This study assesses the performance of temperature extremes over China in two regional climate models(RCMs),RegCM4 and WRF, driven by the ECMWF's 20 th century reanalysis. Based on the advice of the Expert Team on...This study assesses the performance of temperature extremes over China in two regional climate models(RCMs),RegCM4 and WRF, driven by the ECMWF's 20 th century reanalysis. Based on the advice of the Expert Team on Climate Change Detection and Indices(ETCCDI), 12 extreme temperature indices(i.e., TXx, TXn, TNx, TNn, TX90 p, TN90 p,TX10 p, TN10 p WSDI, ID, FD, and CSDI) are derived from the simulations of two RCMs and compared with those from the daily station-based observational data for the period 1981–2010. Overall, the two RCMs demonstrate satisfactory capability in representing the spatiotemporal distribution of the extreme indices over most regions. RegCM performs better than WRF in reproducing the mean temperature extremes, especially over the Tibetan Plateau(TP). Moreover, both models capture well the decreasing trends in ID, FD, CSDI, TX10 p, and TN10 p, and the increasing trends in TXx, TXn, TNx, TNn, WSDI, TX90 p,and TN90 p, over China. Compared with observation, RegCM tends to underestimate the trends of temperature extremes,while WRF tends to overestimate them over the TP. For instance, the linear trends of TXx over the TP from observation,RegCM, and WRF are 0.53?C(10 yr)^(-1), 0.44?C(10 yr)^(-1), and 0.75?C(10 yr)^(-1), respectively. However, WRF performs better than RegCM in reproducing the interannual variability of the extreme-temperature indices. Our findings are helpful towards improving our understanding of the physical realism of RCMs in terms of different time scales, thus enabling us in future work to address the sources of model biases.展开更多
Stroke patients with hemiplegia exhibit flexor spasms in the upper limb and extensor spasms in the lower limb, and their movement patterns vary greatly. Constraint-induced movement therapy is an upper limb rehabilitat...Stroke patients with hemiplegia exhibit flexor spasms in the upper limb and extensor spasms in the lower limb, and their movement patterns vary greatly. Constraint-induced movement therapy is an upper limb rehabilitation technique used in stroke patients with hemiplegia; however, studies of lower extremity rehabilitation are scarce. In this study, stroke patients with lower limb hemiplegia underwent conventional Bobath therapy for 4 weeks as baseline treatment, followed by constraint-induced movement therapy for an additional 4 weeks. The 10-m maximum walking speed and Berg balance scale scores significantly improved following treatment, and lower extremity motor function also improved. The results of functional MRI showed that constraint-induced movement therapy alleviates the reduction in cerebral functional activation in patients, which indicates activation of functional brain regions and a significant increase in cerebral blood perfusJon. These results demonstrate that constraint-induced movement therapy promotes brain functional reorganization in stroke patients with lower limb hemiplegia.展开更多
Lower limb exoskeleton robots offer an effective treatment for patients with lower extremity dysfunction.In order to improve the rehabilitation training effect based on the human motion mechanism,this paper proposes a...Lower limb exoskeleton robots offer an effective treatment for patients with lower extremity dysfunction.In order to improve the rehabilitation training effect based on the human motion mechanism,this paper proposes a humanoid sliding mode neural network controller based on the human gait.A humanoid model is constructed based on the human mechanism,and the parameterised gait trajectory is used as target to design the humanoid control system for robots.Considering the imprecision of the robot dynamics model,the neural network is adopted to compensate for the uncertain part of the model and improve the model accuracy.Moreover,the sliding mode control in the system improves the response speed,tracking performance,and stability of the control system.The Lyapunov stability analysis proves the stability of the control system theoretically.Meanwhile,an evaluation method using the similarity function is improved based on joint angle,velocity,and acceleration to evaluate the comfort of humans in rehabilitation training more reasonably.Finally,to verify the effectiveness of the proposed method,simulations are carried out based on experimental data.The results show that the control system could accurately track the target trajectory,of which the robot is highly similar to the human.展开更多
