Mn-CeOff-l＇i-pillared clay （PILC） is an attrac- tive catalyst for selective catalytic reduction of NOx at low temperature because of its low cost. The poisoning of K and Ca on the catalyst of Mn-CeOx/Ti-PILC is an ...Mn-CeOff-l＇i-pillared clay （PILC） is an attrac- tive catalyst for selective catalytic reduction of NOx at low temperature because of its low cost. The poisoning of K and Ca on the catalyst of Mn-CeOx/Ti-PILC is an important problem because K and Ca are always in presence in flue gas. To investigate the effect of K and Ca on the physicochemical characters of the catalysts, the techniques of NH3-temperature programmed desorption （TPD）, H2-temperature programmed reduction （TPR）, and X-ray photoelectron spectroscopy （XPS） were used to analyze the fresh and deactivated catalysts of Mn-CeOJTi- PILC. （Ca）Mn-CeOx/Ti-PILC and （K）Mn-CeOx/Ti-PILC are denoted for the dopes of the catalyst of Mn-CeOJTi- PILC with Ca and K, respectively. The activities of Mn- CeOx/Ti-PILC, （Ca）Mn-CeOx/Ti-PILC and （K）Mn-CeOx/ Ti-PILC for NH3-selective catalytic reduction （SCR） reaction at low temperature were investigated. The results showed that with the dopes of K and Ca on the catalysts, the SCR activities of the catalysts decreased greatly, and K exhibited more poisoning effect than Ca. With the dopes of K and Ca, the acidity, the redox property and chemisorbed oxygen on the surfaces of the catalysts were decreased, which resulted in a decreasing in SCR activity.展开更多
文摘Mn-CeOff-l＇i-pillared clay （PILC） is an attrac- tive catalyst for selective catalytic reduction of NOx at low temperature because of its low cost. The poisoning of K and Ca on the catalyst of Mn-CeOx/Ti-PILC is an important problem because K and Ca are always in presence in flue gas. To investigate the effect of K and Ca on the physicochemical characters of the catalysts, the techniques of NH3-temperature programmed desorption （TPD）, H2-temperature programmed reduction （TPR）, and X-ray photoelectron spectroscopy （XPS） were used to analyze the fresh and deactivated catalysts of Mn-CeOJTi- PILC. （Ca）Mn-CeOx/Ti-PILC and （K）Mn-CeOx/Ti-PILC are denoted for the dopes of the catalyst of Mn-CeOJTi- PILC with Ca and K, respectively. The activities of Mn- CeOx/Ti-PILC, （Ca）Mn-CeOx/Ti-PILC and （K）Mn-CeOx/ Ti-PILC for NH3-selective catalytic reduction （SCR） reaction at low temperature were investigated. The results showed that with the dopes of K and Ca on the catalysts, the SCR activities of the catalysts decreased greatly, and K exhibited more poisoning effect than Ca. With the dopes of K and Ca, the acidity, the redox property and chemisorbed oxygen on the surfaces of the catalysts were decreased, which resulted in a decreasing in SCR activity.
