The current linear economy assumes abundant,easily accessible,and cost-effective natural resources.However,this assumption is unsustainable,especially considering the world’s current trajectory exceeding the Earth’s...The current linear economy assumes abundant,easily accessible,and cost-effective natural resources.However,this assumption is unsustainable,especially considering the world’s current trajectory exceeding the Earth’s ecological limits.In contrast,circular economy(CE)reduces wastes and improves resource efficiency,making them a more sustainable alternative to the dominant linear model.Biomass energy generated from agricultural leftovers,forestry wastes,and municipal trash provides a renewable substitute for fossil fuels.This reduces greenhouse gas emissions and improves energy security.Proper waste management,including trash reduction,recycling,and innovative waste-to-energy technology,reduces the burden on landfills and incineration and creates renewable energy from materials that would otherwise go to waste.Although integrating these techniques is consistent with the CE’s resource efficiency and waste minimization principles,it requires addressing environmental,technical,and socioeconomic challenges.Given the pressing global issues,transitioning to a CE and implementing sustainable environmental practices are crucial to mitigate the current waste management crisis.The aim of this study is to emphasize the viability of biomass as a source of sustainable energy,the necessity of comprehensive strategies that prioritize ecological sustainability,community involvement,and innovation to achieve a circular principle based future,and the potential obstacles to the implementation of sustainable environmental practices.This study will aid in implementing CE practices to accomplish the Sustainable Development Goals(SDGs)by reducing greenhouse gas emissions and landfill loads.Beyond environmental benefits,it can also bring economic,social,and health improvements.Furthermore,this study will assist societies in addressing global issues,such as resource scarcity,pollution,and climate change,as well as transitioning to a more sustainable and resilient future.展开更多
A series of new biochar-supported composite based on the combination of biochar and metallic nanoparticles(NPs)were produced through single-step pyrolysis of FeCl_3–Ti(OBu)_4 laden agar biomass under NH_3 environment...A series of new biochar-supported composite based on the combination of biochar and metallic nanoparticles(NPs)were produced through single-step pyrolysis of FeCl_3–Ti(OBu)_4 laden agar biomass under NH_3 environment.The physiochemical properties of composites were characterized thoroughly.It has found that heating temperature and N-doping through NH_3-ambiance pyrolysis significantly influence the visible-light sensitivity and bandgap energy of composites.The catalytic activities of composites were measured by degradation of Methylene Blue(MB)in the presence or absence of H_2O_2 and visible-light irradiation.Our best catalyst(N–TiO_2–Fe_3O_4-biochar)exhibits rapid and high MB removal competency(99.99%)via synergism of adsorption,photodegradation,and Fenton-like reaction.Continuous production of O_2U^-and UOH radicles performs MB degradation and mineralization,confirmed by scavenging experiments and degradation product analysis.The local trap state Ti^(3+),Fe_3O_4,and N-carbon of the catalyst acted as active sites.It has suggested that the Ti^(3+)and N-doped dense carbon layer improve charge separation and shuttle that prolonged photo-Fenton like reaction.Moreover,the catalyst is highly stable,collectible,and recyclable up to 5 cycles with high MB degradation efficiency.This work provides a new insight into the synthesis of highly visible-light sensitized biocharsupported photocatalyst through NH_3-ambiance pyrolysis of NPs-laden biomass.展开更多
文摘The current linear economy assumes abundant,easily accessible,and cost-effective natural resources.However,this assumption is unsustainable,especially considering the world’s current trajectory exceeding the Earth’s ecological limits.In contrast,circular economy(CE)reduces wastes and improves resource efficiency,making them a more sustainable alternative to the dominant linear model.Biomass energy generated from agricultural leftovers,forestry wastes,and municipal trash provides a renewable substitute for fossil fuels.This reduces greenhouse gas emissions and improves energy security.Proper waste management,including trash reduction,recycling,and innovative waste-to-energy technology,reduces the burden on landfills and incineration and creates renewable energy from materials that would otherwise go to waste.Although integrating these techniques is consistent with the CE’s resource efficiency and waste minimization principles,it requires addressing environmental,technical,and socioeconomic challenges.Given the pressing global issues,transitioning to a CE and implementing sustainable environmental practices are crucial to mitigate the current waste management crisis.The aim of this study is to emphasize the viability of biomass as a source of sustainable energy,the necessity of comprehensive strategies that prioritize ecological sustainability,community involvement,and innovation to achieve a circular principle based future,and the potential obstacles to the implementation of sustainable environmental practices.This study will aid in implementing CE practices to accomplish the Sustainable Development Goals(SDGs)by reducing greenhouse gas emissions and landfill loads.Beyond environmental benefits,it can also bring economic,social,and health improvements.Furthermore,this study will assist societies in addressing global issues,such as resource scarcity,pollution,and climate change,as well as transitioning to a more sustainable and resilient future.
基金supported by the National Basic Research Program of China (973 Program, 2014CB238903)the National Natural Science Foundation of China (Nos. 41672144, 41173032, and 41373110)
文摘A series of new biochar-supported composite based on the combination of biochar and metallic nanoparticles(NPs)were produced through single-step pyrolysis of FeCl_3–Ti(OBu)_4 laden agar biomass under NH_3 environment.The physiochemical properties of composites were characterized thoroughly.It has found that heating temperature and N-doping through NH_3-ambiance pyrolysis significantly influence the visible-light sensitivity and bandgap energy of composites.The catalytic activities of composites were measured by degradation of Methylene Blue(MB)in the presence or absence of H_2O_2 and visible-light irradiation.Our best catalyst(N–TiO_2–Fe_3O_4-biochar)exhibits rapid and high MB removal competency(99.99%)via synergism of adsorption,photodegradation,and Fenton-like reaction.Continuous production of O_2U^-and UOH radicles performs MB degradation and mineralization,confirmed by scavenging experiments and degradation product analysis.The local trap state Ti^(3+),Fe_3O_4,and N-carbon of the catalyst acted as active sites.It has suggested that the Ti^(3+)and N-doped dense carbon layer improve charge separation and shuttle that prolonged photo-Fenton like reaction.Moreover,the catalyst is highly stable,collectible,and recyclable up to 5 cycles with high MB degradation efficiency.This work provides a new insight into the synthesis of highly visible-light sensitized biocharsupported photocatalyst through NH_3-ambiance pyrolysis of NPs-laden biomass.