The adsorptive removal of antimony (III) has been successfully obtained on montmorillonite (MMT) and modified MMT from synthetic solution. The adsorption behavior of the modified and unmodified MMT has been investigat...The adsorptive removal of antimony (III) has been successfully obtained on montmorillonite (MMT) and modified MMT from synthetic solution. The adsorption behavior of the modified and unmodified MMT has been investigated as a function of initial concentration of metal ion in the solution, pH of the solution and contact time using a batch extraction process. The optimized process can be applied for the adsorption, detection and estimation of antimony from 0.006 μg/ml (6.0 ppb) to 100.00 μg/ml (100.0 ppm) in aqueous solution. It has been observed that almost 99% of antimony (III) can be successfully extracted from a solution containing 100 μg/ml of the metal ion at pH 6.0 at 25?C ± 2?C. The investigation of the kinetics of sorption of antimony (III) on MMT/modified MMTshows intraparticle diffusion to be the rate limiting step during the initial stages of adsorption followed by chemisorption.展开更多
Arsenic (III) adsorption has been studied as a function of concentration of arsenic (III) in the solution, pH of the solu- tion, contact time during the batch extraction process using montmorillonite (MMT) and surfact...Arsenic (III) adsorption has been studied as a function of concentration of arsenic (III) in the solution, pH of the solu- tion, contact time during the batch extraction process using montmorillonite (MMT) and surfactant modified MMT (CPC-MMT and CTAB-MMT) from aqueous solution It has been observed that up to 90% of arsenic (III) can be ex- tracted from a solution containing 100 ppm of As (III) at pH 8.0, within a contact time of 10 minutes. The lowest level of As (III) that could be extracted was found to be 0.4 ppm.展开更多
文摘The adsorptive removal of antimony (III) has been successfully obtained on montmorillonite (MMT) and modified MMT from synthetic solution. The adsorption behavior of the modified and unmodified MMT has been investigated as a function of initial concentration of metal ion in the solution, pH of the solution and contact time using a batch extraction process. The optimized process can be applied for the adsorption, detection and estimation of antimony from 0.006 μg/ml (6.0 ppb) to 100.00 μg/ml (100.0 ppm) in aqueous solution. It has been observed that almost 99% of antimony (III) can be successfully extracted from a solution containing 100 μg/ml of the metal ion at pH 6.0 at 25?C ± 2?C. The investigation of the kinetics of sorption of antimony (III) on MMT/modified MMTshows intraparticle diffusion to be the rate limiting step during the initial stages of adsorption followed by chemisorption.
文摘Arsenic (III) adsorption has been studied as a function of concentration of arsenic (III) in the solution, pH of the solu- tion, contact time during the batch extraction process using montmorillonite (MMT) and surfactant modified MMT (CPC-MMT and CTAB-MMT) from aqueous solution It has been observed that up to 90% of arsenic (III) can be ex- tracted from a solution containing 100 ppm of As (III) at pH 8.0, within a contact time of 10 minutes. The lowest level of As (III) that could be extracted was found to be 0.4 ppm.