Potential evapotranspiration(EPET)is usually calculated by empirical methods from surface meteorological variables,such as temperature,radiation and wind speed.The in-situ measured pan evaporation(ETpan)can also be us...Potential evapotranspiration(EPET)is usually calculated by empirical methods from surface meteorological variables,such as temperature,radiation and wind speed.The in-situ measured pan evaporation(ETpan)can also be used as a proxy for EPET.In this study,EPET values computed from ten models are compared with observed ETpan data in ten Chinese river basins for the period 1961−2013.The daily observed meteorological variables at 2267 stations are used as the input to those models,and a ranking scheme is applied to rank the statistical quantities(ratio of standard deviations,correlation coefficient,and ratio of trends)between ETpan and modeled EPET in different river basins.There are large deviations between the modeled EPET and the ETpan in both the magnitude and the annual trend at most stations.In eight of the basins(except for Southeast and Southwest China),ETpan shows decreasing trends with magnitudes ranging between−0.01 mm d−1 yr−1 and−0.03 mm d−1 yr−1,while the decreasing trends in modeled EPET are less than−0.01 mm d−1 yr−1.Inter comparisons among different models in different river basins suggest that PETHam1 is the best model in the Pearl River basin,PETHam2 outperforms other models in the Huaihe River,Yangtze River and Yellow River basins,and PETFAO is the best model for the remaining basins.Sensitivity analyses reveal that wind speed and sunshine duration are two important factors for decreasing EPET in most basins except in Southeast and Southwest China.The increasing EPET trend in Southeast China is mainly attributed to the reduced relative humidity.展开更多
It is generally agreed that El Nino can be classified into East Pacific(EP)and Central Pacific(CP)types.Nevertheless,little is known about the relationship between these two types of El Ni?o and land surface climate e...It is generally agreed that El Nino can be classified into East Pacific(EP)and Central Pacific(CP)types.Nevertheless,little is known about the relationship between these two types of El Ni?o and land surface climate elements.This study investigates the linkage between EP/CP El Ni?o and summer streamflow over the Yellow and Yangtze River basins and their possible mechanisms.Over the Yellow River basin,the anomalous streamflow always manifests as positive(negative)in EP(CP)years,with a correlation coefficient of 0.39(-0.37);while over the Yangtze River basin,the anomalous streamflow shows as positive in both EP and CP years,with correlation coefficients of 0.72 and 0.48,respectively.Analyses of the surface hydrological cycle indicate that the streamflow is more influenced by local evapotranspiration(ET)than precipitation over the Yellow River basin,while it is dominantly affected by precipitation over the Yangtze River basin.The different features over these two river basins can be explained by the anomalous atmospheric circulation,which is cyclonic(anticyclonic)north(south)of 30°N over East Asia.EP years are dominated by two anticyclones,which bring strong water vapor convergence and induce more precipitation but less ET,and subsequently increase streamflow and flooding risks.In CP years,especially over the Yellow River basin,two cyclones dominate and lead to water vapor divergence and reduce moisture arriving.Meanwhile,the ET enhances mainly due to local high surface air temperature,which further evaporates water from the soil.As a result,the streamflow decreases,which will then increase the drought risk.展开更多
Land surface temperature(LST)is one of the most important factors in the land-atmosphere interaction process.Raw measured LSTs may contain biases due to instrument replacement,changes in recording procedures,and other...Land surface temperature(LST)is one of the most important factors in the land-atmosphere interaction process.Raw measured LSTs may contain biases due to instrument replacement,changes in recording procedures,and other non-climatic factors.This study attempts to reduce the above biases in raw daily measurements and achieves a homogenized daily LST dataset over China using 2360 stations from 1960 through 2017.The high-quality land surface air temperature(LSAT)dataset is used to correct the LST warming biases especially evident during cold months in regions north of 40ºN due to the replacement of observation instruments around 2004.Subsequently,the Multiple Analysis of Series for Homogenization(MASH)method is adopted to detect and then adjust the daily observed LST records.In total,3.68×10^(3) effective breakpoints in 1.65×106 monthly records(about 20%)are