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Luobusaite:A New Mineral 被引量:10
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作者 bai wenji SHI Nicheng +4 位作者 FANG Qingsong LI Guowu XIONG Ming YANG Jingsui RONG He 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2006年第5期656-659,共4页
A group of mantle minerals including about 70-80 subtypes of minerals are discovered from a podiform chromitite in Tibet, China. Recovered minerals include diamond, coesite, moissanite, wustite, Fe-silides and a new m... A group of mantle minerals including about 70-80 subtypes of minerals are discovered from a podiform chromitite in Tibet, China. Recovered minerals include diamond, coesite, moissanite, wustite, Fe-silides and a new mineral, luobusaite. All of these minerals were hand-picked from heavymineral separates of the podiform chromitite in the mantle peridotite of an ophiolite. The grains of luobusaite are as host mineral with inclusions of native silicon or as an intergrowth with native silicon and Fe-Si phase. Luobusaite occurs as irregular grains, with 0.1-0.2 mm in size, consisting of very finegrained aggregates. The mineral is steel-grey in color, metallic luster, and opaque. The empirical formula (based on 2 for Si) is Fe0.83Si2, according to the chemical compositions of luobusaite. X-ray powder-diffraction data: orthorhombic system, space group Cmca, a = 9.874 (14) A, b = 7.784 (5) A, c= 7.829(7) A, Z=16. 展开更多
关键词 new mineral luobusaite CHROMITITE OPHIOLITE TIBET
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Titanium, Ti, A New Mineral Species from Luobusha, Tibet, China 被引量:8
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作者 FANG Qingsong bai wenji +5 位作者 YANG Jingsu RONG He SHI Nicheng LI Guowu XIONG Ming MA Zhesheng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第5期1275-1280,共6页
We describe the new mineral species titanium, ideally Ti, found in the podiform chromitites of the Luobusha ophiolite in Tibet, People's Republic of China. The irregular crystals range from 0.1 to 0.6 mm in diameter ... We describe the new mineral species titanium, ideally Ti, found in the podiform chromitites of the Luobusha ophiolite in Tibet, People's Republic of China. The irregular crystals range from 0.1 to 0.6 mm in diameter and form an intergrowth with coesite and kyanite. Titanium is silver grey in colour, the luster is metallic, it is opaque, the streak is grayish black, and it is non-fluorescent. The mineral is malleable, has a rough to hackly fracture and has no apparent cleavage. The estimated Mohs hardness is 4, and the calculated density is 4.503 g/cm3. The composition is Ti 99.23-100.00 wt%. The mineral is hexagonal, space group P6flmmc. Unit-cell parameters are a 2.950 (2) ~, c 4.686 (1) A,V 35.32 (5) A3, Z = 2. The five strongest powder diffraction lines [d in A (hkl) (I/I0)] are: 2.569 (010) (32), 2.254(011) (100), 1.730 (012) (16), 1.478 (110) (21), and 0.9464 (121) (8). The species and name were approved by the CNMNC (IMA 2010-044). 展开更多
关键词 TITANIUM new mineral species TI CHROMITITE Luobusha ophiolite TIBET
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Naquite, FeSi, a New Mineral Species from Luobusha, Tibet, Western China 被引量:6
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作者 SHI Nlcheng bai wenji +4 位作者 LI Guowu XIONG Ming YANG Jingsu MA Zhesheng RONG He 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第3期533-538,共6页
