1-{4-[（2-hydroxy-benzylidene）amino]phenyl}ethanone functionalized silica gel was synthesized and used as a highly efficient, selective and reusable solid phase extractant for separation and preconcentration of trace...1-{4-[（2-hydroxy-benzylidene）amino]phenyl}ethanone functionalized silica gel was synthesized and used as a highly efficient, selective and reusable solid phase extractant for separation and preconcentration of trace amount of Zn（II） from environmental matrices. The adsorbent was characterized by fourier transform infrared spectroscopy （FT-IR）, elemental analysis,~3C CPMAS NMR spectroscopy, scanning electron microscopy （SEM）, thermogravimetric analysis （TGA） and BET surface area analysis. The dependence of zinc extraction on various analytical parameters such as pH, type and amount of eluent, sample flow rate and interfering ions were investigated in detail. The material exhibited superior adsorption efficiency for Zn（II） with high metal loading capacity of 1.0 mmol/g under optimum conditions. After adsorption, the recovery （〉 98%） of metal ions was accomplished using 1.0 mol/L HNO3 as an eluent. The sorbent was also regenerated by microwave treatment in milder acidic environment （0.1 mol/L HNO3）. The lower detection limit and preconcentration factor of the present method were found out to be 0.04 ~tg/L and 312.5 respectively. The modified silica surface possessed excellent selectivity for the target analytes and the adsorption/desorption process remained effective for at least ten consecutive cycles. The optimized procedure was successfully implemented for the extraction of Zn（II） from mycorrhizal treated fly ash and pharmaceutical samples with reproducible results.展开更多
文摘1-{4-[（2-hydroxy-benzylidene）amino]phenyl}ethanone functionalized silica gel was synthesized and used as a highly efficient, selective and reusable solid phase extractant for separation and preconcentration of trace amount of Zn（II） from environmental matrices. The adsorbent was characterized by fourier transform infrared spectroscopy （FT-IR）, elemental analysis,~3C CPMAS NMR spectroscopy, scanning electron microscopy （SEM）, thermogravimetric analysis （TGA） and BET surface area analysis. The dependence of zinc extraction on various analytical parameters such as pH, type and amount of eluent, sample flow rate and interfering ions were investigated in detail. The material exhibited superior adsorption efficiency for Zn（II） with high metal loading capacity of 1.0 mmol/g under optimum conditions. After adsorption, the recovery （〉 98%） of metal ions was accomplished using 1.0 mol/L HNO3 as an eluent. The sorbent was also regenerated by microwave treatment in milder acidic environment （0.1 mol/L HNO3）. The lower detection limit and preconcentration factor of the present method were found out to be 0.04 ~tg/L and 312.5 respectively. The modified silica surface possessed excellent selectivity for the target analytes and the adsorption/desorption process remained effective for at least ten consecutive cycles. The optimized procedure was successfully implemented for the extraction of Zn（II） from mycorrhizal treated fly ash and pharmaceutical samples with reproducible results.
