Here we reported the fabrication of efficient polymer solar cells from regioregular poly（3-hexylthiophene） （P3HT）：fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester （PC6jBM） mixtures, in which solu...Here we reported the fabrication of efficient polymer solar cells from regioregular poly（3-hexylthiophene） （P3HT）：fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester （PC6jBM） mixtures, in which solution- processed vanadium oxide （VOx） was used as a hole-extracting layer （HEL）. The obtained devices exhibited a high power conversion efficiency of 3.96%, and can be enhanced to 4.06% and 4.16%, respectively, when two types of PEDOT：PSS with different conductivities were used in conjunction with the VOx layer. All the VOx-based devices showed a high fill factor （FF） over 70%, which was ascribed to efficient hole extracting efficiency associated with the solution-processed VOx hole-extracting layer. The origins of the improvement were also studied by transmission spectra, atomic force microscope （AFM）, and capacitance-voltage characteristics.展开更多
基金H.-B.W.sincerely thank National Basic Research Program of China，National Natural Science Foundation of China，Program for New Century Excellent Talents in University (NCET-10-0400) for the financial support
文摘Here we reported the fabrication of efficient polymer solar cells from regioregular poly（3-hexylthiophene） （P3HT）：fullerene derivative [6,6]-phenyl-C61 butyric acid methyl ester （PC6jBM） mixtures, in which solution- processed vanadium oxide （VOx） was used as a hole-extracting layer （HEL）. The obtained devices exhibited a high power conversion efficiency of 3.96%, and can be enhanced to 4.06% and 4.16%, respectively, when two types of PEDOT：PSS with different conductivities were used in conjunction with the VOx layer. All the VOx-based devices showed a high fill factor （FF） over 70%, which was ascribed to efficient hole extracting efficiency associated with the solution-processed VOx hole-extracting layer. The origins of the improvement were also studied by transmission spectra, atomic force microscope （AFM）, and capacitance-voltage characteristics.
