Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)...Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.展开更多
This work reports research concerning the microstructure and sliding wear behaviour of cermet coatings deposited by high velocity oxy-fuel (HVOF) spraying. Two cermets were prepared with the following target compositi...This work reports research concerning the microstructure and sliding wear behaviour of cermet coatings deposited by high velocity oxy-fuel (HVOF) spraying. Two cermets were prepared with the following target compositions namely, Ni (Cr)-65 wt.% TiB2 and Ni (Cr)-40 wt.% TiB2. Coating microstructures were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD), whilst microhardness and sliding wear tests were performed on the coatings to evaluate their performance. The HVOF sprayed deposits had layered, splat-like morphologies typical of thermally sprayed cermets. Coatings consisted primarily of TiB2 particles in a nickel-based binder phase. Other minor peaks in the XRD patterns belong to TiB, Ni2B, NiTiO3 and Ti2Oj. The coatings exhibit an amorphous halo in the diffraction pattern between 2 values of 40° and 50°. Sliding wear behaviour was examined using a conventional ball-on-disc apparatus. A sintered ceramic ball (A12O3) was employed as the counterface. The Ni (Cr)-65 wt.% TiB2 coating had a lower wear rate than Ni (Cr)-40 wt.% TiB2 coating. This may be related to the larger sizes of borides. Wear scar morphologies, on both coatings were examined by using SEM and EDAX detecting in order to establish the wear mechanism. Wear is proposed to proceed by subsurface cracking in these coatings.展开更多
文摘Oxidation behaviors of Ni(Cr)-TiB2 coating deposited by HVOF technique were studied at 800,900 and 1 000℃in air. The microstructures of as-sprayed and oxidized coatings were characterized by X-ray diffractometry(XRD)and scanning electron microscopy(SEM).After oxidation at 800℃,a thin and adherent oxide layer was formed on the surface of the coating.With increasing exposure temperature,the thickness of the oxide layer increased;and at 1 000℃the oxide layer separated from the coating.Investigation of the kinetics of oxidation by using the thermogravimetric analysis(TGA)technique shows a parabolic oxidation rate.
文摘This work reports research concerning the microstructure and sliding wear behaviour of cermet coatings deposited by high velocity oxy-fuel (HVOF) spraying. Two cermets were prepared with the following target compositions namely, Ni (Cr)-65 wt.% TiB2 and Ni (Cr)-40 wt.% TiB2. Coating microstructures were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD), whilst microhardness and sliding wear tests were performed on the coatings to evaluate their performance. The HVOF sprayed deposits had layered, splat-like morphologies typical of thermally sprayed cermets. Coatings consisted primarily of TiB2 particles in a nickel-based binder phase. Other minor peaks in the XRD patterns belong to TiB, Ni2B, NiTiO3 and Ti2Oj. The coatings exhibit an amorphous halo in the diffraction pattern between 2 values of 40° and 50°. Sliding wear behaviour was examined using a conventional ball-on-disc apparatus. A sintered ceramic ball (A12O3) was employed as the counterface. The Ni (Cr)-65 wt.% TiB2 coating had a lower wear rate than Ni (Cr)-40 wt.% TiB2 coating. This may be related to the larger sizes of borides. Wear scar morphologies, on both coatings were examined by using SEM and EDAX detecting in order to establish the wear mechanism. Wear is proposed to proceed by subsurface cracking in these coatings.
