We report a series of highly stable metallophthalocyanine-based covalent organic frameworks(MPc-dxCOFs) linked by robust 1,4-dioxin bonds constructed through nucleophilic aromatic substitution(SNAr)reaction. The chemi...We report a series of highly stable metallophthalocyanine-based covalent organic frameworks(MPc-dxCOFs) linked by robust 1,4-dioxin bonds constructed through nucleophilic aromatic substitution(SNAr)reaction. The chemical structures and crystallinity of the COFs largely remain unchanged even after treating with boiling water(90°C), concentrated acids(12 mol/L HCl) or bases(12 mol/L Na OH), oxidizing(30% H_(2)O_(2)) or reducing agents(1 mol/L NaBH;) for three days due to their stable M-Pc building blocks and resilient dioxin linkers. With metallated phthalocyanine active sites regularly arranged in the stable framework structures, MPc-dx-COFs can be directly used as efficient electrocatalysts for the oxygen reduction reaction(ORR) without pyrolysis treatment that has commonly been used in previous studies.展开更多
基金supported by University of Colorado Boulder and K. C. Wong Education Foundationfinancial support by the Koch Graduate fellowship。
文摘We report a series of highly stable metallophthalocyanine-based covalent organic frameworks(MPc-dxCOFs) linked by robust 1,4-dioxin bonds constructed through nucleophilic aromatic substitution(SNAr)reaction. The chemical structures and crystallinity of the COFs largely remain unchanged even after treating with boiling water(90°C), concentrated acids(12 mol/L HCl) or bases(12 mol/L Na OH), oxidizing(30% H_(2)O_(2)) or reducing agents(1 mol/L NaBH;) for three days due to their stable M-Pc building blocks and resilient dioxin linkers. With metallated phthalocyanine active sites regularly arranged in the stable framework structures, MPc-dx-COFs can be directly used as efficient electrocatalysts for the oxygen reduction reaction(ORR) without pyrolysis treatment that has commonly been used in previous studies.
