Possible Room-Temperature Ferromagnetic Semiconductors

Magnetic semiconductors integrate the dual characteristics of magnets and semiconductors.It is difficult to manufacture magnetic semiconductors that function at room temperature.Here,we review a series of our recent theoretical predictions on room-temperature ferromagnetic semiconductors.Since the creation of two-dimensional(2D)magnetic semiconductors in 2017,there have been numerous developments in both experimental and theoretical investigations.By density functional theory calculations and model analysis,we recently predicted several2D room-temperature magnetic semiconductors,including CrGeSe_(3)with strain,CrGeTe_(3)/PtSe_(2) heterostructure,and technetium-based semiconductors(TcSiTe_(3),TcGeSe_(3),and TcGeTe_(3)),as well as PdBr_(3)and PtBr_(3)with a potential room-temperature quantum anomalous Hall effect.Our findings demonstrated that the Curie temperature of these 2D ferromagnetic semiconductors can be dramatically enhanced by some external fields,such as strain,construction of heterostructure,and electric field.In addition,we proposed appropriate doping conditions for diluted magnetic semiconductors,and predicted the Cr doped GaSb and InSb as possible room-temperature magnetic semiconductors.

High temperature magnetic semiconductors: narrow band gaps and two-dimensional systems

Magnetic semiconductors have been demonstrated to work at low temperatures, but not yet at room temperature for spin electronic applications. In contrast to the p-type diluted magnetic semiconductors, n-type diluted magnetic semiconductors are few. Using a combined method of the density function theory and quantum Monte Carlo simulation, we briefly discuss the recent progress to obtain diluted magnetic semiconductors with both p- and n-type carriers by choosing host semiconductors with a narrow band gap. In addition, the recent progress on two-dimensional intrinsic magnetic semiconductors with possible room temperature ferromangetism and quantum anomalous Hall effect are also discussed.

Regulation of P450 TleB catalytic flow for the synthesis of sulfur-containing indole alkaloids by substrate structure-directed strategy and protein engineering

Indole alkaloids have attracted considerable attention from synthetic chemists and biochemists for their structural diversity and important biological activities.Compared with traditional organic synthesis methods,the strategy of using cytochrome P450s'extraordinary abilities to selectively activate carbon-hydrogen bonds to assist in the synthesis of various indole alkaloids has the characteristics of short synthetic route,mild conditions and high atomic economy.Here,we utilized P450 monooxygenases HinD and TleB to synthesize a novel 6/5/8 tricyclic product from(S)-N-((S)-1-(4-fluoro-1H-indol-3-yl)-3-hydroxypropan-2-yl)-2-mercapto-3-methylbutanamide through the substrate structure-directed strategy.TleB was more effective in catalyzing C–S coupling,and was used to synthesize a series of 6/5/8 tricyclic indololactam derivatives to provide drug candidates.Interestingly,the S–S coupling product was observed in HinD catalysis,which was a minor product in the wild-type TleB catalysis.With the help of protein engineering,we accurately regulated the catalytic flow and reversed the selectivity of TleB to obtain the S–S coupling product.At the same time,the reaction mechanism was reasonably speculated by means of site blocking and protein-substrate complex analysis.

Superconducting,Topological,and Transport Properties of Kagome Metals CsTi_(3)Bi_(5)and RbTi_(3)Bi_(5)

