Deuterium isotope effects in the CO2-reforming of methane to syngas were firstinvestigated over SiO2-supported rhodium catalysts. Normal deuterium isotop effect was morenoticeable on the methane conversion reaction t...Deuterium isotope effects in the CO2-reforming of methane to syngas were firstinvestigated over SiO2-supported rhodium catalysts. Normal deuterium isotop effect was morenoticeable on the methane conversion reaction than on the CO formation reaction, while there wasno such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-Hbond in methane is a key mp and some CO is formed by the reverse water-gas shift reaction.展开更多
文摘Deuterium isotope effects in the CO2-reforming of methane to syngas were firstinvestigated over SiO2-supported rhodium catalysts. Normal deuterium isotop effect was morenoticeable on the methane conversion reaction than on the CO formation reaction, while there wasno such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-Hbond in methane is a key mp and some CO is formed by the reverse water-gas shift reaction.
