A series of polyurethane elastomers (PUEs) were synthesized by using β-cyclodextrin (β-CD) as cross-linker from aliphatic, alicyclic, aromatic diisocyanates, and polyol. The PUEs were characterized by Fourier Transf...A series of polyurethane elastomers (PUEs) were synthesized by using β-cyclodextrin (β-CD) as cross-linker from aliphatic, alicyclic, aromatic diisocyanates, and polyol. The PUEs were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA), swelling test, hardness test and tensile test. The influence of diisocyanate on microphase separation and properties of PUEs was evaluated.展开更多
A series of PUEs which use β-CD as cross-linker were synthesized. Nanoindentation measurements of mechanical properties of these PUEs were made. Load and depth sensing indentation and nano DMA mode were used to evalu...A series of PUEs which use β-CD as cross-linker were synthesized. Nanoindentation measurements of mechanical properties of these PUEs were made. Load and depth sensing indentation and nano DMA mode were used to evaluate mechanical properties of PUEs in nano-scale. The difference between the results from two modes proved the microphase separation in PUEs and to investigate PUE from hard domains and soft domains was of great significance.展开更多
Objective To evaluate the feasibility of using gadopentetate dimeglumine(Gd-DTPA)for dual-energy computed tomography pulmonary angiography(CTPA).Methods Sixty-six patients were randomly divided into three groups and u...Objective To evaluate the feasibility of using gadopentetate dimeglumine(Gd-DTPA)for dual-energy computed tomography pulmonary angiography(CTPA).Methods Sixty-six patients were randomly divided into three groups and underwent CTPA.Group A had a turbo flash scan using an iohexol injection,Group B had a turbo flash scan using Gd-DTPA,and Group C had a dual-energy scan using Gd-DTPA.The original images of Group C were linearly blended with a blending factor of 0.5 or reconstructed at 40,50,60,70,80,90,100,and 110 keV,respectively.The groups were compared in terms of pulmonary artery CT value,image quality,and radiation dose.Results The pulmonary artery CT values were significantly higher in Group C40keV than in Groups B and C,but lower than in Group A.There was no significant difference in the image noise of Groups C40keV,B,and C.Moreover,Group A had the largest beam hardening artifacts of the superior vena cava(SVC),followed by Groups B and C.Group C40keV showed better vascular branching than the other three groups,among which Group B was superior to Group A.The subjective score of the image quality of Groups A,B,and C showed no significant difference,but the score was significantly higher in Group C40keV than in Groups A and B.The radiation dose was significantly lower in Group B than in Groups A and C.Conclusion Gd-CTPA is recommended to patients who are unsuitable for receiving an iodine-based CTPA.Furthermore,a turbo flash scan could surpass a dual-energy scan without consideration for virtual monoenergetic imaging.展开更多
A series of polyurethane elastomers (PUEs) were synthesized from an aromatic diisocyanate (4, 4’-diphenylmethane diisocyanate);a polyether polyol (polytetramethylene glycol, molecular weight: 1000), polyester polyol ...A series of polyurethane elastomers (PUEs) were synthesized from an aromatic diisocyanate (4, 4’-diphenylmethane diisocyanate);a polyether polyol (polytetramethylene glycol, molecular weight: 1000), polyester polyol (poly-caprolactonediol, molecular weight: 1000, or polycarbonate diol, molecular weight: 1000);and β-cyclodextrin (β-CD) as a cross-linker. The effect of the polyol on the morphologies and chemical, thermal, and mechanical properties of the resultant β-CD-based PUEs were investigated in this study. The obtained films were characterized via solubility and swelling tests (chemical properties), differential scanning calorimetry (crystallinity degree), dynamic mechanical analysis (thermal stability), thermogravimetric analysis (thermal stability), tensile testing (mechanical properties), nuclear magnetic resonance spectroscopy, infrared spectroscopy, atomic force microscopy (morphology), contact angle determination (morphology), and scanning electron microscopy (morphology).展开更多
This paper mainly studies the contact extension of conservative or dissipative systems, including some old and new results for wholeness. Then extension of contact system is corresponding to the symplectification of c...This paper mainly studies the contact extension of conservative or dissipative systems, including some old and new results for wholeness. Then extension of contact system is corresponding to the symplectification of contact Hamiltonian system. This is a reciprocal process and the relation between symplectic system and contact system has been discussed. We have an interesting discovery that by adding a pure variable p,the slope of the tangent of the orbit, every differential system can be regarded as an independent subsystem of contact Hamiltonian system defined on the projection space of contact phase space.展开更多
