A novel synthetic method for the preparation of 5-aryl-7-（3,5-dimethyl-lH-pyrazol-l-yl）-2-phenylpyra- zolo[1,5-c]-pyrimidines and 1-（5-aryl-2-phenylpyrazolo[1,5-c]pyrimidin-7-yl）-3-methyl-lH-pyrazol-5-ols is provi...A novel synthetic method for the preparation of 5-aryl-7-（3,5-dimethyl-lH-pyrazol-l-yl）-2-phenylpyra- zolo[1,5-c]-pyrimidines and 1-（5-aryl-2-phenylpyrazolo[1,5-c]pyrimidin-7-yl）-3-methyl-lH-pyrazol-5-ols is provided by condensative cyclization of 5-aryl-7-hydrazino-2-phenylpyrazolo[1,5-c]pyrimidines with 1,3-dicarbonyl compounds. The study of the more reactive position for electrophilic substitusion reactions on such ring system was also achieved.展开更多
文摘A novel synthetic method for the preparation of 5-aryl-7-（3,5-dimethyl-lH-pyrazol-l-yl）-2-phenylpyra- zolo[1,5-c]-pyrimidines and 1-（5-aryl-2-phenylpyrazolo[1,5-c]pyrimidin-7-yl）-3-methyl-lH-pyrazol-5-ols is provided by condensative cyclization of 5-aryl-7-hydrazino-2-phenylpyrazolo[1,5-c]pyrimidines with 1,3-dicarbonyl compounds. The study of the more reactive position for electrophilic substitusion reactions on such ring system was also achieved.