detected.A large number of these effective breakpoints are located over large parts of the Sichuan Basin and southern China.After the MASH procedure,LSTs at more than 80%of the breakpoints are adjusted within+/-0.5℃,and of the remaining breakpoints,only 10%are adjusted over 1.5℃.Compared to the raw LST dataset over the whole domain,the homogenization significantly reduces the mean LST magnitude and its interannual variability as well as its linear trend at most stations.Finally,we perform preliminary analysis upon the homogenized LST and find that the annual mean LST averaged across China shows a significant warming trend[0.22℃(10 yr)^(-1)].The homogenized LST dataset can be further adapted for a variety of applications(e.g.,model evaluation and extreme event characterization).展开更多
Previous studies have demonstrated that offline land surface models(LSMs)and global hydrological models(GHMs)can reasonably reproduce streamflow in large river basins.Global reanalyses supply fine spatiotemporal runof...Previous studies have demonstrated that offline land surface models(LSMs)and global hydrological models(GHMs)can reasonably reproduce streamflow in large river basins.Global reanalyses supply fine spatiotemporal runoff estimates,but they are not fully intercompared and evaluated in China.This study assesses the routed-runoff from five offline LSM/GHM runs(VIC-CN05.1,CLM-CFSR,CLM-ERAI,CLM-MERRA,and CLM-NCEP)and three reanalysis datasets(ERAI/Land,JRA55,and MERRA-2)against the gauged streamflow(26 stations)in major Chinese river basins during 1980–2008.The Catchment-based Macro-scale Floodplain model(CaMa-Flood)is employed to route those runoff datasets to the hydrological stations.Four statistical quantities,including the correlation coefficient(R),standard deviation(STD),Nash–Sutcliffe efficiency coefficient(NSE),and relative error(RE),along with a ranking method,are used to quantify the quality of those products.The results show that the spatial patterns of both modeled and observed streamflow in summer are similar,but their magnitudes are different.Except for MERRA-2,the other products can reproduce well the interannual variability of streamflow in both the Yangtze and Yellow River basins.All products generally underestimate the magnitude and variance of monthly streamflow,while VIC-CN05.1 and JRA55 are closer to observations compared to other products.The correlation coefficients for all products are overall larger than 0.61,with the highest value(0.85)from VIC-CN05.1.In addition to CLM-MERRA,MERRA-2,and CLM-NCEP with relatively small precipitation,other products can simulate peak flow well with positive NSEs up to 0.41(ERAI/Land).Considerable uncertainties exist among the eight products at the Yellow River outlet,which might be because the LSMs ignore frequent human activities.Based on the above statistics,performances of the eight runoff products are ranked in descending order as follows:VIC-CN05.1,ERAI/Land,JRA55,CLM-CFSR,CLM-ERAI,MERRA-2,CLM-MERRA,and CLM-NCEP,which provides a reference for flood/hydrological drought warning and hydroclimatic research in the future.展开更多
Diruthenium ethynyl complexes 1--3 (1: 1,5-dithia-s-indacene-4,8-dione; 2: 4,8-diethoxybenzo[1,2-b:4,5- b']dithiophene; 3: 4,8-didodecyloxybenzo[1,2-b:4,5-b']dithiophene) have been synthesized by incorporatin...Diruthenium ethynyl complexes 1--3 (1: 1,5-dithia-s-indacene-4,8-dione; 2: 4,8-diethoxybenzo[1,2-b:4,5- b']dithiophene; 3: 4,8-didodecyloxybenzo[1,2-b:4,5-b']dithiophene) have been synthesized by incorporating the re- spective conjugated heterocyclic spacer and characterized by NMR and elemental analysis. The effects of bridge ligands' properties on electronic coupling between redox-active ruthenium terminal groups were investigated by electrochemistry, UV/vis/near-IR and IR spectroelectrochemistry combined with density functional theory (DFT) and time-dependent DFT calculations. Electrochemistry results indicated that complexes 1--3 exhibit two fully re- versible oxidation waves, and complexes 2 and 3 with electron-rich and π-conjuagted bridge ligands are character- ized by excellent electrochemical properties. Furthermore, the larger v(C≡C) separation from the IR spectroelec- trochemical results of 2 and 3 and the intense NIR absorption features of singly oxidized species 2+ and 3+ re- vealed that their molecular skeletons have superior abilities to delocalize the positive charge. The spin density dis- tribution from DFT calculations proved the conclusions of this study.展开更多
基金supported by the National Key Technologies R&D Program of China[grant number 2022YFC3002803]the National Science Fund for Distinguished Young Scholars[grant number 41925021].
