Sequential samples of single precipitation event were collected by the use of specially de-signed semi-automatic sequential precipitation collector in the spring of 1988 in Guilin City. ThePH value and soluble chemica...Sequential samples of single precipitation event were collected by the use of specially de-signed semi-automatic sequential precipitation collector in the spring of 1988 in Guilin City. ThePH value and soluble chemical species such as SO, NO, NH, Ca ̄(2+), Mg ̄(2+), Na ̄+, K`+, F ̄- andCl ̄- were analyzed. An apparent decrease in the concentration of all ions except H ̄+ and NO wasobserved at the initial portion of the events. The relative acidity increased as the event progress.The concentration of H ̄+ was the result of comprehensive actions of all ions. The average scavengingratio of events was calculated and it is found that SO was the major contributor for acid rain inGuilin and Ca ̄(2+) was the important neutralizer.展开更多
What a great spiritual loss for us! The perishing of 64 excellent singers is just like the falling of 64 bright stars. Although we don't knox,, their names, their smiling faces, their sonorous singing and their elega...What a great spiritual loss for us! The perishing of 64 excellent singers is just like the falling of 64 bright stars. Although we don't knox,, their names, their smiling faces, their sonorous singing and their elegant dances are deeply engraved in our hearts forever.展开更多
Based on atmospheric chemical kinetics, the rate constant of overall pseudo-first order oxidation re-moval of gaseous pollutants (Kpor,T) is proposed to characterize the atmospheric oxidation capacity in troposphere. ...Based on atmospheric chemical kinetics, the rate constant of overall pseudo-first order oxidation re-moval of gaseous pollutants (Kpor,T) is proposed to characterize the atmospheric oxidation capacity in troposphere. Being a quantitative parameter, Kpor,T can be used to address the issues related to at-mospheric oxidation capacity. By applying this method, the regional oxidation capacity of the atmos-phere in Pearl River Delta (PRD) is numerically simulated based on CBM-IV chemical mechanism. Re-sults show the significant spatio-temporal variation of the atmospheric oxidation capacity in PRD. It is found that OH initiated oxidations, heterogeneous oxidation of SO2, and photolysis of aldehydes are the three most important oxidation processes influencing the atmospheric oxidation capacity in PRD.展开更多
A novel vehicle for the delivery of aspirin (ASA) was prepared from porous nano-hydroxyapafite/poly(styrene-divinylbenzene) [nano-HAP/P(St-DVB)] composite microspheres by grafting nano-HAP [Ca10(PO4)6(OH)2] ...A novel vehicle for the delivery of aspirin (ASA) was prepared from porous nano-hydroxyapafite/poly(styrene-divinylbenzene) [nano-HAP/P(St-DVB)] composite microspheres by grafting nano-HAP [Ca10(PO4)6(OH)2] onto porous P(St-DVB) micro- spheres. Four types of porous composite microspheres were prepared, each with different nano-HAP contents. The ASA-loaded composite microspheres prepared with 10% and 15% nano-HAP (mass ratio) exhibited excellent buoyancy with relatively short instantaneous floating time (within l0 min) and a long sustained floating time (12 h) in simulated gastric juice. They also offered good sustained release of ASA (up to 8 h). Furthermore, these composite microspheres displayed good buff- ering capacity that prevented the buildup of acidity caused by hydrolysis of ASA, keeping the pH of gastric juice within the normal range (pH 0.9 to 1.5). The results showed that porous nano-HAP/P(St-DVB) composite microspheres prepared with 10% and 15% nano-HAP could be used as a novel drug carrier for ASA, providing a sustained release dose without leading to stomach irritation, a side effect that is often associated with ASA medication.展开更多
文摘Sequential samples of single precipitation event were collected by the use of specially de-signed semi-automatic sequential precipitation collector in the spring of 1988 in Guilin City. ThePH value and soluble chemical species such as SO, NO, NH, Ca ̄(2+), Mg ̄(2+), Na ̄+, K`+, F ̄- andCl ̄- were analyzed. An apparent decrease in the concentration of all ions except H ̄+ and NO wasobserved at the initial portion of the events. The relative acidity increased as the event progress.The concentration of H ̄+ was the result of comprehensive actions of all ions. The average scavengingratio of events was calculated and it is found that SO was the major contributor for acid rain inGuilin and Ca ̄(2+) was the important neutralizer.
文摘What a great spiritual loss for us! The perishing of 64 excellent singers is just like the falling of 64 bright stars. Although we don't knox,, their names, their smiling faces, their sonorous singing and their elegant dances are deeply engraved in our hearts forever.
基金the National Basic Research Program of China (Grant Nos: 2005CB422204, 2002CB410802, and 2002CB410801)
文摘Based on atmospheric chemical kinetics, the rate constant of overall pseudo-first order oxidation re-moval of gaseous pollutants (Kpor,T) is proposed to characterize the atmospheric oxidation capacity in troposphere. Being a quantitative parameter, Kpor,T can be used to address the issues related to at-mospheric oxidation capacity. By applying this method, the regional oxidation capacity of the atmos-phere in Pearl River Delta (PRD) is numerically simulated based on CBM-IV chemical mechanism. Re-sults show the significant spatio-temporal variation of the atmospheric oxidation capacity in PRD. It is found that OH initiated oxidations, heterogeneous oxidation of SO2, and photolysis of aldehydes are the three most important oxidation processes influencing the atmospheric oxidation capacity in PRD.
基金financially supported by the Young Scientists Fund of the Natural Science Foundation of Heilongjiang Province (QC2011C099)Scientific Fund of Heilongjiang Province Department of Health (2009-259)+3 种基金Grant from Educational Office of Heilongjiang Province (11551178 and1154HZ11)Fund of Daqing GaoXin Qu (DQGX09YF016)the National Natural Science Foundation of China (30871007)the Natural Science Foundation of Heilongjiang Province (ZD2008-08 and LC2009C12)
文摘A novel vehicle for the delivery of aspirin (ASA) was prepared from porous nano-hydroxyapafite/poly(styrene-divinylbenzene) [nano-HAP/P(St-DVB)] composite microspheres by grafting nano-HAP [Ca10(PO4)6(OH)2] onto porous P(St-DVB) micro- spheres. Four types of porous composite microspheres were prepared, each with different nano-HAP contents. The ASA-loaded composite microspheres prepared with 10% and 15% nano-HAP (mass ratio) exhibited excellent buoyancy with relatively short instantaneous floating time (within l0 min) and a long sustained floating time (12 h) in simulated gastric juice. They also offered good sustained release of ASA (up to 8 h). Furthermore, these composite microspheres displayed good buff- ering capacity that prevented the buildup of acidity caused by hydrolysis of ASA, keeping the pH of gastric juice within the normal range (pH 0.9 to 1.5). The results showed that porous nano-HAP/P(St-DVB) composite microspheres prepared with 10% and 15% nano-HAP could be used as a novel drug carrier for ASA, providing a sustained release dose without leading to stomach irritation, a side effect that is often associated with ASA medication.