Based on the Mg^(2+)complexation with acid chrome blue K(ACBK)at pH 10.2,an automatic system was designed to determine total hardness of water.The system consists of a vector colorimeter,a multi-channel sampling pump ...Based on the Mg^(2+)complexation with acid chrome blue K(ACBK)at pH 10.2,an automatic system was designed to determine total hardness of water.The system consists of a vector colorimeter,a multi-channel sampling pump and both reagents A and B.Two kinds of reagent solutions were prepared and used in this system,i.e.,ammoniacal buffer and ACBK—disodium magnesium EDTA solutions.The experimental results of the standard solutions containing 2 and 3 mg/L of total hardness showed that the relative standard deviations(RSDs)were 1.9%and 2.2%,respectively,and the limit of detection(LOD)was only 0.035 mg/L.The detection of four natural water samples showed that the recoveries were between 85.0%and 108.6%,consistent with those obtained by ICP-AES method.展开更多
基金supported by both the Foundation(PCRRK21005)of State Key Laboratory of Pollution Control and Resource Reuse(Tongji University)The National Key Research and Development Program of China(2019YFC1805300)
文摘Based on the Mg^(2+)complexation with acid chrome blue K(ACBK)at pH 10.2,an automatic system was designed to determine total hardness of water.The system consists of a vector colorimeter,a multi-channel sampling pump and both reagents A and B.Two kinds of reagent solutions were prepared and used in this system,i.e.,ammoniacal buffer and ACBK—disodium magnesium EDTA solutions.The experimental results of the standard solutions containing 2 and 3 mg/L of total hardness showed that the relative standard deviations(RSDs)were 1.9%and 2.2%,respectively,and the limit of detection(LOD)was only 0.035 mg/L.The detection of four natural water samples showed that the recoveries were between 85.0%and 108.6%,consistent with those obtained by ICP-AES method.
