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Growth, Crystal Structure and Characterization of a New Single Crystal: Lithium Sodium Acid Phthalate (LiNaP), for Third Order Nonlinear Optical Applications
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作者 b. sivakumar S. Gokul Raj +1 位作者 G. Ramesh Kumar R. Mohan 《Journal of Crystallization Process and Technology》 2012年第4期130-136,共7页
A new alkali metallo-organic single crystal of Lithium Sodium Acid Phthlate (LiNaP) complex has been synthesized from aqueous solution in the equimolar ratio 3:1:2. Transparent and bulk single crystals of dimension 9 ... A new alkali metallo-organic single crystal of Lithium Sodium Acid Phthlate (LiNaP) complex has been synthesized from aqueous solution in the equimolar ratio 3:1:2. Transparent and bulk single crystals of dimension 9 × 4 ×2 mm3 have been grown from the conventional slow-cooling technique. The crystal structure of the compound has been solved from single crystal X-ray diffraction. The compound 2[C8H4O3]4-Li3+Na+ crystallizes in triclinic system with a space group of Pī having cell dimensions a = 7.5451(2) ? b = 9.8422(3) ? c = 25.2209(7) ? α = 80.299(2);β = 89.204(2);γ = 82.7770(10). FTIR measurement was carried out fo? LiNaP to study the vibrational structure of the compound. The various functional groups present in the molecule and the role of H-bonds in stabilizing the crystal structure of the compound have been explained. Optical absorption properties were studied for the grown crystal using UV-Vis-NIR spectrum. Thermal measurements were carried out for LiNaP to determine the thermal strength as well as to ascertain the hydrated nature of the crystal. Third order nonliner optical studies have also studied by Z-scan techniques. Nonlinear absorption and nonlinear refractive index were found out and the third order bulk susceptibility of compound was also estimated. The results of all studies have been discussed in detail. 展开更多
关键词 Single Crystal X-Ray Diffraction FTIR ANALYSIS UV-Vis-NIR Spectroscopy Thermal ANALYSIS Nonlinear Optical Materials THIRD-ORDER Nonlinearity Z-SCAN
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A PERISHABLE INVENTORY SYSTEM WITH SERVICE FACILITIES, MAP ARRIVALS AND PH- SERVICE TIMES 被引量:3
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作者 Paul MANUEL b. sivakumar G. ARIVARIGNAN 《Journal of Systems Science and Systems Engineering》 SCIE EI CSCD 2007年第1期62-73,共12页
We consider a continuous review perishable (s,S) inventory system with a service facility consisting of a waiting hall of finite capacity and a single server. We assume two types of customers, ordinary and negative,... We consider a continuous review perishable (s,S) inventory system with a service facility consisting of a waiting hall of finite capacity and a single server. We assume two types of customers, ordinary and negative, arrive according to a Markovian Arrival Process (MAP). An ordinary customer joins the queue and a negative customer instead of joining the queue removes one ordinary customer from the queue. The removal rule adopted in this paper is RCE (removal of a customer from the end). The individual customer's unit demand is satisfied after a random time of service which is assumed to have a phase-type distribution. The life time of each item and the lead time of the reorders have been assumed to be independent exponential distributions. The joint probability distribution of the number of customers in the system and the inventory level is obtained for the steady state case. Various stationary system performance measures are computed and the total expected cost rate is calculated. The results are illustrated numerically. 展开更多
关键词 Stochastic inventory Markovian demands service facility positive lead time negative customers
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