This work aims to study the improvement effect of Sm on Mn-based catalysts for selective catalytic reduction (SCR) of NO with NH3.A series of Sm_(x)Mn_(0.3-x)-xTi catalysts (x=0,0.1,0.15,0.2,and 0.3) were prepared by ...This work aims to study the improvement effect of Sm on Mn-based catalysts for selective catalytic reduction (SCR) of NO with NH3.A series of Sm_(x)Mn_(0.3-x)-xTi catalysts (x=0,0.1,0.15,0.2,and 0.3) were prepared by co-precipitation.Activity tests indicated that the Sm_(0.15)Mn_(0.15)Ti catalyst showed superior performances,with a NO conversion of 100%and N_(2)selectivity above 87%at 180–300℃.The characterizations showed that Sm doping suppressed the crystallization of TiO_(2)and Mn2O3phases and increased the specific surface area and acidity.In particular,the surface area increased from 152.2 m^(2)·g^(-1)for Mn0.3Ti to 241.7 m^(2)·g^(-1)for Sm_(0.15)Mn_(0.15)Ti.These effects contributed to the high catalytic activity.The X-ray photoelectron spectroscopy (XPS) results indicated that the relative atomic ratios of Sm^(3+)/Sm and Oβ/O of Sm_(0.15)Mn_(0.15)Ti were 76.77at%and 44.11at%,respectively.The presence of Sm contributed to an increase in surface-absorbed oxygen (Oβ) and a decrease in Mn^(4+)surface concentration,which improved the catalytic activity.In the results of hydrogen temperature-programmed reduction(H_(2)-TPR),the presence of Sm induced a higher reduction temperature and lower H_(2)consumption (0.3 mmol·g^(-1)) for the Sm_(0.15)Mn_(0.15)Ti catalyst compared to the Mn0.3Ti catalyst.The decrease in Mn^(4+)weakened the redox property of the catalysts and increased the N_(2)selectivity by suppressing N_(2)O formation from NH3oxidation and the nonselective catalytic reduction reaction.The in situ diffuse reflectance infrared Fourier transform spectra (DRIFTs) revealed that NH3-SCR of NO over the Sm_(0.15)Mn_(0.15)Ti catalyst mainly followed the Eley–Rideal mechanism.Sm doping increased surface-absorbed oxygen and weakened the redox property to improve the NO conversion and N_(2)selectivity of the Sm_(0.15)Mn_(0.15)Ti catalyst.展开更多
Long noncoding RNA (lncRNA) is a leader of the degree of more than 200 nucleotides, almost do not have the function of protein coding endogenous RNA molecules. Recent studies show that, lncRNA is not encoded protein, ...Long noncoding RNA (lncRNA) is a leader of the degree of more than 200 nucleotides, almost do not have the function of protein coding endogenous RNA molecules. Recent studies show that, lncRNA is not encoded protein, but it has a wide range of biological functions, and lncRNA in human diseases, especially in oncology, more and more attention has been paid to its role. Nasopharyngeal carcinoma (NPC) is a common malignant tumor of the head and neck in South China, which poses a serious threat to people’s health and life. Studies found that lncRNA is widely involved in the invasion, metastasis and prognosis of nasopharyngeal carcinoma (NPC). In this article, we will review the research progress of lncRNA in nasopharyngeal carcinoma.展开更多
The atomic force microscope(AFM)can measure nanoscale morphology and mechanical properties and has a wide range of applications.The traditional method for measuring the mechanical properties of a sample does so for th...The atomic force microscope(AFM)can measure nanoscale morphology and mechanical properties and has a wide range of applications.The traditional method for measuring the mechanical properties of a sample does so for the longitudinal and transverse properties separately,ignoring the coupling between them.In this paper,a data processing and multidimensional mechanical information extraction algorithm for the composite mode of peak force tapping and torsional resonance is proposed.On the basis of a tip–sample interaction model for the AFM,longitudinal peak force data are used to decouple amplitude and phase data of transverse torsional resonance,accurately identify the tip–sample longitudinal contact force in each peak force cycle,and synchronously obtain the corresponding characteristic images of the transverse amplitude and phase.Experimental results show that the measured longitudinal mechanical characteristics are consistent with the transverse amplitude and phase characteristics,which verifies the effectiveness of the method.Thus,a new method is provided for the measurement of multidimensional mechanical characteristics using the AFM.展开更多
