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Kinetics of the thermal disappearance of radicals formed during the radiolysis of L-α-anhydrous asparagine
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作者 ana neacsu Daniela Gheorghe 《Chemical Reports》 2019年第1期13-21,共9页
An EPR study of paramagnetic centers formed by irradiation of polycrystalline L-α-anhydrous asparagine (L-Asn) was performed. The EPR spectra of gamma irradiated samples at room temperature, shown the presence of thr... An EPR study of paramagnetic centers formed by irradiation of polycrystalline L-α-anhydrous asparagine (L-Asn) was performed. The EPR spectra of gamma irradiated samples at room temperature, shown the presence of three types of paramagnetic centers. A possible mechanisms of formation for the three radical species is suggested, based also on literature data. The kinetics of the disappearance of radicals during thermal annealing indicated a complex mechanism. 展开更多
关键词 L-α-anhydrous ASPARAGINE ionizing radiation paramagnetic centers THERMAL DISAPPEARANCE UNPAIRED electron
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