Novel orange-red Sr_(2)GdSbO_(6):xEu^(3+)(x=0,0.05,0.1,0.2,0.3,0.4,0.5 and 0.6) phospho rs were successfully prepared by the traditional high-temperature solid-state method.The results of Rietveld refinement,energy di...Novel orange-red Sr_(2)GdSbO_(6):xEu^(3+)(x=0,0.05,0.1,0.2,0.3,0.4,0.5 and 0.6) phospho rs were successfully prepared by the traditional high-temperature solid-state method.The results of Rietveld refinement,energy dispersive spectroscopy(EDS) spectrum and elemental mapping demonstrate that Eu^(3+) successfully replaces the Gd^(3+) sites and distributes uniformly in the particles of phosphors.The luminescence properties of Sr_(2)GdSbO_(6):Eu_(3+)phosphors were investigated in detail.The emission spectra of the strongest emission peak is the ^(5)D_(0)→^(7)F_(1)(593 nm) transition,which can emit orange-red light under393 nm excitation.When the doping concentration of Eu3+ions is x=0.2,the luminescence intensity of the phosphors reaches the highest.The detailed mechanism of concentration quenching is attributed to dipole-dipole interaction.The thermal stability values of Sr_(2)GdSbO_(6):0.2Eu^(3+) phosphors are 87%,82% and114% under 393,467 and 527 nm excitations,respectively.The causes of the abnormal thermal quenching under 527 nm excitation were analyzed.Based on the abnormal thermal quenching under527 nm excitation,the optical thermometry properties of Sr_(2)GdSbO_(6):0.2Eu^(3+)phosphors were investigated by fluorescence intensity ratio(FIR) technique,and appreciable relative sensitivity was obtained.The results suggest that Sr_(2)GdSbO_(6):0.2Eu^(3+)phosphors can be potentially applied to w-LEDs and optical thermometers.展开更多
基金supported by the National Natural Science Foundation of China (52262020)Guizhou Provincial Department of Education Science and Technology Uprooted Talents Project ([2022] 085)+1 种基金Guizhou Provincial Department of Education Rolling Support for Provincial Universities Scientific Research Platform Team Project ([2022] 036)the Science and Technology Foundation of Guizhou Province (ZK [2021] 328)。
文摘Novel orange-red Sr_(2)GdSbO_(6):xEu^(3+)(x=0,0.05,0.1,0.2,0.3,0.4,0.5 and 0.6) phospho rs were successfully prepared by the traditional high-temperature solid-state method.The results of Rietveld refinement,energy dispersive spectroscopy(EDS) spectrum and elemental mapping demonstrate that Eu^(3+) successfully replaces the Gd^(3+) sites and distributes uniformly in the particles of phosphors.The luminescence properties of Sr_(2)GdSbO_(6):Eu_(3+)phosphors were investigated in detail.The emission spectra of the strongest emission peak is the ^(5)D_(0)→^(7)F_(1)(593 nm) transition,which can emit orange-red light under393 nm excitation.When the doping concentration of Eu3+ions is x=0.2,the luminescence intensity of the phosphors reaches the highest.The detailed mechanism of concentration quenching is attributed to dipole-dipole interaction.The thermal stability values of Sr_(2)GdSbO_(6):0.2Eu^(3+) phosphors are 87%,82% and114% under 393,467 and 527 nm excitations,respectively.The causes of the abnormal thermal quenching under 527 nm excitation were analyzed.Based on the abnormal thermal quenching under527 nm excitation,the optical thermometry properties of Sr_(2)GdSbO_(6):0.2Eu^(3+)phosphors were investigated by fluorescence intensity ratio(FIR) technique,and appreciable relative sensitivity was obtained.The results suggest that Sr_(2)GdSbO_(6):0.2Eu^(3+)phosphors can be potentially applied to w-LEDs and optical thermometers.