A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral ... A new mineral species, named naquite(FeSi), is found in the podiform chromitites of the Luobusha ophiolite in Qusong County, Tibet, China. The detailed composition is Fe 65.65, Si 32.57 and Al 1.78 wt%. The mineral is cubic, space group P213. The irregular crystals range from 15 to 50 μm in diameter and form an intergrowth with luobusaite. Naquite is steel grey in color, opaque, with a metallic lustre and gives a grayish-black streak. The mineral is brittle, has a conchoidal fracture and no apparent cleavage. The estimated Mohs hardness is 6.5, and the calculated density is 6.128 g/cm3. Unit-cell parameters are a 4.486 (4) A, V 90.28 (6)A^3, Z=4. The five strongest powder diffraction lines [d inA(hkl) (I/I0)] are: 3.1742 (110) (40), 2.5917(111) (43), 2.0076 (210) (100), 1.8307 (211) (65), and 1.1990 (321) (36). Originally called 'fersilicite', the species and new name have now been approved by the CNMNC (IMA 2010-010). 展开更多
关键词 new mineral fersilicite CHROMITE Luobusha ophiolite TIBET
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Yarlongite:A New Metallic Carbide Mineral 被引量:3
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作者 SHI Nicheng bai wenji +5 位作者 LI Guowu XIONG Ming FANG Qingsong YANG Jingsui MA Zhesheng RONG He 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2009年第1期52-56,共5页
Yarlongite occurs in ophiolitic chromitite at the Luobusha mine (29°5′N 92°5′E, about 200 km ESE of Lhasa), Qusum County, Shannan Prefecture, Tibet Autonomous Region, People's Republic of China. Associa... Yarlongite occurs in ophiolitic chromitite at the Luobusha mine (29°5′N 92°5′E, about 200 km ESE of Lhasa), Qusum County, Shannan Prefecture, Tibet Autonomous Region, People's Republic of China. Associated minerals are: diamond, moissanite, wiistite, iridium ("osmiridium"), osmium ("iridosmine"), periclase, chromite, native iron, native nickel, native chromium, forsterite, Cr-rich diopside, intermetallic compounds Ni-Fe-Cr, Ni-Cr, Cr-C, etc. Yarlongite and its associated minerals were handpicked from a large heavy mineral sample of chromitite. The metallic carbides associated with yarlongite are cohenite, tongbaite, khamrabaevite and qusongite (IMA2007-034). Yarlongite occurs as irregular grains, with a size between 0.02 and 0.06 mm, steel-grey colour, H Mohs: 5^1/2-6. Tenacity: brittle. Cleavage: (0 0 1) perfect. Fracture: conchoidal. Chemical formula: (Cr4Fe4Ni)29C4, or (Cr,Fe,Ni)29C4, Crystal system: Hexagonal, Space Group: P63/mc, a = 18.839(2) A, c = 4.4960 (9) A, V = 745.7(2) A^3, Z = 6, Density (calc.) = 7.19 g/cm3 (with simplified formula). Yariongite has been approved as a new mineral by the CNMNC (IMA2007-035). Holotype material is deposited at the Geological Museum of China (No. Ml1650). 展开更多
关键词 yarlongite new mineral metallic carbides OPHIOLITE LUOBUSHA TIBET
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银和金催化剂在多环天然产物全合成中的应用研究进展
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作者 豆立娟 石宇冰 +1 位作者 白文己 母伟花 《云南化工》 CAS 2021年第7期8-12,共5页
对近十年来国内外课题组在银、金两种过渡金属催化全合成苯并吡喃、苯并呋喃类化合物、Diels-Alder类型的天然产物和吲哚型生物碱等多环天然产物领域所取得的实验研究成果进行了综述,旨在加深人们对过渡金属银和金催化全合成多环天然产... 对近十年来国内外课题组在银、金两种过渡金属催化全合成苯并吡喃、苯并呋喃类化合物、Diels-Alder类型的天然产物和吲哚型生物碱等多环天然产物领域所取得的实验研究成果进行了综述,旨在加深人们对过渡金属银和金催化全合成多环天然产物的认识,为天然药用资源的可持续利用以及开展活性天然产物化学全合成研究提供有益参考。 展开更多
关键词 过渡金属催化 多环天然产物 全合成
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钯催化C—H键官能团化形成C—X(X=O,N,F,I,……)键的密度泛函理论研究进展
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作者 石宇冰 白文己 +3 位作者 母伟花 李江平 于嘉玮 连冰 《有机化学》 SCIE CAS CSCD 北大核心 2022年第5期1346-1374,共29页
过渡金属催化C—H键官能团化是形成C—X(X=O,N,F,I,……)键的有效方法,在传统有机合成、农药、医药以及构筑含C—X杂环的生物活性天然产物基本骨架方面都扮演着重要角色.钯催化C—H键官能团化形成C—X键的方法具有反应效率高、原子经济... 过渡金属催化C—H键官能团化是形成C—X(X=O,N,F,I,……)键的有效方法,在传统有机合成、农药、医药以及构筑含C—X杂环的生物活性天然产物基本骨架方面都扮演着重要角色.钯催化C—H键官能团化形成C—X键的方法具有反应效率高、原子经济性好、环境友好等优点,是近年来过渡金属催化构建C—X键的研究热点.采用密度泛函理论(DFT)对钯催化C—H键官能团化形成C—X键的反应开展理论研究,可获取有关反应路径的诸多信息,帮助人们从微观层面深入认识此类反应的微观机理和反应选择性调控机制,为改进钯催化C—H键官能团化形成C—X键的选择性和反应性控制拓展新思路.对近十年来钯催化C—H键官能团化形成C—X(X=O,N,F,I,……)键的最新理论研究进展进行了综述,对上述反应的微观机理和反应选择性进行了深入探讨,并对该领域的现存问题和发展前景进行了总结与展望. 展开更多
关键词 钯催化 C—H键官能团化 C—X键形成 反应机理 选择性 密度泛函理论(DFT)
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