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低温NH_3-SCR新型MnO_x@TiO_2纳米棒核壳结构催化剂的合成及抗SO_2性能研究(英文) 被引量:9
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作者 盛重义 麻丁仁 +4 位作者 俞丹青 肖香 黄冰洁 杨柳 王圣 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第4期821-830,共10页
氮氧化物(NO_x)是造成大气污染的主要来源之一,严重威胁人类的身体健康.选择性催化还原(SCR)技术由于其独特的优势而受到青睐.但SCR催化剂容易受到SO_2的侵蚀而失活,使用寿命降低.开发具有抗硫能力强的高活性催化剂已成为脱硝技术研究... 氮氧化物(NO_x)是造成大气污染的主要来源之一,严重威胁人类的身体健康.选择性催化还原(SCR)技术由于其独特的优势而受到青睐.但SCR催化剂容易受到SO_2的侵蚀而失活,使用寿命降低.开发具有抗硫能力强的高活性催化剂已成为脱硝技术研究的热点.核壳结构催化剂由于其独特的外壳结构能有效地减少活性物质与SO_2的接触,减少催化剂中毒,延长催化剂的使用寿命.而水热合成法能有效控制催化剂的外形结构,动力学外裹法能将物质均匀分布在被包裹物质的表面,两者结合有利于核壳结构催化剂的合成.本文采用两步法(水热法+动力学外包裹法)制备的MnO_x@TiO_2纳米棒核壳结构低温脱硝催化剂具有高活性、高稳定性和优异的N2选择性.此外,与MnO_x,TiO_2和MnO_x/TiO_2等纳米材料相比,MnO_x@TiO_2具有更好的SO_2和H2O抗性,表明MnO_x@TiO_2具备良好的运用前景.采用TEM,HR-TEM,XRD,Raman,BET,XPS,NH3-TPD和H2-TPR等方法对催化剂进行了系统的表征.TEM和HR-TEM结果表明,MnO_x@TiO_2表现出明显的核壳结构,且TiO_2颗粒均匀分布在MnO_x纳米棒上.XRD和Raman结果发现MnO_x@TiO_2中含有MnO_2,从而保证了MnO_x@TiO_2具有良好的脱硝活性.同时,BET,NH3-TPD和H2-TPR等结果表明,MnO_x@TiO_2具有丰富的中孔结构和路易斯酸位点,以及强氧化还原能力,因而其催化性能提高.根据SO_2侵蚀后的XPS结果,MnO_x@TiO_2与MnO_x/TiO_2相比,两者中的S元素含量差异小,但前者中的Mn4+降低量远少于后者.表明MnO_x@TiO_2的核壳结构可以在SO_2存在条件下有效地保护活性位点。 展开更多
关键词 低温选择性催化还原 核壳结构 纳米棒 二氧化硫抗性 锰氧化物
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Construction of databases:advances and significance in clinical research 被引量:1
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作者 Erping Long bingjie huang +2 位作者 Liming Wang Xiaoyu Lin Haotian Lin 《Eye Science》 CAS 2015年第4期184-189,共6页
Widely used in clinical research, the database is a new type of data management automation technology and the most efficient tool for data management. In this article, we first explain some basic concepts, such as the... Widely used in clinical research, the database is a new type of data management automation technology and the most efficient tool for data management. In this article, we first explain some basic concepts, such as the definition, classification, and establishment of databases. Afterward, the workflow for establishing databases, inputting data, verifying data, and managing databases is presented. Meanwhile, by discussing the application of databases in clinical research, we illuminate the important role of databases in clinical research practice. Lastly, we introduce the reanalysis of randomized controlled trials(RCTs) and cloud computing techniques, showing the most recent advancements of databases in clinical research. 展开更多
关键词 数据库建设 临床 随机对照试验 数据管理 自动化技术 管理数据库 输入数据 工作流程
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Effect of Several Common Processing Methods on Content Changes of Resistant Starch and Main Nutrients in ‘Luotian Chestnut’
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作者 Linling LI bingjie huang +3 位作者 Hua CHENG Xuehua ZHANG Xiaoling CHEN Shuiyuan CHENG 《Agricultural Biotechnology》 CAS 2018年第5期92-96,共5页
Using 'Luotian chestnut' as the raw material, the content changes of resistant starch and main nutrients in the processed fruit were studied after taken common processing of high-temperature steaming of canned food,... Using 'Luotian chestnut' as the raw material, the content changes of resistant starch and main nutrients in the processed fruit were studied after taken common processing of high-temperature steaming of canned food, sand-mixed frying and cooking without shells, with the aim to find out the effects of different processing methods on the content changes of nutrients in chestnuts. The result showed that there were significant differences in the resistant starch contents by different processing methods. After processing, the retention degree of resistant starch was the lowest using the methods of sand-mixed frying, of 42.42%, while the highest was found in canned chestnut products, of 93.16%. Among the main nutrients, adding water and sugar would reduce content of resistant starch, while increasing the protein content would promote the retention of resistant starch retention. The changes in lipid content had no effect or not a single promoting or weakening effects on the content of resistant starch. 展开更多
关键词 CHESTNUT Resistant starch NUTRIENTS
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Novel CeO_2@TiO_2 core–shell nanostructure catalyst for selective catalytic reduction of NOx with NH_3 被引量:15
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作者 bingjie huang Danqing Yu +1 位作者 Zhongyi Sheng Liu Yang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第5期129-136,共8页
The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction (SCR) of NOx with NH3 in this study. The catalyst presented the obvious core-shel... The CeO2@TiO2 core-shell nanostructure catalyst prepared by a two-step hydrothermal method was used for selective catalytic reduction (SCR) of NOx with NH3 in this study. The catalyst presented the obvious core-shell structure, and the shell was amorphous TiO2 which could protect the active center from the SO2 erosion. The catalyst showed high activity and stability, excellent N2 selectivity and superior SO2 resistance and H2O tolerance. Characterizations such as TEM, HR-TEM, XRD, BET, XPS, NH3-TPD, and H2-TPR were carried out. The results indicated that the catalyst had large surface area and the active sites were well dispersed on the surface. The NH3-TPD, H2-TPR and XPS results implied that its increased SCR activity might be due to the enhancement of NH3 chemisorption and the increase of active oxygen species, both of which were conductive to NH3 activation. The excellent catalytic performance suggests that it is a promising candidate for SCR catalyst. 展开更多
关键词 SCR Core-shell SO2 resistance CeO2 TiO2
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