A solution containing Cr(VI), Cr(NO3)3 and its complex with an organic acid as well as several commercial solutions containing Cr(III) complexes with an organic acid and additionally CO2+, F-, SO42- ions were used for...A solution containing Cr(VI), Cr(NO3)3 and its complex with an organic acid as well as several commercial solutions containing Cr(III) complexes with an organic acid and additionally CO2+, F-, SO42- ions were used for the studies. Results of the studies obtained in the following commercial solutions: Likonda 2AT, Cr(NO3)3 + malonic acid;Likonda 3Cr5 and Likonda 3CrMC are discussed. Steel coated with chromated Zn coatings was contaminated by some microscopic fungi. The variety of fungi on chromated plates diminished, however the propagules of fungi did not disappear completely. The Likonda 3Cr5 solution diminishes fungi contamination on chromated steel most effectively. In water used to rinse the surface of chromated plates the number of fungi propagules was detected to be higher as compared to that on the plate surface. The least quantity of fungi propagules was detected in water used to rinse plates coated in the Likonda 3Cr5 solution. The main part of fungi detected on chromated plates treated in the Likonda 3Cr5 solution were the fungi of Cladosporium species (C.herbarum, C.cladosporioides). The latter species also dominated on chromated plates coated with zinc and treated with the other solution. It should be mentioned, that on these plates chromated in this solution, Actinomycetes of the Streptomyces group were abundant. After comparison of surfaces of the plates treated in four solutions it has been determined that the surface of the plates treated in the Likonda 3Cr5 passivation solution and exposed to modelling conditions changed least of all. It has been noticed that on the subject studied white porous rust accumulates, the intensity of this process on the surface studied determines both the probability of corrosion and the resistance of the used safety means to the external factors.展开更多
The growth of the microscopic fungi on the solid surface has a great influence on technical materials destruction. The aim of this study was to determine the influence of two strains of micromycetesPenicillium palitan...The growth of the microscopic fungi on the solid surface has a great influence on technical materials destruction. The aim of this study was to determine the influence of two strains of micromycetesPenicillium palitansstrain6 andArthrinium phaeospermumstrain 10 on morphological and structural properties of carbon steel surfaces in the nutrient medium. The difference in consumption of chlorine byP. palitans6(0.07 wt%) andA. phaeospermum10(0.04 wt%) and the difference in accumulation of a newly formed elementmanganese forP. palitans6(0.01 wt%) andA. phaeospermum10(0.03 wt%) has been observed. A relation between the surface and interface fungal stimulated processes, the biotic oxidation of steel surface as well as formation of the mixed oxides on the biomodified steel surface has been determined. The morphology of surfaces was characterized by scanning electron microscopy, the structure—by the X-ray diffraction method, Fourier transformation infrared and X-ray fluorescence spectroscopy.展开更多
文摘A solution containing Cr(VI), Cr(NO3)3 and its complex with an organic acid as well as several commercial solutions containing Cr(III) complexes with an organic acid and additionally CO2+, F-, SO42- ions were used for the studies. Results of the studies obtained in the following commercial solutions: Likonda 2AT, Cr(NO3)3 + malonic acid;Likonda 3Cr5 and Likonda 3CrMC are discussed. Steel coated with chromated Zn coatings was contaminated by some microscopic fungi. The variety of fungi on chromated plates diminished, however the propagules of fungi did not disappear completely. The Likonda 3Cr5 solution diminishes fungi contamination on chromated steel most effectively. In water used to rinse the surface of chromated plates the number of fungi propagules was detected to be higher as compared to that on the plate surface. The least quantity of fungi propagules was detected in water used to rinse plates coated in the Likonda 3Cr5 solution. The main part of fungi detected on chromated plates treated in the Likonda 3Cr5 solution were the fungi of Cladosporium species (C.herbarum, C.cladosporioides). The latter species also dominated on chromated plates coated with zinc and treated with the other solution. It should be mentioned, that on these plates chromated in this solution, Actinomycetes of the Streptomyces group were abundant. After comparison of surfaces of the plates treated in four solutions it has been determined that the surface of the plates treated in the Likonda 3Cr5 passivation solution and exposed to modelling conditions changed least of all. It has been noticed that on the subject studied white porous rust accumulates, the intensity of this process on the surface studied determines both the probability of corrosion and the resistance of the used safety means to the external factors.
文摘The growth of the microscopic fungi on the solid surface has a great influence on technical materials destruction. The aim of this study was to determine the influence of two strains of micromycetesPenicillium palitansstrain6 andArthrinium phaeospermumstrain 10 on morphological and structural properties of carbon steel surfaces in the nutrient medium. The difference in consumption of chlorine byP. palitans6(0.07 wt%) andA. phaeospermum10(0.04 wt%) and the difference in accumulation of a newly formed elementmanganese forP. palitans6(0.01 wt%) andA. phaeospermum10(0.03 wt%) has been observed. A relation between the surface and interface fungal stimulated processes, the biotic oxidation of steel surface as well as formation of the mixed oxides on the biomodified steel surface has been determined. The morphology of surfaces was characterized by scanning electron microscopy, the structure—by the X-ray diffraction method, Fourier transformation infrared and X-ray fluorescence spectroscopy.