Sodium-ion batteries(SIBs)have been regarded as one of the most competitive alternatives for lithium-ion batteries(LIBs)due to the abundance of sodium and comparable electrochemical characteristics of sodium to that o...Sodium-ion batteries(SIBs)have been regarded as one of the most competitive alternatives for lithium-ion batteries(LIBs)due to the abundance of sodium and comparable electrochemical characteristics of sodium to that of lithium.However,while highly desired,developing stable anode materials remains a critical challenge.In this work,the development of a stable anode for SIBs is reported,a poriferous nanoflake-assembled flower-like nickel tetraphosphide(PNAF-NP)with high surface area and typical mesoporous property.Due to the unique structure,the PANF-NP anode exhibits excellent reversible capacity of 648.34mAhg^(-1) at 0.2Ag^(-1) with a Coulombic efficiency of 98.67%,and superior cycling stability at 0.2Ag^(-1) with high retention capacity of 456.34 mAhg^(-1) and average Coulombic efficiency of 99.19%after 300 cycles.Moreover,the high reversible capacity of 614.43,589.49,512.66,and 432.23mAhg^(-1) is achieved at 0.5,1,2,and 5Ag^(-1),respectively,indicating the superior rate capability of the PNAF-NP anode.This work represents a great advancement in the field of SIBs by reporting a high-performance anode material.展开更多
文摘Sodium-ion batteries(SIBs)have been regarded as one of the most competitive alternatives for lithium-ion batteries(LIBs)due to the abundance of sodium and comparable electrochemical characteristics of sodium to that of lithium.However,while highly desired,developing stable anode materials remains a critical challenge.In this work,the development of a stable anode for SIBs is reported,a poriferous nanoflake-assembled flower-like nickel tetraphosphide(PNAF-NP)with high surface area and typical mesoporous property.Due to the unique structure,the PANF-NP anode exhibits excellent reversible capacity of 648.34mAhg^(-1) at 0.2Ag^(-1) with a Coulombic efficiency of 98.67%,and superior cycling stability at 0.2Ag^(-1) with high retention capacity of 456.34 mAhg^(-1) and average Coulombic efficiency of 99.19%after 300 cycles.Moreover,the high reversible capacity of 614.43,589.49,512.66,and 432.23mAhg^(-1) is achieved at 0.5,1,2,and 5Ag^(-1),respectively,indicating the superior rate capability of the PNAF-NP anode.This work represents a great advancement in the field of SIBs by reporting a high-performance anode material.
