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Dropwise condensation heat transfer enhancement on surfaces micro/nano structured by a two-step electrodeposition process 被引量:4
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作者 Hamid Reza TALESH BAHRAMI alireza azizi Hamid SAFFARI 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第5期1065-1076,共12页
Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two diffe... Condensation is an important regime of heat transfer which has wide applications in different industries such as power plants,heating,ventilating and air conditioning,and refrigeration.Condensation occurs in two different modes including filmwise (FWC) and dropwise (DWC) condensation.DWC occurring on hydrophobic and superhydrophobic surfaces has a much higher heat transfer capacity than FWC.Therefore,wide investigations have been done to produce DWC in recent years.Superhydrophobic surfaces have micro/nano structures with low surface energy.In this study,a two-step electrodeposition process is used to produce micro/nano structures on copper specimens.The surface energy of specimens is reduced by a self-assembled monolayer using ethanol and 1-octadecanethiol solution.The results show that there is an optimum condition for electrodeposition parameters.For example,a surface prepared by 2000 s step time has 5 times greater heat transfer than FWC while a surface with 4000 s step time has nearly the same heat transfer as FWC.The surfaces of the fabricated specimens are examined using XRD and SEM analyses.The SEM analyses of the surfaces show that there are some micro-structures on the surfaces and the surface porosities are reduced by increasing the second step electrodeposition time. 展开更多
关键词 dropwise condensation heat transfer ELECTRODEPOSITION micro/nano structure POROSITY
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超薄蛭石纳米片基人工界面层调控Zn^(2+)离子通量助力高性能锌金属负极
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作者 李建文 周双 +7 位作者 孟欣雨 陈逸宁 傅纯雁 alireza azizi 赵晓光 解维闵 常智 潘安强 《Science Bulletin》 SCIE EI CAS CSCD 2023年第12期1283-1294,M0004,共13页
水系锌离子电池因其成本低、安全性高成为了近年来的研究热点,然而循环过程中的枝晶生长和界面腐蚀等问题严重限制了此类电池的实际应用。本文利用超薄蛭石纳米片(Vermiculite sheets,VS)在锌金属负极表面制备了具有核壳结构的多功能离... 水系锌离子电池因其成本低、安全性高成为了近年来的研究热点,然而循环过程中的枝晶生长和界面腐蚀等问题严重限制了此类电池的实际应用。本文利用超薄蛭石纳米片(Vermiculite sheets,VS)在锌金属负极表面制备了具有核壳结构的多功能离子整流器(Ionrectifier,IRT)人工界面层.其中,疏水性聚偏二氟乙烯(PVDF)外壳能够将H_(2)O从锌负极表面驱离,赋予其优异的抗腐蚀效率(94.8%);VS内核的天然负电层间能够促进Zn^(2+)的迁移动力学(t_(+)=0.79)和密实沉积.结果表明,锌负极的电化学稳定性和沉积一致性大大提高,即使在高电流密度(3mA cm^(-2))下,IRT保护下的锌负极仍能稳定工作1600小时以上,并获得2400mAh cm^(-2)的累积放电容量.同时,利用该人工界面层组装的Zn//NH_(4)V_(4)O_(10)软包电池在1Ag^(-1)下循环150圈后的容量保持率高达94.3%.这种低成本、高效率的负极界面改性策略为水系电池的商业化提供了可能。 展开更多
关键词 锌负极 锌离子电池 电化学稳定性 放电容量 整流器 软包电池 循环过程 锌金属
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