Nano sized La0.4F3：Ce0.45,Tb0.15（core）, La0.4F3：Ce0.45,Tb0.15（Ti O2）（core） shell, La0.55F：Ce0.45, and La0.85F3：Tb0.15 particles were synthesized by adopting co-precipitation technique in acidic environment a...Nano sized La0.4F3：Ce0.45,Tb0.15（core）, La0.4F3：Ce0.45,Tb0.15（Ti O2）（core） shell, La0.55F：Ce0.45, and La0.85F3：Tb0.15 particles were synthesized by adopting co-precipitation technique in acidic environment and coated with Ti O2 to form a core-shell structure by adopting a mechanical dispersion method at room temperature. The synthesized materials were characterized using X-ray diffraction（XRD）, transmission electron microscopy（TEM）, Fourier transform infrared spectroscopy（FTIR）, ultraviolet-visible spectroscopy（UV-Vis） absorption, photoluminescence and lifetime spectroscopy. The crystal structure of La0.4F3：Ce0.45,Tb0.15 remained the same as La F3 after being doped with Ce and Tb ions but with a slight decrease in the lattice parameter. TEM image confirmed the formation of a core-shell structure. The La0.4F3：Ce0.45,Tb0.15/Ti O2 exhibited Tb3＋ fluorescence enhancement by a factor of 1.76. Scintillation from the synthesized materials was also observed under X-ray excitation.展开更多
文摘Nano sized La0.4F3：Ce0.45,Tb0.15（core）, La0.4F3：Ce0.45,Tb0.15（Ti O2）（core） shell, La0.55F：Ce0.45, and La0.85F3：Tb0.15 particles were synthesized by adopting co-precipitation technique in acidic environment and coated with Ti O2 to form a core-shell structure by adopting a mechanical dispersion method at room temperature. The synthesized materials were characterized using X-ray diffraction（XRD）, transmission electron microscopy（TEM）, Fourier transform infrared spectroscopy（FTIR）, ultraviolet-visible spectroscopy（UV-Vis） absorption, photoluminescence and lifetime spectroscopy. The crystal structure of La0.4F3：Ce0.45,Tb0.15 remained the same as La F3 after being doped with Ce and Tb ions but with a slight decrease in the lattice parameter. TEM image confirmed the formation of a core-shell structure. The La0.4F3：Ce0.45,Tb0.15/Ti O2 exhibited Tb3＋ fluorescence enhancement by a factor of 1.76. Scintillation from the synthesized materials was also observed under X-ray excitation.
