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高分散的Pt促进氨分解中活性Fe_(x)N的形成 被引量:1
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作者 Keshia Saradima Indriadi 韩沛杰 +4 位作者 丁世鹏 姚冰清 Shinya Furukawa 何迁 颜宁 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2023年第7期297-305,共9页
在氢经济的背景下,氨分解在制氢中起着重要作用.铁基催化剂因价格低廉且活性适中而备受欢迎,对大规模应用具有吸引力.然而,铁基催化剂向更高活性Fe_(x)N物种的转化较慢,导致诱导期延长.为了解决该问题,本文研究了在氨分解中添加Pt对Fe_(... 在氢经济的背景下,氨分解在制氢中起着重要作用.铁基催化剂因价格低廉且活性适中而备受欢迎,对大规模应用具有吸引力.然而,铁基催化剂向更高活性Fe_(x)N物种的转化较慢,导致诱导期延长.为了解决该问题,本文研究了在氨分解中添加Pt对Fe_(x)N形成的影响.结果表明,即使添加少量(0.1 wt%)Pt,也能显著提高Fe_(x)N的形成速率,使其增加3倍以上.Pt通过反溢流促进H_(2)脱附,相反,反溢流暴露出更多发生氮化的Fe表面位点,导致Fe_(x)N的形成.高角度环形暗场扫描透射电子显微镜、X射线衍射和原位X射线吸收光谱表征揭示了Fe2N活性物质的形成.H_(2)程序升温脱附、H_(2)程序升温还原和原位X射线吸收谱证实了氢反溢流和溢流效应的存在.总之,本文加深了对铁催化剂在氨分解中活性物种形成机制的理解,为提高其催化性能提供了一个简单策略. 展开更多
关键词 氨分解 氮化铁 氮化 Pt促进 氢反溢流
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Effect of Aging Parameters on Inconel 718 Fabricated by Laser Directed Energy Deposition 被引量:1
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作者 Nataniel Yong Syn Tham Grace Rui Si Tay +2 位作者 bingqing yao Kaiqiang Wu ZhiLi Dong 《Chinese Journal of Mechanical Engineering(Additive Manufacturing Frontiers)》 2023年第4期112-121,共10页
Inconel 718 is a nickel-based superalloy of high interest in high temperature applications such as turbine parts.To be used in such applications,heat treatments are commonly applied to dissolute Laves phase and to ach... Inconel 718 is a nickel-based superalloy of high interest in high temperature applications such as turbine parts.To be used in such applications,heat treatments are commonly applied to dissolute Laves phase and to achieve𝛾γ′phase.However,conventional heat treatment methods for wrought Inconel 718 may not be suitable for Inconel 718 fabricated by laser directed energy deposition(LDED)due to its unique microstructure formed during the rapid solidification process.There has been a lack of investigation in heat treatments for Inconel 718 fabricated by this process,specifically around the impact of aging parameters on this alloy.In this study,the effects of aging parameters were studied by performing seven different heat treatments,including solutionising and aging treatments.Our results indicate that for LDED Inconel 718,a high temperature solution treatment of 1100℃for 1 h followed by single aging at 650℃for 20 h achieved a tensile strength and elongation of 1247 MPa and 23%,respectively.Further,results indicated that even with a shorter aging time of 10 h,γ′phase was found to be of comparable size to the standard double aged treatment. 展开更多
关键词 Inconel 718 Laser directed energy deposition Heat treatment Microstructure Additive manufacturing
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