Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiomet...Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.展开更多
A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their in...A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their influence on total nutrient concentrations of coal mine spoil during early phase of plantation establishment. Soil samples were analyzed for total organic carbon （SOC）, Kjeldahl nitrogen （TKN） and phosphorus （TP） at spoil depths of 0-10 and 10-20 cm under 4- and 5-year-old plantations of all species. A significant effect on concentrations of total SOC, TKN and TP were observed due to plantation age, species and soil depth. However, corresponding con- centrations （SOC, TKN and TP） were substantially lower at spoil profile of 10-20 cm. In comparison, plantation ofA. lebbeck showed greater SOC and nutrient concentrations followed by D. strictus, A. procera and T. grandis, respectively. Therefore, present study clearly indicates attributing qualities of plantation towards improving redeveloping soil of mine spoil varied with species.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 40571130)the Natural Science Foundation of Shanghai, China (No. 07ZR14032)
文摘Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.
文摘A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their influence on total nutrient concentrations of coal mine spoil during early phase of plantation establishment. Soil samples were analyzed for total organic carbon （SOC）, Kjeldahl nitrogen （TKN） and phosphorus （TP） at spoil depths of 0-10 and 10-20 cm under 4- and 5-year-old plantations of all species. A significant effect on concentrations of total SOC, TKN and TP were observed due to plantation age, species and soil depth. However, corresponding con- centrations （SOC, TKN and TP） were substantially lower at spoil profile of 10-20 cm. In comparison, plantation ofA. lebbeck showed greater SOC and nutrient concentrations followed by D. strictus, A. procera and T. grandis, respectively. Therefore, present study clearly indicates attributing qualities of plantation towards improving redeveloping soil of mine spoil varied with species.
