FORMATION OF GRADIENT COATING OF Fe-BASED ALLOY WITH RARE EARTHS BY PLASMA SURFACING

A gradient coating of Fe-based alloy was manufactured with rare earths (RE) by plasma surfacing on Q235 steel substrate. The coatings were studied by using X-ray diffraction(XRD), scanning electron microscope(SEM), differential thermal analyzer(DTA), and electron probe micro-analyzer (EPMA). The results show that the phases of the two kinds of coatings(with and without RE) both include α-Fe, Fe7C3, Fe3C, Cr2B, Fe2B and FeB. The microstructure of F314 coating is mainly hypereutectic, the pro-phases Cr7C3 and Cr2B are loose, crassi, spiculate and contain microcracks. The brittleness of the coating is high, and the average hardness is 787 HV. When 0.8wt% RE was added into the F314 alloy, the microstructure varied from hypoeutectic to hypereutectic continuously, The hardness appears as gradient distribution with the highest value of 773 HV, meanwhile, the brittleness decreases significantly. The formation of gradient structure depends on the fallowing factors: (i) the conversion of RE. The addition of RE lowers the elements point and Fe-C eutectic temperature, thus the base metal melting acutely. (ii) the heating of plasma arc. Graded temperature results in directional solidification, thus the gradient structure forms easily. The main reasons for the hardness decrease with RE addition in the alloy are the ratio of hard phase lowering and the hardness of the hard phase decreasing.

Role of grain boundary character on Bi segregation-induced embrittlement in ultrahigh-purity copper

Bismuth(Bi),as an impurity element in copper and copper-based alloys,usually has a strong tendency of grain boundary(GB)segregation,which depends on the GB characters.However,the influence of such a segregation on the properties of ultrahigh-purity copper has been rarely reported and the exact structural arrangements of Bi atoms at different GBs remain largely unclear.In this study,we investigated the influ-ence of trace amounts of Bi(50-300 wt ppm)on the ductility of an ultrahigh-purity copper(99.99999%)in the range of room temperature to 900°C.The tensile results show that the addition of Bi seriously damages the ductility of the ultrahigh-purity copper at temperatures of 450-900°C,which is due to the GB segregation of Bi.On this basis,such a segregation behavior at different types of GBs,including high and low angle GBs(HAGBs/LAGBs),and twin boundaries(TBs),via the scanning electron microscope-electron backscattered diffraction(SEM-EBSD)and aberration-corrected scanning transmission electron microscope(AC-STEM)investigations,combined with the first-principles calculations were systematically studied.The atomistic characterizations demonstrate an anisotropic Bi segregation,where severe enrich-ment of Bi atoms typically occurs at the HAGBs,while the absence of Bi adsorption prevails at LAGBs or TBs.In particular,the segregated Bi at random HAGBs exhibited the directional bilayer adsorption,while the special symmetrical7 HAGB presented a unique Bi-rich cluster superstructure.Our findings pro-vide a comprehensive experimental and computational understanding on the atomic-scale segregation of impurities in metallic materials.

The design and performance of GRD onboard the GECAM satellite

Background Each GECAM satellite payload contains 25 gamma-ray detectors(GRDs),which can detect gamma-rays and particles and can roughly localize the Gamma-Ray Bursts(GRBs).GRD was designed using lanthanum bromide(LaBr3)crystal as the sensitive material with the rear end coupled with silicon photomultiplier(SiPM)array for readout.Purpose In aerospace engineering design of GRD,there are many key points to be studied.In this paper,we present the specific design scheme of GRD,the assembly and the performance test results of detectors.Methods Based on Monte Carlo simulation and experimental test results,the specific schematic design and assembling process of GRD were optimized.After being fully assembled,the GRDs were conducted performance tests by using radioactive source and also conducted random vibration tests.Result and conclusion The test results show that all satellite-borne GRDs have energy resolution<16%at 59.5 keV,meeting requirements of satellite in scientific performance.The random vibration test shows that GRD can maintain in a stable performance,which meets the requirement of spatial application.

The design and performance of charged particle detector onboard the GECAM mission

Background The Gravitational wave highly energetic Electromagnetic Counterpart All-sky Monitor(GECAM)is dedicated to detecting gravitational wave gamma-ray bursts.It is capable of all-sky monitoring over and discovering gamma-ray bursts and new radiation phenomena.GECAM consists of two microsatellites,each equipped with 8 charged particle detectors(CPDs)and 25 gamma-ray detectors(GRDs).Purpose The CPD is used to measure charged particles in the space environment,monitor energy and flow intensity changes,and identify between gamma-ray bursts and space charged particle events in conjunction with GRD.Methods CPD uses plastic scintillator as the sensitive material for detection,silicon photomultiplier array as the optically readable device,and the inlaid Am-241 radioactive source as the onboard calibration means.Conclusion In this paper,we will present the working principle,physical design,functional implementation and preliminary performance test results of the CPD.As a result,the energy range of electron,gamma-ray detection efficiency and dead time are tested to be better than the indexes required through the ground calibration experiment.

