A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper.The mathematical model is solved by numerical methods based on finite elements combined with the linea...A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper.The mathematical model is solved by numerical methods based on finite elements combined with the linear driving force approximation.A criterion based on the model to identify the diffusion controlling mechanism(macropore diffusion,micropore diffusion,or both)is proposed.The effects of different adsorption isotherms(linear,Freundlich,or Langmuir)on the concentration profiles and on curves of fractional uptake versus time are investigated.In addition,the influences of model parameters concerning the pore networks on the fractional uptake are studied as well.展开更多
基金financial support by the National Natural Science Foundation of China(Grant No.91534120)China National Petroleum Company under the contract number DQZX-KY-17-019
文摘A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper.The mathematical model is solved by numerical methods based on finite elements combined with the linear driving force approximation.A criterion based on the model to identify the diffusion controlling mechanism(macropore diffusion,micropore diffusion,or both)is proposed.The effects of different adsorption isotherms(linear,Freundlich,or Langmuir)on the concentration profiles and on curves of fractional uptake versus time are investigated.In addition,the influences of model parameters concerning the pore networks on the fractional uptake are studied as well.
