Carbon nitride(C_(3)N_(4))holds great promise for photocatalytic H_(2)O_(2)production from oxygen reduction.In spite of great research efforts,they still suffer from low catalytic efficiency primarily limited by the f...Carbon nitride(C_(3)N_(4))holds great promise for photocatalytic H_(2)O_(2)production from oxygen reduction.In spite of great research efforts,they still suffer from low catalytic efficiency primarily limited by the fast recombination of photogenerated charge carriers.In this work,we report the multiscale structural engineering of C_(3)N_(4)to significantly improve its optoelectronic properties and consequently photocatalytic performance.The product consists of porous spheres with high surface areas,abundant nitrogen defects,and alkali metal doping.Under visible light irradiation,our catalyst shows a remarkable H_(2)O_(2)production rate of 3,080μmol·g^(−1)·h^(−1),which is more than 10 times higher than that of bulk C_(3)N_(4)and exceeds those of most other C_(3)N_(4)-based photocatalysts.Moreover,the catalyst exhibits great stability,and can continuously work for 15 h without obvious activity decay under visible light irradiation,eventually giving rise to a high H_(2)O_(2)concentration of ca.45 mM.展开更多
基金the financial support from the National Key R&D Program of China(No.2017YFA0204800)the National Natural Science Foundation of China(No.22002100)the Collaborative Innovation Center of Suzhou Nano Science and Technology,and the 111 Project and Joint International Research Laboratory of Carbon-Based Functional Materials and Devices.
文摘Carbon nitride(C_(3)N_(4))holds great promise for photocatalytic H_(2)O_(2)production from oxygen reduction.In spite of great research efforts,they still suffer from low catalytic efficiency primarily limited by the fast recombination of photogenerated charge carriers.In this work,we report the multiscale structural engineering of C_(3)N_(4)to significantly improve its optoelectronic properties and consequently photocatalytic performance.The product consists of porous spheres with high surface areas,abundant nitrogen defects,and alkali metal doping.Under visible light irradiation,our catalyst shows a remarkable H_(2)O_(2)production rate of 3,080μmol·g^(−1)·h^(−1),which is more than 10 times higher than that of bulk C_(3)N_(4)and exceeds those of most other C_(3)N_(4)-based photocatalysts.Moreover,the catalyst exhibits great stability,and can continuously work for 15 h without obvious activity decay under visible light irradiation,eventually giving rise to a high H_(2)O_(2)concentration of ca.45 mM.