基金sponsored by the National Key R&D Program of China(Nos.2021YFC1910504,2019YFC 1907101,and 2019YFC1907103)the Key R&D Program of Ningxia Hui Autonomous Region,China(Nos.2020BCE01001 and 2021BEG01003)+3 种基金the National Natural Science Foundation of China(Nos.U2002212,51672024,52102058,and 52204414)the Xijiang Innovation and Entrepreneurship Team(No.2017A0109004)the Fundamental Research Funds for the Central Universities(Nos.FRF-TP20-097A1Z and FRF-TP-20-031A1)the Foshan Science and Technology Innovation Special Foundation(No.BK22BE001)。
文摘This work aims to study the improvement effect of Sm on Mn-based catalysts for selective catalytic reduction (SCR) of NO with NH3.A series of Sm_(x)Mn_(0.3-x)-xTi catalysts (x=0,0.1,0.15,0.2,and 0.3) were prepared by co-precipitation.Activity tests indicated that the Sm_(0.15)Mn_(0.15)Ti catalyst showed superior performances,with a NO conversion of 100%and N_(2)selectivity above 87%at 180–300℃.The characterizations showed that Sm doping suppressed the crystallization of TiO_(2)and Mn2O3phases and increased the specific surface area and acidity.In particular,the surface area increased from 152.2 m^(2)·g^(-1)for Mn0.3Ti to 241.7 m^(2)·g^(-1)for Sm_(0.15)Mn_(0.15)Ti.These effects contributed to the high catalytic activity.The X-ray photoelectron spectroscopy (XPS) results indicated that the relative atomic ratios of Sm^(3+)/Sm and Oβ/O of Sm_(0.15)Mn_(0.15)Ti were 76.77at%and 44.11at%,respectively.The presence of Sm contributed to an increase in surface-absorbed oxygen (Oβ) and a decrease in Mn^(4+)surface concentration,which improved the catalytic activity.In the results of hydrogen temperature-programmed reduction(H_(2)-TPR),the presence of Sm induced a higher reduction temperature and lower H_(2)consumption (0.3 mmol·g^(-1)) for the Sm_(0.15)Mn_(0.15)Ti catalyst compared to the Mn0.3Ti catalyst.The decrease in Mn^(4+)weakened the redox property of the catalysts and increased the N_(2)selectivity by suppressing N_(2)O formation from NH3oxidation and the nonselective catalytic reduction reaction.The in situ diffuse reflectance infrared Fourier transform spectra (DRIFTs) revealed that NH3-SCR of NO over the Sm_(0.15)Mn_(0.15)Ti catalyst mainly followed the Eley–Rideal mechanism.Sm doping increased surface-absorbed oxygen and weakened the redox property to improve the NO conversion and N_(2)selectivity of the Sm_(0.15)Mn_(0.15)Ti catalyst.
文摘Long noncoding RNA (lncRNA) is a leader of the degree of more than 200 nucleotides, almost do not have the function of protein coding endogenous RNA molecules. Recent studies show that, lncRNA is not encoded protein, but it has a wide range of biological functions, and lncRNA in human diseases, especially in oncology, more and more attention has been paid to its role. Nasopharyngeal carcinoma (NPC) is a common malignant tumor of the head and neck in South China, which poses a serious threat to people’s health and life. Studies found that lncRNA is widely involved in the invasion, metastasis and prognosis of nasopharyngeal carcinoma (NPC). In this article, we will review the research progress of lncRNA in nasopharyngeal carcinoma.
基金This project is supported by the General Program of the National Natural Science Foundation of China(62073227)the National Natural Science Foundation of China(61927805 and 61903359).
文摘The atomic force microscope(AFM)can measure nanoscale morphology and mechanical properties and has a wide range of applications.The traditional method for measuring the mechanical properties of a sample does so for the longitudinal and transverse properties separately,ignoring the coupling between them.In this paper,a data processing and multidimensional mechanical information extraction algorithm for the composite mode of peak force tapping and torsional resonance is proposed.On the basis of a tip–sample interaction model for the AFM,longitudinal peak force data are used to decouple amplitude and phase data of transverse torsional resonance,accurately identify the tip–sample longitudinal contact force in each peak force cycle,and synchronously obtain the corresponding characteristic images of the transverse amplitude and phase.Experimental results show that the measured longitudinal mechanical characteristics are consistent with the transverse amplitude and phase characteristics,which verifies the effectiveness of the method.Thus,a new method is provided for the measurement of multidimensional mechanical characteristics using the AFM.