The close-coupled selective catalytic reduction(cc-SCR)catalyst is an effective technology to reduce tailpipe NOx emission during cold start.This paper investigated the optimal ammonia storage under steady and transie...The close-coupled selective catalytic reduction(cc-SCR)catalyst is an effective technology to reduce tailpipe NOx emission during cold start.This paper investigated the optimal ammonia storage under steady and transient state in the cc-SCR.The study showed that a trade-off between NOx conversion efficiency and ammonia slip is observed on the pareto solutions under steady state,and the optimal ammonia storage is calculated with ammonia slip less than 10μL/L based on the ChinaⅥemission legislation.The rapid temperature increase will lead to severe ammonia slip in the transient test cycle.A simplified 0-D calculation method on ammonia slip under transient state is proposed based on kinetic model of ammonia adsorption and desorption.In addition,the effect of ammonia storage,catalyst temperature and temperature increasing rate on ammonia slip are analyzed.The optimal ammonia storage is calculated with maximum ammonia slip less than 100μL/L according to the oxidation efficiency of ammonia slip catalyst(ASC)downstream cc-SCR.It was found that the optimal ammonia storage under transient state is much lower than that under steady state in cc-SCR at lower temperature,and a phase diagram is established to analyze the influence of temperature and temperature increasing rate on optimal ammonia storage.展开更多
Natural gas engines have become increasingly important in transportation applications,especially in the commercial vehicle sector.With increasing demand for high efficiency and low emissions,new technologies must be e...Natural gas engines have become increasingly important in transportation applications,especially in the commercial vehicle sector.With increasing demand for high efficiency and low emissions,new technologies must be explored to overcome the performance limitations of natural gas engines such as limits on lean or dilute combustion,unstable combustion,low burning velocity,and high emissions of CH_(4) and NO_(x).This paper reviews the progress of research on natural gas engines over recent decades,concentrating on ignition and combustion systems,mixture preparation,the development of different combustion modes,and after-treatment strategies.First,the features,advantages,and disadvantages of natural gas engines are introduced,following which the development of advanced ignition systems,organization of highly turbulent flows,and the preparation of high-reactivity mixtures in spark ignition engines are discussed with a focus on pre-chamber jet ignition,combustion chamber design,and H_(2)-enriched natural gas combustion.Third,the progress in natural gas dual-fuel engines is highlighted,including the exploration of new combustion modes,the development of novel pilot fuels,and the optimization of combustion control strategies.The fourth section discusses after-treatment systems for natural gas engines operating in different combustion modes.Finally,conclusions and future trends in the development of high-efficiency and clean combus-tion in natural gas engines are summarized.展开更多
The ceramic insulators of spark plugs in gasoline engines are especially prone to damage when deto-knock occurs.To under-stand the damage process and mechanism,the present work investigated the impact resistance of ce...The ceramic insulators of spark plugs in gasoline engines are especially prone to damage when deto-knock occurs.To under-stand the damage process and mechanism,the present work investigated the impact resistance of ceramic insulators using detonation waves as impact sources.A test device that generates detonation waves was developed,representing a novel means of evaluating the knock resistance of ceramic insulators.Various impact types and detonation intensities were employed,and detonation initiation and propagation at peak pressures greater than 100 MPa were assessed using synchronous high-speed direct photography and pressure measurements.The test results demonstrate that ceramic insulators tend to break at the base of the breathing chamber when damaged by a single high peak pressure detonation wave impact.In contrast,multiple low pressure impacts eventually break the insulator into multiple fragments.The data also show that the positioning of a ground electrode upstream of the ceramic insulator greatly increases the resistance of the ceramic to the detonation impact.A two-dimensional computational fluid dynamics simulation coupled with a chemical kinetics analysis demonstrated that this improved resistance can be ascribed to a reduced peak pressure that appears after the detonation wave diffracts from the electrode prior to contacting the ceramic insulator.展开更多
