The effect of Li and Mn substitution on the dielectric, ferroelectric and piezoelectric properties of lead free K0.5Na0.5NbO3 （KNN） was investigated. Samples were prepared using a conventional solid state reaction m...The effect of Li and Mn substitution on the dielectric, ferroelectric and piezoelectric properties of lead free K0.5Na0.5NbO3 （KNN） was investigated. Samples were prepared using a conventional solid state reaction method. The sintefing temperature for all the samples was 1050℃. The optimum doping concentration for the enhancement of different properties without the introduction of any other co-dopants such as Ti, Sb, and La was investigated. X-ray diffraction analysis confirmed that all the samples crystallize in a single phase perovskite structure. The dielectric properties were investigated as a function of temperature and applied electric field frequency. Compared with Li-substituted KNN （KLNN）, Mn-substituted KNN （KMNN） exhibited a higher dielectric constant εmax （i.e., 4840） at its critical transition temperature Tc （i.e., 421℃） along with a lower value of tangent loss at 10 kHz and greater values of saturation polarisation Ps （i.e., 20.14 μC/cm^2） and remnant polarisation Pr （i.e., 15.48 μC/cm^2）. The piezoelectric constant （d33） of KMNN was 178 pC/N, which is comparable to that of lead-based hard ceramics. The results presented herein suggest that B-site or Mn substitution at the optimum concentration results in good enhancement of different properties required for materials used in memory devices and other applications.展开更多
When dielectric elastomers sandwiched between compliant electrodes and high electric voltage is applied to the dielectric elastomers. Then due to the electrostatic force between the electrodes the elastomers expands i...When dielectric elastomers sandwiched between compliant electrodes and high electric voltage is applied to the dielectric elastomers. Then due to the electrostatic force between the electrodes the elastomers expands in plane and contract out of plane so that it becomes thinner. As the thickness decreases we observe the increase in the applied electric voltage with the positive feedback effect. This positive feedback leads the electrical as well as mechanical breakdown of elastomer. By applying a mechanical pre-stretch the mechanical stability of dielectric elastomers gets also increased. In this paper, a new generalized set of strain/stretch variables qrN has been introduced to get the expression for second order elastic moduli for the ideal electro elastic material deformed to orthorhombic structure. The strength of a loaded crystal determined from the new moduli has been compared with the strength of classical (Green, Stretch) moduli. It has been observed that the use of incorrect formula by ignoring shear strain leads to incorrect estimation of stability. This problem has been resolved by considering stretch variable in tensor form as generally observed in the process of electrostriction in the elastomers.展开更多
文摘The effect of Li and Mn substitution on the dielectric, ferroelectric and piezoelectric properties of lead free K0.5Na0.5NbO3 （KNN） was investigated. Samples were prepared using a conventional solid state reaction method. The sintefing temperature for all the samples was 1050℃. The optimum doping concentration for the enhancement of different properties without the introduction of any other co-dopants such as Ti, Sb, and La was investigated. X-ray diffraction analysis confirmed that all the samples crystallize in a single phase perovskite structure. The dielectric properties were investigated as a function of temperature and applied electric field frequency. Compared with Li-substituted KNN （KLNN）, Mn-substituted KNN （KMNN） exhibited a higher dielectric constant εmax （i.e., 4840） at its critical transition temperature Tc （i.e., 421℃） along with a lower value of tangent loss at 10 kHz and greater values of saturation polarisation Ps （i.e., 20.14 μC/cm^2） and remnant polarisation Pr （i.e., 15.48 μC/cm^2）. The piezoelectric constant （d33） of KMNN was 178 pC/N, which is comparable to that of lead-based hard ceramics. The results presented herein suggest that B-site or Mn substitution at the optimum concentration results in good enhancement of different properties required for materials used in memory devices and other applications.
文摘When dielectric elastomers sandwiched between compliant electrodes and high electric voltage is applied to the dielectric elastomers. Then due to the electrostatic force between the electrodes the elastomers expands in plane and contract out of plane so that it becomes thinner. As the thickness decreases we observe the increase in the applied electric voltage with the positive feedback effect. This positive feedback leads the electrical as well as mechanical breakdown of elastomer. By applying a mechanical pre-stretch the mechanical stability of dielectric elastomers gets also increased. In this paper, a new generalized set of strain/stretch variables qrN has been introduced to get the expression for second order elastic moduli for the ideal electro elastic material deformed to orthorhombic structure. The strength of a loaded crystal determined from the new moduli has been compared with the strength of classical (Green, Stretch) moduli. It has been observed that the use of incorrect formula by ignoring shear strain leads to incorrect estimation of stability. This problem has been resolved by considering stretch variable in tensor form as generally observed in the process of electrostriction in the elastomers.