Based on a hydrothermal method, the Ce3+/Tb3+ co-doped Ba Gd F5 nanocrystals were synthesized by controlling the introduction concentration of Ba2+ and Gd3+. The samples were characterized by X-ray diffraction(XRD), f...Based on a hydrothermal method, the Ce3+/Tb3+ co-doped Ba Gd F5 nanocrystals were synthesized by controlling the introduction concentration of Ba2+ and Gd3+. The samples were characterized by X-ray diffraction(XRD), field emission scanning electron microscopy(FESEM) images, photoluminescence(PL) excitation, and emission spectra, as well as the photoluminescence dynamic decay curves. With the increase of the Ba2+ concentration in the synthesis procedure, the positions of diffraction peaks of XRD patterns move toward lower degree, and the case of the samples synthesized with the increase of the Gd3+ concentration is contrary, which consists well with each other. The FE-SEM images suggest that the BaGdF5 nanocrystals are in spherical morphology,and the average diameters decrease with the increase of Ba2+ or Gd3+ concentration. For the 4f–5d transition of Ce3+ is sensitive to the environment of local lattice, the PL excitation and emission spectra of the samples are different. The 4f–4f transition of Tb3+ also presents different optical properties in different host lattices. The variations of the optical properties of Ce3+ and Tb3+ as well as the lifetime of the 5D4+7F5 emission of Tb3+ are also consistent well with each other in the two series of samples.展开更多
In general, inorganic filler/polyurethane elastomer(PUE) composites possess favorable properties, such as modulus, chemical resistance, and heat stability, are promising for broadening the application area of polyuret...In general, inorganic filler/polyurethane elastomer(PUE) composites possess favorable properties, such as modulus, chemical resistance, and heat stability, are promising for broadening the application area of polyurethanes(PU). For the experiments, a series of cerium oxide(CeO_(2))/PUE composites were prepared with different sizes and appearance of CeO_(2), and different mixing methods as well. CeO_(2) particles with different sizes were added into PUs during the formation of urethane linkage and the chain-extend process, respectively. The morphology along with mechanical properties, thermal properties of the composites were studied. The results suggest that the size of CeO_(2) and mixing methods influence the microstructure of PUs which has profound effect on properties of these composites. The composites tend to form more quantity of hard domains(HDs) with small size when CeO_(2) particles were added before the formation of urethane linkage, whereas Ce O2 particles increase the size of HDs when added with chain extender into PU prepolymer.展开更多
To prepare tungsten/rubber composites with good gamma-ray shielding performances and fine mechanical properties,a composite surface modifier is employed to make surface modification of the tungsten powders.
Iodinated boron dipyrromethene(BODIPY) dyes with 8-hydroxyl-quinoline or phenylamine moiety at the meso-position on the BODIPY core were used as efficient photosensitizers(PSs) of three-component light-driven producti...Iodinated boron dipyrromethene(BODIPY) dyes with 8-hydroxyl-quinoline or phenylamine moiety at the meso-position on the BODIPY core were used as efficient photosensitizers(PSs) of three-component light-driven production of H_2 system from acidic aqueous solution in conjunction with a cobaloxime[CoⅢ(dmgH)_2 PyCl](dmgH = dimethylglyoximate, and py = pyridine) as proton-reducing catalyst and ascorbic acid(H_2 A) as sacrificial electron donor. This is the first example of BODIPYs as homogeneous hydrogen-generating PSs employed in the acidic aqueous conditions. That they are active in the acidic solutions and inactive in the basic conditions may indicate that the extent of competition between intramolecular and intermolecular electron transfer reactions exists. Efficient bimolecular electron transfer reaction between PS and molecular catalyst is needed to make H_2 production, while the intramolecular electron transfer of PS may curb H_2 production. The results underscore that the chemical modification of BODIPYs can be performed, thus allowing for the transformation of acid and base conditions for the light-driven H_2 production.展开更多
文摘A series of polyurethane elastomers (PUEs) were synthesized by using β-cyclodextrin (β-CD) as cross-linker from aliphatic, alicyclic, aromatic diisocyanates, and polyol. The PUEs were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA), swelling test, hardness test and tensile test. The influence of diisocyanate on microphase separation and properties of PUEs was evaluated.
