It has been a long-standing question whether dewetting of polymer film from non-wettable substrate surfaceswherein the bicontinuous morphology never forms in the dewetting film is due to spinodal instability or hetero...It has been a long-standing question whether dewetting of polymer film from non-wettable substrate surfaceswherein the bicontinuous morphology never forms in the dewetting film is due to spinodal instability or heterogeneousnucleation. In this experiment, we use a simple method to make the distinction through introduction of topographical defectsof the films by rubbing the sample surface with a rayon cloth. Spinodal dewetting is identified for those films that dewet by acharateristic wavevector, q, independent of the density of rubbing-induced defects. Heterogeneous nucleation, on the otherhand, is identified for those with q increasing with increasing density of defects. Our result shows that PS films on oxidecoated silicon with thickness less than ≈ 13 nm are dominated by spinodal dewetting, but the thicker films are dominated bynucleation dewetting. We also confirm that spinodal dewetting does not necessarily lead to a bicontinuous morphology in thedewetting film, contrary to the classic theory of Cahn.展开更多
Experimental and simulation data[Moreau et al.,Plasma Phys.Control.Fusion 62,014013(2019);Kaymak et al.,Phys.Rev.Lett.117,035004(2016)]indicate that self-generated magnetic fields play an important role in enhancing t...Experimental and simulation data[Moreau et al.,Plasma Phys.Control.Fusion 62,014013(2019);Kaymak et al.,Phys.Rev.Lett.117,035004(2016)]indicate that self-generated magnetic fields play an important role in enhancing the flux and energy of relativistic electrons accelerated by ultra-intense laser pulse irradiation with nanostructured arrays.A fully relativistic analytical model for the generation of the magnetic field based on electron magneto-hydrodynamic description is presented here.The analytical model shows that this self-generated magnetic field originates in the nonparallel density gradient and fast electron current at the interfaces of a nanolayered target.A general formula for the self-generated magnetic field is found,which closely agrees with the simulation scaling over the relevant intensity range.The result is beneficial to the experimental designs for the interaction of the laser pulse with the nanostructured arrays to improve laser-to-electron energy coupling and the quality of forward hot electrons.展开更多
基金This work was supported by the Institute of Nano Science and Technology and the Hong Kong University of Science and Technology through the Postdoctoral Matching Fund.
文摘It has been a long-standing question whether dewetting of polymer film from non-wettable substrate surfaceswherein the bicontinuous morphology never forms in the dewetting film is due to spinodal instability or heterogeneousnucleation. In this experiment, we use a simple method to make the distinction through introduction of topographical defectsof the films by rubbing the sample surface with a rayon cloth. Spinodal dewetting is identified for those films that dewet by acharateristic wavevector, q, independent of the density of rubbing-induced defects. Heterogeneous nucleation, on the otherhand, is identified for those with q increasing with increasing density of defects. Our result shows that PS films on oxidecoated silicon with thickness less than ≈ 13 nm are dominated by spinodal dewetting, but the thicker films are dominated bynucleation dewetting. We also confirm that spinodal dewetting does not necessarily lead to a bicontinuous morphology in thedewetting film, contrary to the classic theory of Cahn.
基金This work was supported by the Science Challenge Project(No.TZ2016005)NSAF(No.U1730449)+1 种基金the National Natural Science Foundation of China(Nos.11575030 and 11975055)the National Key Programme for S&T Research and Development in China(No.2016YFA0401100).
文摘Experimental and simulation data[Moreau et al.,Plasma Phys.Control.Fusion 62,014013(2019);Kaymak et al.,Phys.Rev.Lett.117,035004(2016)]indicate that self-generated magnetic fields play an important role in enhancing the flux and energy of relativistic electrons accelerated by ultra-intense laser pulse irradiation with nanostructured arrays.A fully relativistic analytical model for the generation of the magnetic field based on electron magneto-hydrodynamic description is presented here.The analytical model shows that this self-generated magnetic field originates in the nonparallel density gradient and fast electron current at the interfaces of a nanolayered target.A general formula for the self-generated magnetic field is found,which closely agrees with the simulation scaling over the relevant intensity range.The result is beneficial to the experimental designs for the interaction of the laser pulse with the nanostructured arrays to improve laser-to-electron energy coupling and the quality of forward hot electrons.
