Magnetic susceptibility of a series of dinuclear Ⅴ(Ⅳ) . Co(Ⅱ) and Mn(Ⅲ) complexes has been measured in the temperature range of 1. 5 ～300K. The isotropic Heisenberg theory has been applied to study the temperatur...Magnetic susceptibility of a series of dinuclear Ⅴ(Ⅳ) . Co(Ⅱ) and Mn(Ⅲ) complexes has been measured in the temperature range of 1. 5 ～300K. The isotropic Heisenberg theory has been applied to study the temperature-dependent behaviour of the magnetic susceptibility of these complexes and a corresponding program for fitting the experimental results has been set up on a VAX 11/785 computer. Conclusions can be drawn that the three complexes studied are all anti-ferromagnetically coupled with coupling constants -4. 4 , -115. 2 , and - 8. 4 cm￣(-1) for Ⅴ(Ⅳ) . Co(Ⅱ) ,and Mn(Ⅲ) complexes, respectively.展开更多
文摘Magnetic susceptibility of a series of dinuclear Ⅴ(Ⅳ) . Co(Ⅱ) and Mn(Ⅲ) complexes has been measured in the temperature range of 1. 5 ～300K. The isotropic Heisenberg theory has been applied to study the temperature-dependent behaviour of the magnetic susceptibility of these complexes and a corresponding program for fitting the experimental results has been set up on a VAX 11/785 computer. Conclusions can be drawn that the three complexes studied are all anti-ferromagnetically coupled with coupling constants -4. 4 , -115. 2 , and - 8. 4 cm￣(-1) for Ⅴ(Ⅳ) . Co(Ⅱ) ,and Mn(Ⅲ) complexes, respectively.
