The meteorological early-warning loudspeaker is a specific initiative for the meteorological departments to address the issues concerning issues concerning agriculture,countryside and farmers.Its significance is that ...The meteorological early-warning loudspeaker is a specific initiative for the meteorological departments to address the issues concerning issues concerning agriculture,countryside and farmers.Its significance is that it can promptly deliver the early-warning information concerning some meteorological disasters(such as torrential rains,typhoons,cold wave,hail)to the areas affected,so as to provide reference and protection for agricultural production and effectively reduce the loss of agricultural producers.Up to now,the meteorological early-warning loudspeakers in Benxi have covered the villages.However,due to irregular occurrence of meteorological disasters,the listeners will turn off the information receivers of meteorological early-warning loudspeakers when they fail to receive meteorological information for a long time,so that the users can not promptly know the early-warning information regarding some sudden meteorological disasters.In view of this,the meteorological departments have introduced a series of management measures,such as the daily use of loudspeakers to publish weather forecast information,aimed at improving the online rate and usage rate of meteorological loudspeakers.And the management platform for online rate of meteorological early-warning loudspeakers is an important part of the management system.展开更多
Here,a new designed core/satellite gold nanoprobe was developed for detecting trace mount of benzoyl peroxide(BPO) based on its deboronation.This gold nanoassembly(the BE-Au NPs_(12/65)) wa s constructed via borate es...Here,a new designed core/satellite gold nanoprobe was developed for detecting trace mount of benzoyl peroxide(BPO) based on its deboronation.This gold nanoassembly(the BE-Au NPs_(12/65)) wa s constructed via borate ester formation between large 4-mercaptophenylboronic acid(MPBA) modified Au NPs(the MPBAAu NPs_(65),as cores) and small dopamine modified AuNPs(the D PA-AuNPs_(12),as satellites).Particularly,upon addition of BPO,it would trigger the deboronation for the BE-AuNPs_(12/65) probes accompanying with distinct color changes from blue,purple to wine red,which implied the disassembly of the core/satellite nanostructure after the breakage of carbon to boron chemical bond.By measuring the absorbance ratio at 665 nm and 545 nm,quantification of BPO was achieved in the range of 10.0-100.0 nmol/L,which could also be easily observed by naked eyes.The nanoprobe utilized a boronate deprotection mechanism and the LSPR properties of Au NPs to provide high selectivity for detecting BPO over similar ROS/RNS with the limit of detection as low as 7.2 nmol/L.The practical applicability of this assay was verified through successful determining BPO in flour samples,which demonstrated its great potentials in food safety field.展开更多
文摘The meteorological early-warning loudspeaker is a specific initiative for the meteorological departments to address the issues concerning issues concerning agriculture,countryside and farmers.Its significance is that it can promptly deliver the early-warning information concerning some meteorological disasters(such as torrential rains,typhoons,cold wave,hail)to the areas affected,so as to provide reference and protection for agricultural production and effectively reduce the loss of agricultural producers.Up to now,the meteorological early-warning loudspeakers in Benxi have covered the villages.However,due to irregular occurrence of meteorological disasters,the listeners will turn off the information receivers of meteorological early-warning loudspeakers when they fail to receive meteorological information for a long time,so that the users can not promptly know the early-warning information regarding some sudden meteorological disasters.In view of this,the meteorological departments have introduced a series of management measures,such as the daily use of loudspeakers to publish weather forecast information,aimed at improving the online rate and usage rate of meteorological loudspeakers.And the management platform for online rate of meteorological early-warning loudspeakers is an important part of the management system.
基金financial support from the National Natural Science Foundation of China(Nos.U1736201,21677019 and 41403021)Capital Health Research and Development of Special(No.2018-4-1014)the Key Research and Development Program of Beijing(No.D171100008317001)。
文摘Here,a new designed core/satellite gold nanoprobe was developed for detecting trace mount of benzoyl peroxide(BPO) based on its deboronation.This gold nanoassembly(the BE-Au NPs_(12/65)) wa s constructed via borate ester formation between large 4-mercaptophenylboronic acid(MPBA) modified Au NPs(the MPBAAu NPs_(65),as cores) and small dopamine modified AuNPs(the D PA-AuNPs_(12),as satellites).Particularly,upon addition of BPO,it would trigger the deboronation for the BE-AuNPs_(12/65) probes accompanying with distinct color changes from blue,purple to wine red,which implied the disassembly of the core/satellite nanostructure after the breakage of carbon to boron chemical bond.By measuring the absorbance ratio at 665 nm and 545 nm,quantification of BPO was achieved in the range of 10.0-100.0 nmol/L,which could also be easily observed by naked eyes.The nanoprobe utilized a boronate deprotection mechanism and the LSPR properties of Au NPs to provide high selectivity for detecting BPO over similar ROS/RNS with the limit of detection as low as 7.2 nmol/L.The practical applicability of this assay was verified through successful determining BPO in flour samples,which demonstrated its great potentials in food safety field.