文摘A series of PUEs which use β-CD as cross-linker were synthesized. Nanoindentation measurements of mechanical properties of these PUEs were made. Load and depth sensing indentation and nano DMA mode were used to evaluate mechanical properties of PUEs in nano-scale. The difference between the results from two modes proved the microphase separation in PUEs and to investigate PUE from hard domains and soft domains was of great significance.
基金supported by grants from the Scientific Research Project of Hunan Health Commission in 2019(No.B2019071)the Scientific Research Project of Hunan Health Commission in 2020(No.B20200059).
文摘Objective To evaluate the feasibility of using gadopentetate dimeglumine(Gd-DTPA)for dual-energy computed tomography pulmonary angiography(CTPA).Methods Sixty-six patients were randomly divided into three groups and underwent CTPA.Group A had a turbo flash scan using an iohexol injection,Group B had a turbo flash scan using Gd-DTPA,and Group C had a dual-energy scan using Gd-DTPA.The original images of Group C were linearly blended with a blending factor of 0.5 or reconstructed at 40,50,60,70,80,90,100,and 110 keV,respectively.The groups were compared in terms of pulmonary artery CT value,image quality,and radiation dose.Results The pulmonary artery CT values were significantly higher in Group C40keV than in Groups B and C,but lower than in Group A.There was no significant difference in the image noise of Groups C40keV,B,and C.Moreover,Group A had the largest beam hardening artifacts of the superior vena cava(SVC),followed by Groups B and C.Group C40keV showed better vascular branching than the other three groups,among which Group B was superior to Group A.The subjective score of the image quality of Groups A,B,and C showed no significant difference,but the score was significantly higher in Group C40keV than in Groups A and B.The radiation dose was significantly lower in Group B than in Groups A and C.Conclusion Gd-CTPA is recommended to patients who are unsuitable for receiving an iodine-based CTPA.Furthermore,a turbo flash scan could surpass a dual-energy scan without consideration for virtual monoenergetic imaging.
文摘A series of polyurethane elastomers (PUEs) were synthesized from an aromatic diisocyanate (4, 4’-diphenylmethane diisocyanate);a polyether polyol (polytetramethylene glycol, molecular weight: 1000), polyester polyol (poly-caprolactonediol, molecular weight: 1000, or polycarbonate diol, molecular weight: 1000);and β-cyclodextrin (β-CD) as a cross-linker. The effect of the polyol on the morphologies and chemical, thermal, and mechanical properties of the resultant β-CD-based PUEs were investigated in this study. The obtained films were characterized via solubility and swelling tests (chemical properties), differential scanning calorimetry (crystallinity degree), dynamic mechanical analysis (thermal stability), thermogravimetric analysis (thermal stability), tensile testing (mechanical properties), nuclear magnetic resonance spectroscopy, infrared spectroscopy, atomic force microscopy (morphology), contact angle determination (morphology), and scanning electron microscopy (morphology).
基金supported by the National Natural Science Foundation of China (Nos.11771105, 12071410)the Natural Science Foundation of Guangxi Province (Nos.2017GXNSFFA198012)Guangxi Distinguished Expert Project。
文摘This paper mainly studies the contact extension of conservative or dissipative systems, including some old and new results for wholeness. Then extension of contact system is corresponding to the symplectification of contact Hamiltonian system. This is a reciprocal process and the relation between symplectic system and contact system has been discussed. We have an interesting discovery that by adding a pure variable p,the slope of the tangent of the orbit, every differential system can be regarded as an independent subsystem of contact Hamiltonian system defined on the projection space of contact phase space.