Dedicated SiPM array for GRD of GECAM

Purpose The discovery of gravitational waves and gamma-ray bursts heralds the era of multi-messenger astronomy.With the adoption of two small satellites to achieve the all-sky monitoring of gamma-ray bursts,the gravitational wave highenergy electromagnetic counterpart all-sky monitor(GECAM)possesses a quasi-real-time early warning ability and plays an important role in positioning the sources of gravitational waves and in subsequent observations.Each satellite of GECAM was fitted with 253-inch-diameter gamma-ray detectors(GRD),covering an energy range of 8–2 MeV.GRDs have adopted silicon photomultiplier tubes(SiPM)in lieu of photomultiplier tubes(PMT)to adapt to the dimensional limitations of micro-satellites.Methods A unique 3-inch circular SiPM array was designed.In this design,646×6 mm chips were arranged evenly in a circular manner with the seams filled with reflecting films,thus achieving satisfactory uniformity of light collection.The integrated pre-amplifier circuit on the back of the SiPM array adopted two-level grouping and summing;further,it achieved a satisfactory signal-to-noise ratio.Two high-gain and low-gain channels were adopted to achieve a large dynamic range,and two independent power supply units were used,where each unit can be closed separately,thus improving reliability.Results Performance studies show that this SiPM array meets the requirements of GECAM.Conclusion A 3-inch SiPM array have been developed that uses grouped summation,reflective films,a circular arrangement,two groups of independent power supplies,high-and low-gain signals,differential signal output technologies,etc.This solution can be used not only for GECAM,but also as a general solution for SiPM-based scintillation detectors.

The technology for detection of gamma-ray burst with GECAM satellite

Introduction The main physical objective of the GECAM satellite is to detect gamma-ray bursts,which is related to gravitational waves of double compact object mergers.The GECAM satellite also detects and investigates various bursts of high-energy celestial bodies.Purposes and methods In this study,we designed,developed and calibrated the payload and launched it into orbit with GECAM satellite.The payload consists of the gamma ray detector(GRD,for detecting 4 keV–4 MeV X/γray),the charged particle detector(CPD,for detecting 150 keV–5 MeV charged particle),and the electronic box(EBOX).The all-sky field coverage is achieved via two 229-degree large-area satellites positioned 180 degrees apart and are on opposite sides of the geo-center.Each satellite is equipped with 25 GRDs and 8 CPDs;thus,the satellite can identify charged particle bursts in space.Gamma-ray detectors adopt lanthanum bromide crystal technology combined with silicon photomultipliers.This is the first time that this technology was used massively in space detectors.Conclusions The GECAM satellite can quickly determine the direction of gamma-ray bursts(positioning)via indexing and fitting method,while the transmit variability,energy spectrum and direction of the gamma-ray bursts guide subsequent observations through the Beidou-3 RDSS in quasi-real time.It will play an important role in the study of high energy celestial bursts.

Quality assurance test and failure analysis of SiPM arrays of GECAM satellites

Background The Gravitational wave high-energy Electromagnetic Counterpart All-sky Monitor(GECAM)satellite developed a SiPM-based gamma-ray detector to monitor the gravitational wave-related GRBs and guide subsequent observations in other wavelengths of EM.Purpose As all the available SiPM devices belong to commercial grade,quality assurance tests need to be performed in accordance with the aerospace specifcations.Methods In the SiPM application of GECAM,quality assurance experiments were conducted.The mechanism of the failure of SiPM devices was analyzed during the development process.Result Based on the quality assurance test results,the fnal pass rate of SiPM array was 95%.Based on the failure analysis,it was found that a piece of SiPM had a leakage channel after longtime operation due to device defects.Conclusion According to the accumulated experience,in the reliability test of SiPM,it is necessary to pay special attention to test the impedance of each pin of SiPM to ground and confrm that the power switch state of SiPM is controllable.

The data acquisition algorithm designed for the SiPM-based detectors of GECAM satellite

Background The Gravitational Wave High-energy Electromagnetic Counterpart All-sky Monitor(GECAM)consists of 2 microsatellites,each of which contains 25 GRD(LaBr3)detectors and 8 CPD(plastic scintillator)detectors.Method silicon photomultiplier(SiPM)array is used to read each detector.The output signal of these detectors with SiPM array is very special and challenging to readout.In this study,a novel data acquisition(DAQ)algorithm for these detectors is designed and implemented,and the content of the output event packet is defined.Result and Conclusion The performances,including the event acquisition efficiency of this DAQ algorithm,are extensively verified through experimental tests.From the on-ground and in-flight tests,this algorithm has excellent performance despite the very limited resources and short development time of GECAM mission.