Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability a...Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability after fracturing.In this study,the novel extruded Mg-10Gd-3Y-0.3Zr-xNi alloys will be reported and their microstructure,mechanical and corrosion behaviors will be also studied.The results show that Ni contents influence phase precipitation behaviors.With adding 0.2 wt%Ni,a large amount of Zr_(7)Ni_(10)phases will be precipitated insidesα-Mg matrix,directly leading to degradation of strength and large corrosion rate.With further increasing Ni contents,the precipitation phases can be changed from Mg_(5)RE to 18R-LPSO structure,resulting in higher mechanical properties and faster corrosion rate.Moreover,adding Ni element also change the texture orientation by influencing the precipitation behavior of the alloys.The alloys invented in this paper have attained the highest compressive and tensile properties among all the reported dissoluble magnesium alloys.This work is beneficial in understanding the role of Ni in the magnesium alloys and provides more materials alternatives for the fabrication of dissoluble fracturing tools.展开更多
Microstructures of nanoporous Pd are essentially important for its physical and chemical properties.In this work,we show that the microstructures of nanoporous Pd can be tuned by adjusting compositions of the precurso...Microstructures of nanoporous Pd are essentially important for its physical and chemical properties.In this work,we show that the microstructures of nanoporous Pd can be tuned by adjusting compositions of the precursor alloys,and dealloying and heat treatment parameters.Both the ligament and pore sizes decrease with increasing the electrochemical potential upon dealloying and the concentration of noble component in the precursor alloys.Heat treatment causes coarsening of the nanoporous structure.Above a critical temperature,the nanoporous structures are subjected to significant coarsening.Below the critical temperature,surface diffusion is believed to dominate the coarsening process.Above the critical temperature,the nanoporous structure coarsens remarkably at a rather high rate,which is ascribed to a multiple-mechanism controlled process.展开更多
基金The National Natural Science Foundation of China(Nos.51671017,51971020)the Major State Research and Development Program of China(No.2016YFB0300801)+4 种基金Beijing Municipal Natural Science Foundation(No.2202033)Beijing Laboratory of Metallic Materials and Processing for Modern Transportationthe fund of the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP201835)the Fundamental Research Funds for the Central Universities(No.FRF-IC-19–010,FRF-IC-19–015)the Opening Research Fund of State Key Laboratory for Advanced Metals and Materials(2018-Z04)。
文摘Magnesium alloys,a novel functional material for the fabrication of fracturing tools,are being paid more and more attentions recently due to their relatively high mechanical properties and fast dissolubility ability after fracturing.In this study,the novel extruded Mg-10Gd-3Y-0.3Zr-xNi alloys will be reported and their microstructure,mechanical and corrosion behaviors will be also studied.The results show that Ni contents influence phase precipitation behaviors.With adding 0.2 wt%Ni,a large amount of Zr_(7)Ni_(10)phases will be precipitated insidesα-Mg matrix,directly leading to degradation of strength and large corrosion rate.With further increasing Ni contents,the precipitation phases can be changed from Mg_(5)RE to 18R-LPSO structure,resulting in higher mechanical properties and faster corrosion rate.Moreover,adding Ni element also change the texture orientation by influencing the precipitation behavior of the alloys.The alloys invented in this paper have attained the highest compressive and tensile properties among all the reported dissoluble magnesium alloys.This work is beneficial in understanding the role of Ni in the magnesium alloys and provides more materials alternatives for the fabrication of dissoluble fracturing tools.
基金supported financially by the National Natural Science Foundation of China(Nos.51771153,51371147,51790481 and 51431008)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX201825)。
文摘Microstructures of nanoporous Pd are essentially important for its physical and chemical properties.In this work,we show that the microstructures of nanoporous Pd can be tuned by adjusting compositions of the precursor alloys,and dealloying and heat treatment parameters.Both the ligament and pore sizes decrease with increasing the electrochemical potential upon dealloying and the concentration of noble component in the precursor alloys.Heat treatment causes coarsening of the nanoporous structure.Above a critical temperature,the nanoporous structures are subjected to significant coarsening.Below the critical temperature,surface diffusion is believed to dominate the coarsening process.Above the critical temperature,the nanoporous structure coarsens remarkably at a rather high rate,which is ascribed to a multiple-mechanism controlled process.