基金supported by the National Natural Science Foundation of China(62304189 and 62304002)the Natural Science Foundation of Xiamen City(3502Z20227063)+3 种基金the Natural Science Foundation of Fujian Province(2023J011450 and 2023J011452)the Key Technologies Innovation and Industrialization Projects of Fujian Province(2023XQ022)the National Natural Science Foundation of China Joint Fund for Cross-strait Scientific and Technological Cooperation(U2005212)the Open Fund of Xiamen Key Laboratory of High Performance Metal and Materials of Xiamen University。
基金financially supported by the National Natural Science Foundation of China (No. 61205217)the National Science Foundation for Distinguished Young Scholars of Fujian Province (No. 2012J06024)+2 种基金the Natural Science Foundation of Fujian Province (No. 2011J05142)the Science and Technology Plan of Xiamen City (No. 3502Z20123040)the Ministry of Education in China Project of Humanities and Social Sciences (No. 11YJC820135)
文摘Based on a hydrothermal method, the Ce3+/Tb3+ co-doped Ba Gd F5 nanocrystals were synthesized by controlling the introduction concentration of Ba2+ and Gd3+. The samples were characterized by X-ray diffraction(XRD), field emission scanning electron microscopy(FESEM) images, photoluminescence(PL) excitation, and emission spectra, as well as the photoluminescence dynamic decay curves. With the increase of the Ba2+ concentration in the synthesis procedure, the positions of diffraction peaks of XRD patterns move toward lower degree, and the case of the samples synthesized with the increase of the Gd3+ concentration is contrary, which consists well with each other. The FE-SEM images suggest that the BaGdF5 nanocrystals are in spherical morphology,and the average diameters decrease with the increase of Ba2+ or Gd3+ concentration. For the 4f–5d transition of Ce3+ is sensitive to the environment of local lattice, the PL excitation and emission spectra of the samples are different. The 4f–4f transition of Tb3+ also presents different optical properties in different host lattices. The variations of the optical properties of Ce3+ and Tb3+ as well as the lifetime of the 5D4+7F5 emission of Tb3+ are also consistent well with each other in the two series of samples.
基金financially supported by Funding of Jiangsu Educational Committee (No. 19KJB430042)。
文摘In general, inorganic filler/polyurethane elastomer(PUE) composites possess favorable properties, such as modulus, chemical resistance, and heat stability, are promising for broadening the application area of polyurethanes(PU). For the experiments, a series of cerium oxide(CeO_(2))/PUE composites were prepared with different sizes and appearance of CeO_(2), and different mixing methods as well. CeO_(2) particles with different sizes were added into PUs during the formation of urethane linkage and the chain-extend process, respectively. The morphology along with mechanical properties, thermal properties of the composites were studied. The results suggest that the size of CeO_(2) and mixing methods influence the microstructure of PUs which has profound effect on properties of these composites. The composites tend to form more quantity of hard domains(HDs) with small size when CeO_(2) particles were added before the formation of urethane linkage, whereas Ce O2 particles increase the size of HDs when added with chain extender into PU prepolymer.
基金financially supported by the National Natural Science Foundation of China (No. 52078247)Qing Lan Project of Yangzhou University (Dr. LJL)
文摘To prepare tungsten/rubber composites with good gamma-ray shielding performances and fine mechanical properties,a composite surface modifier is employed to make surface modification of the tungsten powders.
基金the National Natural Science Foundation of China (Nos. 21641011, 21571115 and 21701133)the Program for New Century Excellent Talents in Fujian Province University and the Fujian Key Laboratory of Functional Materials and Applications (No. fma2017107)+2 种基金the Natural Science Foundation of Shandong Province (No. JQ201803)Young Scholars Program of Shandong University (No. 2015WLJH24)the Fundamental Research Funds of Shandong University (No. 104.205.2.5) for financial support of this work
文摘Iodinated boron dipyrromethene(BODIPY) dyes with 8-hydroxyl-quinoline or phenylamine moiety at the meso-position on the BODIPY core were used as efficient photosensitizers(PSs) of three-component light-driven production of H_2 system from acidic aqueous solution in conjunction with a cobaloxime[CoⅢ(dmgH)_2 PyCl](dmgH = dimethylglyoximate, and py = pyridine) as proton-reducing catalyst and ascorbic acid(H_2 A) as sacrificial electron donor. This is the first example of BODIPYs as homogeneous hydrogen-generating PSs employed in the acidic aqueous conditions. That they are active in the acidic solutions and inactive in the basic conditions may indicate that the extent of competition between intramolecular and intermolecular electron transfer reactions exists. Efficient bimolecular electron transfer reaction between PS and molecular catalyst is needed to make H_2 production, while the intramolecular electron transfer of PS may curb H_2 production. The results underscore that the chemical modification of BODIPYs can be performed, thus allowing for the transformation of acid and base conditions for the light-driven H_2 production.