gases,Behar and Pinzgofer et al.'s results were adopted in the former researches,in which the ratio of C2/C3 is basically a constant while the ratio of C1/C2 gradually increases in the course of primary cracking of kerogen. Otherwise in the course of secondary cracking of oil,the ratio of C2/C3 increases rapidly while C1/C2 keeps relatively stable. Our study on analogue experiment shows that,whether it is oil or kerogen,in its process of gas generating by cracking,the ratios of C2/C3,C1/C2 or C1/C3 will all be increased with the growth of thermal conditions. In comparison,the ratio of C2/C3,which is affected by genetic type to some comparatively less extent,mainly responds to the maturity of gases,while the value of C2/C3 is about 2,and that of C2/iC4 is about 10,and the corresponding value of Ro is about 1.5%―1.6%. The influence of gas source on C2/C3 is less than that of gas maturity,otherwise C1/C2(or C1/C3) is obviously affected by cracking matrices. The ratios of C1/C2,C1/C3 of oil-cracked gases are less than that of kerogen-cracked gases,under the condition that the ratios of C2/C3 are similar in value,so are the value of dryness indexes. There exists wide diffidence between this view and the former discrimination method in theory. The analysis of the spot sample indicates that we can apply the above basic view to dealing efficiently with the problem of the discrimination between oil-cracked gas and kerogen-cracked gas.