基金supported by the National Natural Science Fund for Distinguished Young Scholars[41925021]the Key Project of the Ministry of Science and Technology of China[2022YFC3002803].
基金supported by the Key Project of the Ministry of Science and Technology of China(Grant No.2016YFA0602401)National Natural Science Foundation of China(Grant No.41575089)
文摘This study assesses the performance of temperature extremes over China in two regional climate models(RCMs),RegCM4 and WRF, driven by the ECMWF's 20 th century reanalysis. Based on the advice of the Expert Team on Climate Change Detection and Indices(ETCCDI), 12 extreme temperature indices(i.e., TXx, TXn, TNx, TNn, TX90 p, TN90 p,TX10 p, TN10 p WSDI, ID, FD, and CSDI) are derived from the simulations of two RCMs and compared with those from the daily station-based observational data for the period 1981–2010. Overall, the two RCMs demonstrate satisfactory capability in representing the spatiotemporal distribution of the extreme indices over most regions. RegCM performs better than WRF in reproducing the mean temperature extremes, especially over the Tibetan Plateau(TP). Moreover, both models capture well the decreasing trends in ID, FD, CSDI, TX10 p, and TN10 p, and the increasing trends in TXx, TXn, TNx, TNn, WSDI, TX90 p,and TN90 p, over China. Compared with observation, RegCM tends to underestimate the trends of temperature extremes,while WRF tends to overestimate them over the TP. For instance, the linear trends of TXx over the TP from observation,RegCM, and WRF are 0.53?C(10 yr)^(-1), 0.44?C(10 yr)^(-1), and 0.75?C(10 yr)^(-1), respectively. However, WRF performs better than RegCM in reproducing the interannual variability of the extreme-temperature indices. Our findings are helpful towards improving our understanding of the physical realism of RCMs in terms of different time scales, thus enabling us in future work to address the sources of model biases.
文摘Stroke patients with hemiplegia exhibit flexor spasms in the upper limb and extensor spasms in the lower limb, and their movement patterns vary greatly. Constraint-induced movement therapy is an upper limb rehabilitation technique used in stroke patients with hemiplegia; however, studies of lower extremity rehabilitation are scarce. In this study, stroke patients with lower limb hemiplegia underwent conventional Bobath therapy for 4 weeks as baseline treatment, followed by constraint-induced movement therapy for an additional 4 weeks. The 10-m maximum walking speed and Berg balance scale scores significantly improved following treatment, and lower extremity motor function also improved. The results of functional MRI showed that constraint-induced movement therapy alleviates the reduction in cerebral functional activation in patients, which indicates activation of functional brain regions and a significant increase in cerebral blood perfusJon. These results demonstrate that constraint-induced movement therapy promotes brain functional reorganization in stroke patients with lower limb hemiplegia.
基金National Natural Science Foundation of China,Grant/Award Numbers:No.62073297,No.U1813201。
文摘Lower limb exoskeleton robots offer an effective treatment for patients with lower extremity dysfunction.In order to improve the rehabilitation training effect based on the human motion mechanism,this paper proposes a humanoid sliding mode neural network controller based on the human gait.A humanoid model is constructed based on the human mechanism,and the parameterised gait trajectory is used as target to design the humanoid control system for robots.Considering the imprecision of the robot dynamics model,the neural network is adopted to compensate for the uncertain part of the model and improve the model accuracy.Moreover,the sliding mode control in the system improves the response speed,tracking performance,and stability of the control system.The Lyapunov stability analysis proves the stability of the control system theoretically.Meanwhile,an evaluation method using the similarity function is improved based on joint angle,velocity,and acceleration to evaluate the comfort of humans in rehabilitation training more reasonably.Finally,to verify the effectiveness of the proposed method,simulations are carried out based on experimental data.The results show that the control system could accurately track the target trajectory,of which the robot is highly similar to the human.
