期刊文献+
共找到3篇文章
< 1 >
每页显示 20 50 100
氯离子对ChCl-Urea低共熔溶剂中银电沉积的电化学行为影响
1
作者 战充波 张润佳 +4 位作者 付旭 孙海静 周欣 王保杰 孙杰 《电化学》 CAS CSCD 北大核心 2022年第5期68-75,共8页
以氯化胆碱-尿素低共熔溶剂为基础液,使用循环伏安法、计时电流法、Tafel极化曲线、Gerisher交换电流密度法、扫描电子显微镜以及X射线衍射等方法研究了电沉积银过程中的电沉积机理、电结晶行为,以及NH_(4)Cl存在下对配合物、相组成以... 以氯化胆碱-尿素低共熔溶剂为基础液,使用循环伏安法、计时电流法、Tafel极化曲线、Gerisher交换电流密度法、扫描电子显微镜以及X射线衍射等方法研究了电沉积银过程中的电沉积机理、电结晶行为,以及NH_(4)Cl存在下对配合物、相组成以及镀层微观形貌等的影响。结果表明,ChCl-Urea体系中氯离子的加入改变了Ag^(+)的还原电位(vs.Ag|AgCl),镀液中Ag^(+)形成了配合物[AgCl_(n)]^(1-n),使还原电位发生了负移,由-0.85 V负移至-0.98 V。通过拟合CA曲线和理论曲线对比发现,Ag(I)在ChCl-Urea DES中的成核方式与氯离子的浓度有关,低浓度下的成核方式具有三维瞬时成核和三维连续成核的混合成核特征,高浓度下的成核方式符合三维瞬时成核。镀液中主要放电络离子是[AgCl_(2)]^(-)。电沉积得到的是紧密颗粒球状纯银镀层,氯离子的加入抑制了枝晶状银镀层的生成。 展开更多
关键词 氯化胆碱-尿素低共熔溶剂 银电沉积 添加剂 络合物 电化学行为
下载PDF
Effect of phosphate conversion film on fatigue and corrosion fatigue behavior of an as-rolled Mg–3.08Zn–0.83Al(in wt.%)alloy
2
作者 bao-jie wang Dao-kui Xu +2 位作者 Shuo wang Xiang-bo Xu En-hou Han 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2023年第12期2557-2565,共9页
Through investigating and comparing the fatigue behavior of an as-rolled Mg–3.08Zn–0.83Al(in wt.%)alloy performing surface phosphate conversion film treatment,it revealed that the determined fatigue strength of surf... Through investigating and comparing the fatigue behavior of an as-rolled Mg–3.08Zn–0.83Al(in wt.%)alloy performing surface phosphate conversion film treatment,it revealed that the determined fatigue strength of surface treated samples at 106 cycles in air was 65 MPa,whereas the fatigue strength was only 35 MPa when tested in 3.5 wt.%NaCl solution.Failure analysis demonstrated that in air,the fatigue crack initiation was mainly dominated by the interaction between the retarding effect of phosphate conversion film on cyclic slips occurring in the underneath substrate.When the matrix cannot endure the accumulated stress concentration due to the irreversibility of cyclic slips,the fatigue crack will preferentially initiate at sample subsurface.Since the phosphate conversion film cracked easily under the cyclic loading and lost its protectiveness on the substrate in 3.5 wt.%NaCl solution,fatigue cracks were preferentially nucleated at the localized corrosion pits. 展开更多
关键词 Mg alloy Corrosion fatigue Surface film PITTING Crack initiation
原文传递
Research Progress on the Corrosion Behavior of Magnesium-Lithium-Based Alloys: A Review 被引量:13
3
作者 bao-jie wang Ji-Yu Luan +3 位作者 Dao-Kui Xu Jie Sun Chuan-Qiang Li En-Hou Han 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2019年第1期1-9,共9页
In this review paper, the research progress on corrosion behavior of hexagonal close-packed(HCP) singular phase, body cubic-centered(BCC) singular phase and(HCP + BCC) duplex-structured Mg–Li alloys has been summariz... In this review paper, the research progress on corrosion behavior of hexagonal close-packed(HCP) singular phase, body cubic-centered(BCC) singular phase and(HCP + BCC) duplex-structured Mg–Li alloys has been summarized and reviewed, and the future trend about the studies on corrosion behavior of Mg–Li-based alloys and possible solving methods for the improvement in corrosion resistance are discussed also. 展开更多
关键词 Magnesium–lithium ALLOYS Crystallographic structure CORROSION behavior CORROSION product FILM CORROSION mechanism
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部