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Platinium Nanoparticles Deposited on Oxygen-Containing Functional Groups at Carbon Vulcane XC-72 as a Cathode Catalyst for Direct Methanol Fuel Cell
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作者 Sajjad Sadaghat Sharehjini ahmad nozad golikand Mohammad Yari 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期840-,共1页
1 Results Surface oxidized carbon vulcane XC-72 as catalyst support, prepared by chemically anchoring Pt onto the surface modified carbon vulcane XC-72. The nanoparticles of Pt are synthesized by reduction of H2PtCl6 ... 1 Results Surface oxidized carbon vulcane XC-72 as catalyst support, prepared by chemically anchoring Pt onto the surface modified carbon vulcane XC-72. The nanoparticles of Pt are synthesized by reduction of H2PtCl6 with sodium borohydride in a 5.5 buffer solution of sodium citrate, the complexation of citrate with metal ions is beneficial to the formation of nanoparticles. For comparison, an electrode is prepared by E-Tek Pt/C 20 Wt% with a typical Pt loading of 50 μg·cm-2, that shows higher specifi... 展开更多
关键词 modified carbon vulcane XC-72 Pt nanoparticles fuel cell methanol electro-oxidation
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New Synthesis of Pt-Ru Nanoparticles on Surface Modified Carbon Vulcane XC-72 as an Effective Catalyst for Direct Methanol Fuel Cell
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作者 ahmad nozad golikand Sajjad Sadaghat Sharehjini Mohammad Yari 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期827-,共1页
1 Results Pt-Ru nanoparticles are synthesised on the surface oxidized carbon Vulcane XC-72 as catalyst support by chemically anchoring Pt and Ru onto the surface of modified carbon vulcane XC-72 (by refluxing in 70% H... 1 Results Pt-Ru nanoparticles are synthesised on the surface oxidized carbon Vulcane XC-72 as catalyst support by chemically anchoring Pt and Ru onto the surface of modified carbon vulcane XC-72 (by refluxing in 70% HNO3 at 120 ℃ for 12 h to introduce surface functional groups) .The nanoparticles of Pt and Ru are synthesized by reduction of H2PtCl6 and K4Ru(CN)6 with sodium borohydride in a 5.5 buffer solution of sodium citrate,the complexation of citrate with metal ions is beneficial to the formati... 展开更多
关键词 carbon vulcane XC-72 Pt-Ru nanoparticles fuel cell methanol electro-oxidation
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