基金supported by the National Natural Science Foundation of China(Grant No.41875106)the National Key R&D Program of China(Grant No.2016YFA0602401)。
文摘Potential evapotranspiration(EPET)is usually calculated by empirical methods from surface meteorological variables,such as temperature,radiation and wind speed.The in-situ measured pan evaporation(ETpan)can also be used as a proxy for EPET.In this study,EPET values computed from ten models are compared with observed ETpan data in ten Chinese river basins for the period 1961−2013.The daily observed meteorological variables at 2267 stations are used as the input to those models,and a ranking scheme is applied to rank the statistical quantities(ratio of standard deviations,correlation coefficient,and ratio of trends)between ETpan and modeled EPET in different river basins.There are large deviations between the modeled EPET and the ETpan in both the magnitude and the annual trend at most stations.In eight of the basins(except for Southeast and Southwest China),ETpan shows decreasing trends with magnitudes ranging between−0.01 mm d−1 yr−1 and−0.03 mm d−1 yr−1,while the decreasing trends in modeled EPET are less than−0.01 mm d−1 yr−1.Inter comparisons among different models in different river basins suggest that PETHam1 is the best model in the Pearl River basin,PETHam2 outperforms other models in the Huaihe River,Yangtze River and Yellow River basins,and PETFAO is the best model for the remaining basins.Sensitivity analyses reveal that wind speed and sunshine duration are two important factors for decreasing EPET in most basins except in Southeast and Southwest China.The increasing EPET trend in Southeast China is mainly attributed to the reduced relative humidity.
基金the Key Project of the Ministry of Science and Technology of China (Grant No. 2016YFA0602401)the National Natural Science Foundation of China (Grant No. 41875106)
文摘It is generally agreed that El Nino can be classified into East Pacific(EP)and Central Pacific(CP)types.Nevertheless,little is known about the relationship between these two types of El Ni?o and land surface climate elements.This study investigates the linkage between EP/CP El Ni?o and summer streamflow over the Yellow and Yangtze River basins and their possible mechanisms.Over the Yellow River basin,the anomalous streamflow always manifests as positive(negative)in EP(CP)years,with a correlation coefficient of 0.39(-0.37);while over the Yangtze River basin,the anomalous streamflow shows as positive in both EP and CP years,with correlation coefficients of 0.72 and 0.48,respectively.Analyses of the surface hydrological cycle indicate that the streamflow is more influenced by local evapotranspiration(ET)than precipitation over the Yellow River basin,while it is dominantly affected by precipitation over the Yangtze River basin.The different features over these two river basins can be explained by the anomalous atmospheric circulation,which is cyclonic(anticyclonic)north(south)of 30°N over East Asia.EP years are dominated by two anticyclones,which bring strong water vapor convergence and induce more precipitation but less ET,and subsequently increase streamflow and flooding risks.In CP years,especially over the Yellow River basin,two cyclones dominate and lead to water vapor divergence and reduce moisture arriving.Meanwhile,the ET enhances mainly due to local high surface air temperature,which further evaporates water from the soil.As a result,the streamflow decreases,which will then increase the drought risk.
基金This work was supported by the National Science Fund for Distinguished Young Scholars(Grant No.41925021)the National Natural Science Foundation of China(Grant No.41875106).
文摘Land surface temperature(LST)is one of the most important factors in the land-atmosphere interaction process.Raw measured LSTs may contain biases due to instrument replacement,changes in recording procedures,and other non-climatic factors.This study attempts to reduce the above biases in raw daily measurements and achieves a homogenized daily LST dataset over China using 2360 stations from 1960 through 2017.The high-quality land surface air temperature(LSAT)dataset is used to correct the LST warming biases especially evident during cold months in regions north of 40ºN due to the replacement of observation instruments around 2004.Subsequently,the Multiple Analysis of Series for Homogenization(MASH)method is adopted to detect and then adjust the daily observed LST records.In total,3.68×10^(3) effective breakpoints in 1.65×106 monthly records(about 20%)are detected.A large number of these effective breakpoints are located over large parts of the Sichuan Basin and southern China.After the MASH procedure,LSTs at more than 80%of the breakpoints are adjusted within+/-0.5℃,and of the remaining breakpoints,only 10%are adjusted over 1.5℃.Compared to the raw LST dataset over the whole domain,the homogenization significantly reduces the mean LST magnitude and its interannual variability as well as its linear trend at most stations.Finally,we perform preliminary analysis upon the homogenized LST and find that the annual mean LST averaged across China shows a significant warming trend[0.22℃(10 yr)^(-1)].The homogenized LST dataset can be further adapted for a variety of applications(e.g.,model evaluation and extreme event characterization).
