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Optical properties of phosphate glasses co-doped with Yb^(3+) and silver nanoparticles
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作者 M.A.Vallejo H. M.A.Martinez G. +1 位作者 a.v.kiryanov J.L.Lucio M. 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第12期249-253,共5页
We report the fabrication and spectroscopic characterization of Yb^3+-doped phosphate glass, also containing silver nitrate. Scanning electron microscopy(SEM) provides the evidence of the formation of silver nano-p... We report the fabrication and spectroscopic characterization of Yb^3+-doped phosphate glass, also containing silver nitrate. Scanning electron microscopy(SEM) provides the evidence of the formation of silver nano-particles(SNPs), which are formed as a consequence of melting and thermal decomposition of Ag NO3. Absorption spectra of the samples in the visible-to-near-infrared spectral range reveal the presence of bands centered at 410 nm associated with the SNP-plasmon resonance, and at 976 nm due to the Yb^3+. Under 916-nm laser-diode pumping, the effect of the SNP reflects that: i) the fluorescence in the 950-nm–1150-nm spectral range is strongly enhanced(~ 30 times), while the fluorescence decay time associated with the ^2F5/2→^2F7/2transition of Yb^3+ increases 25%, and ii) the basic lasing properties(saturation pumping intensity, the emission and absorption cross sections) are substantially improved. 展开更多
关键词 rare earths phosphate glasses silver nanoparticles
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