Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-per...Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-performance and long-term operating devices.In this work,inspired by biological protein,nickelporphyrin(Ni-P)with electron cloud on conjugate ring is applied into Sn-based perovskite to prevent perovskite from being eroded.The synergistic effect of water and oxygen is broken in grain boundaries and surface so that the stability of PSCs can be improved obviously,despite there is hardly any barrier for water to erode.Simultaneously,the electron-rich molecules can passivate the defects of perovskite such as iodine vacancy.Moreover,the ester group in Ni-P molecule can bind with SnI;to form complex and then restrain nucleation.Combining with the template effect of 2D molecular,the crystallization of perovskite films is optimized.Therefore,the Sn-based PSCs with Ni-P achieve a stabilized power conversion efficiency(PCE)of 7.79%with negligible hysteresis in fexible devices,respectively.Moreover,the PSCs can maintain 80%of the pristine PCE after 300 h under air environment.展开更多
Grain boundary cracks in flexible perovskite films can be repaired by filling with self-repairing polymers during the preparation and wearable operation.However,the self-repairing polymers are commonly active through ...Grain boundary cracks in flexible perovskite films can be repaired by filling with self-repairing polymers during the preparation and wearable operation.However,the self-repairing polymers are commonly active through external heating or humidification treatments,which cannot match with the human body's temperature tolerance of wearable devices.Herein,a body temperature-responsive shape memory polyurethane(SMPU)is demonstrated to achieve the real-time mechanical self-repairing of grain boundary cracks(~37°C).Furthermore,the strong intermolecular interaction between SMPU and the uncoordinated Pb2+and I−,can reduce the trap density in perovskite films.The blade-coated device achieves a power conversion efficiency(PCE)of 21.33%,which is among the best reported flexible perovskite solar cells(PSCs;0.10 cm2).Importantly,the device with SMPU can recover more than 80%of the PCE after 6000 cycles(bending radius:8 mm).Finally,the flexible PSCs are used for wearable solar power supply of a smartphone,which show great potential for self-repairing wearable electronics.展开更多
基金support from the National Natural Science Foundation of China(NSFC)(22005131,52173169 and 11564025)。
文摘Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-performance and long-term operating devices.In this work,inspired by biological protein,nickelporphyrin(Ni-P)with electron cloud on conjugate ring is applied into Sn-based perovskite to prevent perovskite from being eroded.The synergistic effect of water and oxygen is broken in grain boundaries and surface so that the stability of PSCs can be improved obviously,despite there is hardly any barrier for water to erode.Simultaneously,the electron-rich molecules can passivate the defects of perovskite such as iodine vacancy.Moreover,the ester group in Ni-P molecule can bind with SnI;to form complex and then restrain nucleation.Combining with the template effect of 2D molecular,the crystallization of perovskite films is optimized.Therefore,the Sn-based PSCs with Ni-P achieve a stabilized power conversion efficiency(PCE)of 7.79%with negligible hysteresis in fexible devices,respectively.Moreover,the PSCs can maintain 80%of the pristine PCE after 300 h under air environment.
基金the support from the National Natural Science Foundation of China(NSFC)(U20A20128,52263027,22379060,52173169 and 52222312)the"Double Thousand Plan"Science and Technology Innovation High-end Talent Project of Jiangxi Province(jxsq2019201049)+2 种基金the Natural Science Foundation of Jiangxi Province(20231ZDH04036,20212BAB214055 and 20224ACB204007)China National Postdoctoral Program for Innovative Talents(BX2021117)China Postdoctoral Science Foundation(2021M700060)。
基金National Key R&D Program of China,Grant/Award Number:2018YFA0208501National Natural Science Foundation of China,Grant/Award Numbers:21401167,22005131,22075296,51803217,5210031012,52173169,91963212+5 种基金Beijing Nova Program from Beijing Municipal ScienceTechnology Commission,Grant/Award Number:Z201100006820037Beijing National Laboratory for Molecular Sciences,Grant/Award Number:BNLMSCXXM-202005Youth Innovation Promotion Association CAS,Grant/Award Number:2020032Key R&D and Promotion Project of Henan Province,Grant/Award Number:192102210032Outstanding Young Talent Research Fund of Zhengzhou University。
文摘Grain boundary cracks in flexible perovskite films can be repaired by filling with self-repairing polymers during the preparation and wearable operation.However,the self-repairing polymers are commonly active through external heating or humidification treatments,which cannot match with the human body's temperature tolerance of wearable devices.Herein,a body temperature-responsive shape memory polyurethane(SMPU)is demonstrated to achieve the real-time mechanical self-repairing of grain boundary cracks(~37°C).Furthermore,the strong intermolecular interaction between SMPU and the uncoordinated Pb2+and I−,can reduce the trap density in perovskite films.The blade-coated device achieves a power conversion efficiency(PCE)of 21.33%,which is among the best reported flexible perovskite solar cells(PSCs;0.10 cm2).Importantly,the device with SMPU can recover more than 80%of the PCE after 6000 cycles(bending radius:8 mm).Finally,the flexible PSCs are used for wearable solar power supply of a smartphone,which show great potential for self-repairing wearable electronics.