基金Supported by the National Key Research and Development Program of China(2016YFA0602401)National Natural Science Foundation of China(41875106).
文摘Previous studies have demonstrated that offline land surface models(LSMs)and global hydrological models(GHMs)can reasonably reproduce streamflow in large river basins.Global reanalyses supply fine spatiotemporal runoff estimates,but they are not fully intercompared and evaluated in China.This study assesses the routed-runoff from five offline LSM/GHM runs(VIC-CN05.1,CLM-CFSR,CLM-ERAI,CLM-MERRA,and CLM-NCEP)and three reanalysis datasets(ERAI/Land,JRA55,and MERRA-2)against the gauged streamflow(26 stations)in major Chinese river basins during 1980–2008.The Catchment-based Macro-scale Floodplain model(CaMa-Flood)is employed to route those runoff datasets to the hydrological stations.Four statistical quantities,including the correlation coefficient(R),standard deviation(STD),Nash–Sutcliffe efficiency coefficient(NSE),and relative error(RE),along with a ranking method,are used to quantify the quality of those products.The results show that the spatial patterns of both modeled and observed streamflow in summer are similar,but their magnitudes are different.Except for MERRA-2,the other products can reproduce well the interannual variability of streamflow in both the Yangtze and Yellow River basins.All products generally underestimate the magnitude and variance of monthly streamflow,while VIC-CN05.1 and JRA55 are closer to observations compared to other products.The correlation coefficients for all products are overall larger than 0.61,with the highest value(0.85)from VIC-CN05.1.In addition to CLM-MERRA,MERRA-2,and CLM-NCEP with relatively small precipitation,other products can simulate peak flow well with positive NSEs up to 0.41(ERAI/Land).Considerable uncertainties exist among the eight products at the Yellow River outlet,which might be because the LSMs ignore frequent human activities.Based on the above statistics,performances of the eight runoff products are ranked in descending order as follows:VIC-CN05.1,ERAI/Land,JRA55,CLM-CFSR,CLM-ERAI,MERRA-2,CLM-MERRA,and CLM-NCEP,which provides a reference for flood/hydrological drought warning and hydroclimatic research in the future.
基金The authors acknowledge financial support from Na- tional Natural Science Foundation of China (No. 21602049) and the Natural Science Foundation of Hu- nan Province, China (No. 2017JJ3004).
文摘Diruthenium ethynyl complexes 1--3 (1: 1,5-dithia-s-indacene-4,8-dione; 2: 4,8-diethoxybenzo[1,2-b:4,5- b']dithiophene; 3: 4,8-didodecyloxybenzo[1,2-b:4,5-b']dithiophene) have been synthesized by incorporating the re- spective conjugated heterocyclic spacer and characterized by NMR and elemental analysis. The effects of bridge ligands' properties on electronic coupling between redox-active ruthenium terminal groups were investigated by electrochemistry, UV/vis/near-IR and IR spectroelectrochemistry combined with density functional theory (DFT) and time-dependent DFT calculations. Electrochemistry results indicated that complexes 1--3 exhibit two fully re- versible oxidation waves, and complexes 2 and 3 with electron-rich and π-conjuagted bridge ligands are character- ized by excellent electrochemical properties. Furthermore, the larger v(C≡C) separation from the IR spectroelec- trochemical results of 2 and 3 and the intense NIR absorption features of singly oxidized species 2+ and 3+ re- vealed that their molecular skeletons have superior abilities to delocalize the positive charge. The spin density dis- tribution from DFT calculations proved the conclusions of this study.