The recently discovered ATi_(3)Bi_(5)(A=Cs,Rb)exhibit intriguing quantum phenomena including superconductivity,electronic nematicity,and abundant topological states.ATi_(3)Bi_(5)present promising platforms for studying kagome superconductivity,band topology,and charge orders in parallel with AV3Sb5.In this work,we comprehensively analyze various properties of ATi_(3)Bi_(5)covering superconductivity under pressure and doping,band topology under pressure,thermal conductivity,heat capacity,electrical resistance,and spin Hall conductivity(SHC)using first-principles calculations.Calculated superconducting transition temperature(Tc)of CsTi_(3)Bi_(5)and RbTi_(3)Bi_(5)at ambient pressure are about 1.85 and 1.92 K.When subject to pressure,Tc of CsTi_(3)Bi_(5)exhibits a special valley and dome shape,which arises from quasi-two-dimensional compression to three-dimensional isotropic compression within the context of an overall decreasing trend.Furthermore,Tc of RbTi_(3)Bi_(5)can be effectively enhanced up to 3.09 K by tuning the kagome van Hove singularities(VHSs)and flat band through doping.Pressures can also induce abundant topological surface states at the Fermi energy(EF)and tune VHSs across EF.Additionally,our transport calculations are in excellent agreement with recent experiments,confirming the absence of charge density wave.Notably,SHC of CsTi_(3)Bi_(5)can reach up to 226h·(e·Ω·cm)^(-1)at EF.Our work provides a timely and detailed analysis of the rich physical properties for ATi_(3)Bi_(5),offering valuable insights for further experimental verifications and investigations in this field.

A toughness based deformation limit for X- and K-joints under brace axial tension

This study reports a deformation limit for the initiation of ductile fracture failure in fatigue-cracked circular hollow section （CHS） X- and K-joints subjected to brace axial tension. The proposed approach sets the deformation limit as the numerically computed crack driving force in a fatigue crack at the hot-spot location in the tubular joint reaches the material fracture toughness measured from standard fracture specimens. The calibration of the numerical procedure predicates on reported numerical computations on the crack driving force and previously published verification study against large-scale CHS X-joints with fatigue generated surface cracks. The development of the deformation limit includes a normalization procedure, which covers a wide range of the geometric parameters and material toughness levels. The lower-bound deformation limits thus developed follow a linear relationship with respect to the crack-depth ratio for both X- and K-joints. Comparison of the predicated deformation limit against experimental on cracked tubular X- and K- joints demonstrates the conservative nature of the proposed deformation limit. The proposed deformation limit, when extrapolated to a zero crack depth, provides an estimate on the deformation limits for intact X- and K-joints under brace axial loads.

The Roles of acyI-CoA： Diacylglycerol Acyltransferase 2 Genes in the Biosynthesis of Triacylglycerols by the Green Algae Chlamydomonas reinhardtii

Dear Editor, Triacylglycerols （triglycerides） （TAGs）, as the major storage forms of energy, mainly are stored in adipocytes, myocytes, enterocytes, hepatocytes, and mammary epithelial cells in mammals, oilseeds in plants, and lipid droplets in microorgan- isms （Yen et al., 2008）. Aside from energy storage, TAGs have essential functions in multiple physiological processes. In plants, TAGs are crucial for seed oil accumulation, germina- tion, and seedling development （Zhang et al., 2005, 2009）. Notably, TAGs derived from plants and microorganisms could serve as the feedstock for biofuels production （Deng et al., 2009）. Therefore, understanding of the molecular basis of TAGs bio- synthesis and storage is of considerable economic importance.

Survey of Safety Management Approaches to Unmanned Aerial Vehicles and Enabling Technologies

Unmanned aerial vehicle(UAV)has a rapid development over the last decade.However,an increasing number of severe flight collision events caused by explosive growth of UAV have drawn widespread concern.It is an important issue to investigate safety management approaches of UAVs to ensure safe and efficient operation.In this paper,we present a comprehensive overview of safety management approaches in large,middle and small scales.In large-scale safety management,path-planning problem is a crucial issue to ensure safety and ordered operation of UAVs globally.In middle-scale safety management,it is an important issue to study the conflict detection and resolution methods.And in small-scale safety management,real-time collision avoidance is the last line of ensuring safety.Moreover,a UAV can be regarded as a terminal device connected through communication and information network.Therefore,the enabling technologies,such as sensing,command and control communication,and collaborative decision-making control technology,have been studied in the last.