Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and ...Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability gamma of 5.18x10(-32) esu via heterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.展开更多
Actinide elements encaged in a superatomic cluster can exhibit unique properties due to their hyperactive valence electrons. Herein, the electronic and spectroscopic properties of Th@Au14 are predicted and compared wi...Actinide elements encaged in a superatomic cluster can exhibit unique properties due to their hyperactive valence electrons. Herein, the electronic and spectroscopic properties of Th@Au14 are predicted and compared with that of the isoelectronic entities [Ac@Au14]- and [Pa@Au14]＋ using density functional theory. The calculation results indicate that these clusters all adopt a closed- shell superatomic 18-electron configuration of the 1S21p61D10 Jellium state. The absorption spectrum of Th@Au14 can be interpreted by the Jelliumatic orbital model. In addition, calculated spectra of pyridine-Th@Au14 complexes in the blue laser band exhibit strong peaks attributable to charge transfer （CT） from the metal to the pyridine molecule. These charge-transfer bands lead to a resonant surface-enhanced Raman scattering （SERS） enhancement of -104. This work suggests a basis for designing and synthesizing SERS substrate materials based on actinide-embedded gold superatom models.展开更多
文摘Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability gamma of 5.18x10(-32) esu via heterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.
基金Acknowledgements We would like to thank Drs. Jun Liu and Lei Chen for the stimulating discussions. We would also like to acknowledge the support of the National Natural Science Foundation of China （No. 11374004） and the Science and Technology Development Program of Jilin Province of China （No. 20150519021JH）. Z. W. also acknowledges the Fok Ying Tung Education Foundation （No. 142001） and High Performance Computing Center of Jilin University.
文摘Actinide elements encaged in a superatomic cluster can exhibit unique properties due to their hyperactive valence electrons. Herein, the electronic and spectroscopic properties of Th@Au14 are predicted and compared with that of the isoelectronic entities [Ac@Au14]- and [Pa@Au14]＋ using density functional theory. The calculation results indicate that these clusters all adopt a closed- shell superatomic 18-electron configuration of the 1S21p61D10 Jellium state. The absorption spectrum of Th@Au14 can be interpreted by the Jelliumatic orbital model. In addition, calculated spectra of pyridine-Th@Au14 complexes in the blue laser band exhibit strong peaks attributable to charge transfer （CT） from the metal to the pyridine molecule. These charge-transfer bands lead to a resonant surface-enhanced Raman scattering （SERS） enhancement of -104. This work suggests a basis for designing and synthesizing SERS substrate materials based on actinide-embedded gold superatom models.
