The title compound [Cu （ADC） （2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reve...The title compound [Cu （ADC） （2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure.展开更多
文摘The title compound [Cu （ADC） （2, 2＇-bipy）]n （ADC = C2 （COO）2^2.） was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2＇-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu （Ⅱ） ions, forming coordination polymer structure.
