Lead halide perovskite nanocrystals have recently demonstrated great potential as x-ray scintillators,yet they stll suffer toxicity issues,inferior light yield(LY)caused by severe self-absorption.Nontoxic bivalent eur...Lead halide perovskite nanocrystals have recently demonstrated great potential as x-ray scintillators,yet they stll suffer toxicity issues,inferior light yield(LY)caused by severe self-absorption.Nontoxic bivalent europium ions(Eu^(2+))with intrinsically efficient and self-absorption-free d-f transition are a prospective replacement for the toxic Pb^(2+).Here,we demonstrated solution-processed organic-inorganic hybrid halide BA_(10)Eul_(12)(BA denotes C_(4)H_(9)NH_(4)^(+))single crystals for the first time.展开更多
Metasurfaces,also known as 2D artificial metamaterials,are attracting great attention due to their unprecedented performances and functionalities that are hard to achieve by conventional diffractive or refractive elem...Metasurfaces,also known as 2D artificial metamaterials,are attracting great attention due to their unprecedented performances and functionalities that are hard to achieve by conventional diffractive or refractive elements.With their sub-wavelength optical scatterers,metasurfaces have been utilized to freely modify different characteristics of incident light such as amplitude,polarization,phase,and frequency.Compared to traditional bulky lenses,metasurface lenses possess the advantages of flatness,light weight,and compatibility with semiconductor manufacture technology.They have been widely applied to a range of scenarios including imaging,solar energy harvesting,optoelectronic detection,etc.In this review,we will first introduce the fundamental design principles for metalens,and then report recent theoretical and experimental progress with emphasis on methods to correct chromatic and monochromatic aberrations.Finally,typical applications of metalenses and corresponding design rules will be presented,followed by a brief outlook on the prospects and challenges of this field.展开更多
Cadmium selenide(CdSe)belongs to the binary II-VI group semiconductor with a direct bandgap of~1.7 eV.The suitable bandgap,high stability,and low manufacturing cost make CdSe an extraordinary candidate as the top cell...Cadmium selenide(CdSe)belongs to the binary II-VI group semiconductor with a direct bandgap of~1.7 eV.The suitable bandgap,high stability,and low manufacturing cost make CdSe an extraordinary candidate as the top cell material in silicon-based tandem solar cells.However,only a few studies have focused on CdSe thin-film solar cells in the past decades.With the advantages of a high deposition rate(~2µm/min)and high uniformity,rapid thermal evaporation(RTE)was used to maximize the use efficiency of CdSe source material.A stable and pure hexagonal phase CdSe thin film with a large grain size was achieved.The CdSe film demonstrated a 1.72 eV bandgap,narrow photoluminescence peak,and fast photoresponse.With the optimal device structure and film thickness,we finally achieved a preliminary efficiency of 1.88%for CdSe thin-film solar cells,suggesting the applicability of CdSe thin-film solar cells.展开更多
基金the National Key R&D Program of China(grant no.2021YFB3501800)the National Natural Science Foundation of China(62250003,61725401,62104077,62204092,62004076,and 62134003)+2 种基金the Postdoctoral Research Foundation of China(2022M710054)the Foundation for Innovative Research Groups of Hubei Province of China(2020CFA034)This research is also supported by the Open Project Program of Wuhan National Laboratory for Optoelectronics(no.2022WNLOKF004).
文摘Lead halide perovskite nanocrystals have recently demonstrated great potential as x-ray scintillators,yet they stll suffer toxicity issues,inferior light yield(LY)caused by severe self-absorption.Nontoxic bivalent europium ions(Eu^(2+))with intrinsically efficient and self-absorption-free d-f transition are a prospective replacement for the toxic Pb^(2+).Here,we demonstrated solution-processed organic-inorganic hybrid halide BA_(10)Eul_(12)(BA denotes C_(4)H_(9)NH_(4)^(+))single crystals for the first time.
基金We thank Prof.Wei Wu,Prof.Jianguo Guan,Dr.Hao Yang,and Dr.Yunxiang Wang for helpful discussions.Boxiang Song would like to acknowledge support from the National Natural Science Foundation of China(Grant No.6210031401).
文摘Metasurfaces,also known as 2D artificial metamaterials,are attracting great attention due to their unprecedented performances and functionalities that are hard to achieve by conventional diffractive or refractive elements.With their sub-wavelength optical scatterers,metasurfaces have been utilized to freely modify different characteristics of incident light such as amplitude,polarization,phase,and frequency.Compared to traditional bulky lenses,metasurface lenses possess the advantages of flatness,light weight,and compatibility with semiconductor manufacture technology.They have been widely applied to a range of scenarios including imaging,solar energy harvesting,optoelectronic detection,etc.In this review,we will first introduce the fundamental design principles for metalens,and then report recent theoretical and experimental progress with emphasis on methods to correct chromatic and monochromatic aberrations.Finally,typical applications of metalenses and corresponding design rules will be presented,followed by a brief outlook on the prospects and challenges of this field.
基金the National NaturalScience Foundation of China (Grant Nos. 61725401, 61904058,and 62050039)the National Key R&D Program of China (No.2016YFA0204000)+2 种基金the Innovation Fund of WNLO, National PostdoctoralProgram for Innovative Talent (No. BX20190127)the Graduates’ InnovationFund of Huazhong University of Science and Technology (No.2020yjsCXCY003)China Postdoctoral Science Foundation Project(Nos. 2019M662623 and 2020M680101).
文摘Cadmium selenide(CdSe)belongs to the binary II-VI group semiconductor with a direct bandgap of~1.7 eV.The suitable bandgap,high stability,and low manufacturing cost make CdSe an extraordinary candidate as the top cell material in silicon-based tandem solar cells.However,only a few studies have focused on CdSe thin-film solar cells in the past decades.With the advantages of a high deposition rate(~2µm/min)and high uniformity,rapid thermal evaporation(RTE)was used to maximize the use efficiency of CdSe source material.A stable and pure hexagonal phase CdSe thin film with a large grain size was achieved.The CdSe film demonstrated a 1.72 eV bandgap,narrow photoluminescence peak,and fast photoresponse.With the optimal device structure and film thickness,we finally achieved a preliminary efficiency of 1.88%for CdSe thin-film solar cells,suggesting the applicability of CdSe thin-film solar cells.
