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Oxone-Mediated Preparation of Ester Derivatives Using Indium(III) Triflate and Various Alcohols 被引量:1
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作者 Tomoko Mineno Daiki Takano +2 位作者 Saika Komiya azusa sato Hisao Kansui 《Green and Sustainable Chemistry》 2022年第1期1-8,共8页
Esters are known as one of the most fundamental chemical moieties and also essentially useful components, especially for medicinal agents. Herein, using benzaldehyde and its derivatives as starting materials, Oxone-me... Esters are known as one of the most fundamental chemical moieties and also essentially useful components, especially for medicinal agents. Herein, using benzaldehyde and its derivatives as starting materials, Oxone-mediated preparation of ester derivatives in the presence of a catalytic amount of indium(III) triflate is described. Alcohols with various chain lengths, which functioned as solvents and substrates, were examined. Overall, the oxidative esterification starting with benzaldehyde derivatives possessing electron withdrawing groups proceeded smoothly and gave sufficient yields, in comparison to the reactions with the derivatives having electron donating groups. 展开更多
关键词 OXONE Oxidative Esterification Benzaldehyde Derivatives Ester Derivatives Indium(III) Triflate ALCOHOLS
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