Sorption by soil organic matter(SOM)is considered the most important process affecting the bioavailability of hydrophobic organic chemicals(HOCs)in soil.The sorption capacity of SOM for HOCs is affected by many enviro...Sorption by soil organic matter(SOM)is considered the most important process affecting the bioavailability of hydrophobic organic chemicals(HOCs)in soil.The sorption capacity of SOM for HOCs is affected by many environmental factors.In this study,we investigated the effects of soil pH and water saturation level on HOC sorption capacity of SOM using batch sorption experiments.Values of soil organic carbon-water partition coefficient(K_(OC))of six selected polycyclic aromatic hydrocarbons(PAHs)were measured in an artificial soil under various soil pH and water saturation conditions.Passive sampling was used to measure K_(OC)with polydimethylsiloxane as the sampling material.Regardless of soil pH,K_(OC)increased with increasing soil water saturation level for lower-molecular-weight PAHs.In contrast,K_(OC)decreased with increasing soil water saturation level for higher-molecular-weight PAHs.Despite some fluctuations,K_(OC)tended to decrease with increasing soil pH at all water saturation levels.This indicates that earlier studies on the effects of soil pH on K_(OC)under saturated conditions could be extended to unsaturated soils.These K_(OC)tendencies were reproduced in three different natural soils,suggesting that the effects of soil water saturation level and pH might be generalized,at least for PAHs.The PAH sorption capacity of SOM was found to be resilient under dynamic soil pH conditions,which can be used to adjust the effects of soil pH.展开更多
Reactivity of chlorine towards hydrophobic groups present in natural organic matter(NOM)provokes the formation of carcinogenic disinfection byproducts such as trihalomethanes in chlorinated water. The present study ...Reactivity of chlorine towards hydrophobic groups present in natural organic matter(NOM)provokes the formation of carcinogenic disinfection byproducts such as trihalomethanes in chlorinated water. The present study aimed to investigate the variations in coagulant activity of alum using two different bioflocculants(coagulant aid) namely, Moringa oleifera and Cyamopsis tetragonoloba for the removal of hydrophobic fractions of NOM and subsequent chlorine consumption by treated water. Effect of dual coagulants on trihalomethane surrogate parameters such as total organic carbon, dissolved organic carbon, UV absorbing materials and prominent hydrophobic species such as phenolic groups along with aromatic chromophores, polyhydroxy aromatic moiety have also been studied. The concept of differential spectroscopy and absorbance slope index has been employed to understand the combined effects of alum-bioflocculants on the reactivity of NOM with chlorine. Our result shows that the combination of alum and C. tetragonoloba is more efficient for reducing trihalomethane surrogates from chlorinated water as compared to M. oleifera. C. tetragonoloba elicited synchronized effects of sweep coagulation and particle bridging-adsorption which eventually facilitated efficient removal of hydrophobic fractions of NOM. The variation in the mechanistic approach of bioflocculants was due to the presence of cationic charge on M. oleifera and adhesive property of C. tetragonoloba.展开更多
基金supported by the Subsurface Environment Management Projects funded by the Korea Environmental Industry and Technology Institute,Korea(No.2020002440005)。
文摘Sorption by soil organic matter(SOM)is considered the most important process affecting the bioavailability of hydrophobic organic chemicals(HOCs)in soil.The sorption capacity of SOM for HOCs is affected by many environmental factors.In this study,we investigated the effects of soil pH and water saturation level on HOC sorption capacity of SOM using batch sorption experiments.Values of soil organic carbon-water partition coefficient(K_(OC))of six selected polycyclic aromatic hydrocarbons(PAHs)were measured in an artificial soil under various soil pH and water saturation conditions.Passive sampling was used to measure K_(OC)with polydimethylsiloxane as the sampling material.Regardless of soil pH,K_(OC)increased with increasing soil water saturation level for lower-molecular-weight PAHs.In contrast,K_(OC)decreased with increasing soil water saturation level for higher-molecular-weight PAHs.Despite some fluctuations,K_(OC)tended to decrease with increasing soil pH at all water saturation levels.This indicates that earlier studies on the effects of soil pH on K_(OC)under saturated conditions could be extended to unsaturated soils.These K_(OC)tendencies were reproduced in three different natural soils,suggesting that the effects of soil water saturation level and pH might be generalized,at least for PAHs.The PAH sorption capacity of SOM was found to be resilient under dynamic soil pH conditions,which can be used to adjust the effects of soil pH.
基金Science and Engineering Research Board (SERB), Department of Science and Technology (DST), Government of India for the financial support received for research project (SR/S3/CEE/0004/2013)Department of Environmental Science and Engineering, Indian Institute of Technology (ISM) Dhanbad
文摘Reactivity of chlorine towards hydrophobic groups present in natural organic matter(NOM)provokes the formation of carcinogenic disinfection byproducts such as trihalomethanes in chlorinated water. The present study aimed to investigate the variations in coagulant activity of alum using two different bioflocculants(coagulant aid) namely, Moringa oleifera and Cyamopsis tetragonoloba for the removal of hydrophobic fractions of NOM and subsequent chlorine consumption by treated water. Effect of dual coagulants on trihalomethane surrogate parameters such as total organic carbon, dissolved organic carbon, UV absorbing materials and prominent hydrophobic species such as phenolic groups along with aromatic chromophores, polyhydroxy aromatic moiety have also been studied. The concept of differential spectroscopy and absorbance slope index has been employed to understand the combined effects of alum-bioflocculants on the reactivity of NOM with chlorine. Our result shows that the combination of alum and C. tetragonoloba is more efficient for reducing trihalomethane surrogates from chlorinated water as compared to M. oleifera. C. tetragonoloba elicited synchronized effects of sweep coagulation and particle bridging-adsorption which eventually facilitated efficient removal of hydrophobic fractions of NOM. The variation in the mechanistic approach of bioflocculants was due to the presence of cationic charge on M. oleifera and adhesive property of C. tetragonoloba.