The CoFe_2alloy(CF) was prepared by reducing CoFe_2O_4 in the H_2 ambient. Subsequently the CF sample was nitrided in the NH_3 atmosphere to produce the composite of CoFe_2N and CoFe_2. The magnetostriction, thermal...The CoFe_2alloy(CF) was prepared by reducing CoFe_2O_4 in the H_2 ambient. Subsequently the CF sample was nitrided in the NH_3 atmosphere to produce the composite of CoFe_2N and CoFe_2. The magnetostriction, thermal expansion, resistivity and corrosion resistance of CF sample and the nitrided sample(CFN)at 1000?C were investigated. The saturation magnetostriction coefficiency λ_s and thermal expansion coefficient ? at 300 K for the nitrided CFN were 50 ppm and 10 ppm/K, respectively, approximately equal to those for the CF sample. However, compared with CF, CFN presents a decrease in temperature coefficient R_λ(300 K) of magnetostriction by 11%. The smaller resistivity and improved corrosion resistance in the H_2SO_4 solution may expand the applications of the CoFe_2 in the fields needing lower resistivity or in the acidic environment.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 51471001, 11174004 and 11304001)Key Project of the Foundation of Anhui Educational Committee (No. KJ2013A035)
文摘The CoFe_2alloy(CF) was prepared by reducing CoFe_2O_4 in the H_2 ambient. Subsequently the CF sample was nitrided in the NH_3 atmosphere to produce the composite of CoFe_2N and CoFe_2. The magnetostriction, thermal expansion, resistivity and corrosion resistance of CF sample and the nitrided sample(CFN)at 1000?C were investigated. The saturation magnetostriction coefficiency λ_s and thermal expansion coefficient ? at 300 K for the nitrided CFN were 50 ppm and 10 ppm/K, respectively, approximately equal to those for the CF sample. However, compared with CF, CFN presents a decrease in temperature coefficient R_λ(300 K) of magnetostriction by 11%. The smaller resistivity and improved corrosion resistance in the H_2SO_4 solution may expand the applications of the CoFe_2 in the fields needing lower resistivity or in the acidic environment.