基金supported by the National Natural Science Foundation of China(No.51976100)the co-founding of FAW Jiefang Automobile Co.,Ltd.Wuxi Diesel Engine Factory,Saudi Aramco Technologies CompanyShandong Chambroad Petrochemicals Co.,Ltd.with the project“Fuel and Engine Co-optimization for high Efficiency and Net-Zero Emission Heavy-duty Engine”。
文摘The close-coupled selective catalytic reduction(cc-SCR)catalyst is an effective technology to reduce tailpipe NOx emission during cold start.This paper investigated the optimal ammonia storage under steady and transient state in the cc-SCR.The study showed that a trade-off between NOx conversion efficiency and ammonia slip is observed on the pareto solutions under steady state,and the optimal ammonia storage is calculated with ammonia slip less than 10μL/L based on the ChinaⅥemission legislation.The rapid temperature increase will lead to severe ammonia slip in the transient test cycle.A simplified 0-D calculation method on ammonia slip under transient state is proposed based on kinetic model of ammonia adsorption and desorption.In addition,the effect of ammonia storage,catalyst temperature and temperature increasing rate on ammonia slip are analyzed.The optimal ammonia storage is calculated with maximum ammonia slip less than 100μL/L according to the oxidation efficiency of ammonia slip catalyst(ASC)downstream cc-SCR.It was found that the optimal ammonia storage under transient state is much lower than that under steady state in cc-SCR at lower temperature,and a phase diagram is established to analyze the influence of temperature and temperature increasing rate on optimal ammonia storage.
基金This work is supported by the Key Program of National Natural Science Foundation of China(21761142012)the National Key Research and Development Program of China[2016YFB0101402][2017YFE0102800].
文摘Natural gas engines have become increasingly important in transportation applications,especially in the commercial vehicle sector.With increasing demand for high efficiency and low emissions,new technologies must be explored to overcome the performance limitations of natural gas engines such as limits on lean or dilute combustion,unstable combustion,low burning velocity,and high emissions of CH_(4) and NO_(x).This paper reviews the progress of research on natural gas engines over recent decades,concentrating on ignition and combustion systems,mixture preparation,the development of different combustion modes,and after-treatment strategies.First,the features,advantages,and disadvantages of natural gas engines are introduced,following which the development of advanced ignition systems,organization of highly turbulent flows,and the preparation of high-reactivity mixtures in spark ignition engines are discussed with a focus on pre-chamber jet ignition,combustion chamber design,and H_(2)-enriched natural gas combustion.Third,the progress in natural gas dual-fuel engines is highlighted,including the exploration of new combustion modes,the development of novel pilot fuels,and the optimization of combustion control strategies.The fourth section discusses after-treatment systems for natural gas engines operating in different combustion modes.Finally,conclusions and future trends in the development of high-efficiency and clean combus-tion in natural gas engines are summarized.
基金This work was supported by National Natural Science Foundation of China(Grant Nos.91541206 and 51706121)China Postdoctoral Science Foundation(Grant No.2017T100076).
文摘The ceramic insulators of spark plugs in gasoline engines are especially prone to damage when deto-knock occurs.To under-stand the damage process and mechanism,the present work investigated the impact resistance of ceramic insulators using detonation waves as impact sources.A test device that generates detonation waves was developed,representing a novel means of evaluating the knock resistance of ceramic insulators.Various impact types and detonation intensities were employed,and detonation initiation and propagation at peak pressures greater than 100 MPa were assessed using synchronous high-speed direct photography and pressure measurements.The test results demonstrate that ceramic insulators tend to break at the base of the breathing chamber when damaged by a single high peak pressure detonation wave impact.In contrast,multiple low pressure impacts eventually break the insulator into multiple fragments.The data also show that the positioning of a ground electrode upstream of the ceramic insulator greatly increases the resistance of the ceramic to the detonation impact.A two-dimensional computational fluid dynamics simulation coupled with a chemical kinetics analysis demonstrated that this improved resistance can be ascribed to a reduced peak pressure that appears after the detonation wave diffracts from the electrode prior to contacting the ceramic insulator.