Ammonium salts, （NH4）6HPMo11MO40 （M = Ni, Co, Fe）, have been investigated for the oxidation of propane, with molecular oxygen, at temperature ranging between 380 ℃ and 420 ℃ after in-situ pre-treatment performed...Ammonium salts, （NH4）6HPMo11MO40 （M = Ni, Co, Fe）, have been investigated for the oxidation of propane, with molecular oxygen, at temperature ranging between 380 ℃ and 420 ℃ after in-situ pre-treatment performed at two heating rate of 5 or 9 ℃/min. They were characterized by BET method, XRD, 31p NMR, UV-Vis and IR techniques. The catalysts were found active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-treated with the heating rate of 9 ℃/min.展开更多
文摘Ammonium salts, （NH4）6HPMo11MO40 （M = Ni, Co, Fe）, have been investigated for the oxidation of propane, with molecular oxygen, at temperature ranging between 380 ℃ and 420 ℃ after in-situ pre-treatment performed at two heating rate of 5 or 9 ℃/min. They were characterized by BET method, XRD, 31p NMR, UV-Vis and IR techniques. The catalysts were found active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-treated with the heating rate of 9 ℃/min.
